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11.
Ten bis(4-aryloxy-3-nitrophenyl) sulfones were synthesized via a phase-transfer catalyzed, nucleophilic displacement reaction involving phenoxides and bis(4-chloro-3-nitrophenyl) sulfone. 相似文献
12.
Void swelling is an important phenomenon observed in both nuclear fuels and cladding materials in operating nuclear reactors. In this work we develop a phase-field model to simulate void evolution and void volume change in irradiated materials. Important material processes, including the generation of defects such as vacancies and self-interstitials, their diffusion and annihilation, and void nucleation and evolution, have been taken into account in this model. The thermodynamic and kinetic properties, such... 相似文献
13.
We report a highly accurate phase-based technique for measuring arbitrarily long optical distance with subnanometer precision. The method employs a Michelson interferometer with a pair of harmonically related light sources, one cw and the other low coherence. By slightly detuning (~2 nm) the center wavelength of the low-coherence source between scans of the target sample, we can use the phase relationship between the heterodyne signals of the cw and the low-coherence light to measure the separation between reflecting interfaces with subnanometer precision. As this technique is completely free of 2pi ambiguity, an issue that plagues most phase-based techniques, it can be used to measure arbitrarily long optical distances without loss of precision. We demonstrate one application of this technique, the high-precision determination of the differential refractive index. 相似文献
14.
Blood analysis by Raman spectroscopy 总被引:1,自引:0,他引:1
Concentrations of multiple analytes were simultaneously measured in whole blood with clinical accuracy, without sample processing, using near-infrared Raman spectroscopy. Spectra were acquired with an instrument employing nonimaging optics, designed using Monte Carlo simulations of the influence of light-scattering-absorbing blood cells on the excitation and emission of Raman light in turbid medium. Raman spectra were collected from whole blood drawn from 31 individuals. Quantitative predictions of glucose, urea, total protein, albumin, triglycerides, hematocrit, and hemoglobin were made by means of partial least-squares (PLS) analysis with clinically relevant precision (r(2) values >0.93). The similarity of the features of the PLS calibration spectra to those of the respective analyte spectra illustrates that the predictions are based on molecular information carried by the Raman light. This demonstrates the feasibility of using Raman spectroscopy for quantitative measurements of biomolecular contents in highly light-scattering and absorbing media. 相似文献
15.
We introduce Hilbert phase microscopy (HPM) as a novel optical technique for measuring high transverse resolution quantitative phase images associated with optically transparent objects. Because of its single-shot nature, HPM is suitable for investigating rapid phenomena that take place in transparent structures such as biological cells. The potential of this technique for studying biological systems is demonstrated with measurements of red blood cells, and its ability to quantify dynamic processes on a millisecond scale is exemplified with measurements of evaporating micrometer-sized water droplets. 相似文献
16.
We report on a high statistics search for the Ξ??(1860) resonance in Σ?-nucleus collisions at 340 GeV/c. No evidence for this resonance is found in our data sample which contains 676000 Ξ? candidates above bakground. For the decay channel Ξ??(1860)→Ξ? π ? and the kinematic range 0.15<xF<0.9 we find a 3σ upper limit for the production cross section of 3.1 and 3.5 μb per nucleon, for reactions with carbon and copper, respectively. 相似文献
17.
Kevin Tienda Zhenning Yu Fadwa Constandinidis Andria Fortney William A. Feld Eric Fossum 《Journal of polymer science. Part A, Polymer chemistry》2011,49(13):2908-2915
A series of poly(arylene ether)s, (PAEs), carrying a pendant diphenyl phosphoryl group were prepared via the nucleophilic aromatic substitution (NAS) reactions of 3,5‐difluorotriphenylphosphine oxide, 6 . The difluoro monomer 6 was synthesized via two‐step reaction sequence and subsequently characterized by 1H, 13C, 19F, and 31P NMR spectroscopy, GC/MS, and elemental analysis. The reactivity of the electrophilic sites in 6 , activated by only a diphenylphosphoryl group located in the meta‐position, in 6 was probed via NMR spectroscopy and model reactions and was determined to be sufficient to undergo typical NAS reactions. High molecular weight, amorphous, organic soluble poly(arylene ether)s, bearing a pendant diphenylphosphoryl group, were prepared via the reaction of 6 with a variety of bis‐phenols under typical NAS conditions. The poly(arylene ether)s were characterized for structure via the use of 1H, 13C, and 31P NMR spectroscopy while their thermal properties were evaluated using DSC and TGA analysis. The glass transition temperatures (Tg) of the synthesized PAEs ranged from 143 to 175 °C, while their 5% weight loss temperatures ranged from 467 to 510 °C under nitrogen and from 470 to 526 °C in air. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
18.
Ohne Zusammenfassung 相似文献
19.
A. Kurtenacker A. Fritsch F. Raschig E. H. Riesenfeld G. W. Feld und R. Willst?tter 《Fresenius' Journal of Analytical Chemistry》1925,67(1-2):64-67
Ohne Zusammenfassung 相似文献
20.
E. Bonvin R. Bopp L. J. Carroll A. J. Cass S. U. Chung M. Donnat P. A. Dorsaz M. E. Feliks L. Fluri J. N. Jackson M. N. Kienzle-Focacci J. G. Lynch M. Martin L. Mathys P. J. Negus L. Perini R. Poultney W. H. Range L. Rosselet S. W. Snow A. S. Thompson R. M. Turnbull M. Werlen WA -Collaboration 《Zeitschrift fur Physik C Particles and Fields》1989,41(4):591-598
A search for pairs of highp T prompt photons produced in hydrogen by a 280 GeV/c incidentπ - beam has been carried out using a fine-grained electromagnetic calorimeter and the Omega spectrometer at the CERN SPS. Clear evidence for the existence of such events is found with a six standard deviation signal forp T >3.0 GeV/c. The cross-sections are consistent with beyond leading order QCD calculations. A discussion on the determination of α s is also presented. 相似文献