基于5-(4-(2,6-二(2-吡啶基)-4-吡啶基)苯氧基)间苯二甲酸的Ni(Ⅱ)和Cd(Ⅱ)配位聚合物的合成与晶体结构

用溶剂热法合成了2个以5-(4-(2,6-二(2-吡啶基)-4-吡啶基)苯氧基)间苯二甲酸(H₂L)为配体的金属-有机配位聚合物:{[NiL(H₂O)]·H₂O}_n(1),[CdL(phen)]_n(2)。通过X-射线单晶衍射,元素分析和红外光谱进行了结构表征。结构分析表明,在1中,L^2-配体的2个羧基氧原子桥连相邻的2个Ni(Ⅱ)离子,形成平行于a轴的一维链,链间则通过吡啶氮原子与金属离子连接,最终形成具有(4,4)-连接三维网络结构。在2中,Cd(Ⅱ)为七配位的单帽三棱柱几何构型,L^2-配体通过2个羧基和1个吡啶基与3个中心金属Cd(Ⅱ)相连,形成(3,3)-连接的二维层面结构,又通过面间的π…π堆积作用形成了3D超分子结构。测定了配位聚合物的热稳定性和2的荧光性质。     

Novel lead(II) carboxylate-arsonate hybrids

Hydrothermal reactions of lead(II) acetate with phenylarsonic acid (H₂L¹) (or 4-hydroxy-3-nitrophenylarsonic acid, H₃L²) and 5-sulfoisophthalic acid monosodium salt (NaH₂SIP) (or 1,3,5-benzenetricarboxylic acid (H₃BTC)) as the second metal linkers afforded three novel mixed-ligand lead(II) carboxylate-arsonates, namely, Pb₅(SIP)₂(L¹)₂(H₂O) 1, Pb₃(SIP)(L²)(H₂O) 2 and Pb(H₂L²)(H₂BTC) 3. The structure of 1 features a complicated 3D network composed of 2D double layers of lead(II) sulfoisophthalate bridged by 1D chains of lead(II) arsonates along b-axis, forming large tunnels along b-axis which are occupied by phenyl rings of the arsonate ligands. In 2, the Pb(II) ions are bridged by {L²}³⁻ anions into a 2D double layer whereas the interconnection of the Pb(II) ions via bridging and chelating SIP anions gave a 2D double layer. The cross-linkage of the above two building units leads to a complicated 3D network. In 3, the interconnection of the Pb(II) ions via bridging {H₂L²}⁻ and {H₂BTC}⁻ anions leads to a 1D double chain down a-axis. These 1D chains are further interconnected via hydrogen bonds among non-coordination carboxylate groups and arsonate oxygens into a 3D supramolecular architecture.     

Two new coordination polymers based on tartaric acid ligand: Syntheses,crystal structure and thermal stability

Two new coordination polymers [Cd₃(D-Tar)₃]_n (1) and [Pb(meso-Tar)]_n (2) (H₂Tar = tartaric acid) have been synthesized by hydrothermal reaction and characterized by single crystal X-ray diffraction analysis and IR spectra. 1 crystallizes in the C222₁ chiral space group and shows a 3D (4,4)-connected net with the (4.6.8⁴)₄(4.6².8².10)(4.6².8³)(4.6³.8²)(4.6³.8²)₄(4.8⁵)₂ topology. 2 possesses a 3D (4,4)-connected net with the (4³.6².8) topology. In addition, the thermogravimetric analyses (TGA) results for polymers are discussed.     

Interaction of a New Fluorescent Probe with DNA and its Use in Determination of DNA

In this paper we reported a metal complex 1-Zn (2,5-di-[2-(3,5-bis(2-pyridylmethyl)amine-4-hydroxy-phenyl)-ethylene]-pyrazine-Zn) as a fluorescent probe sensing DNA. The result of the competitive experiment of the probe with ethidium bromide (EB) to bind DNA, absorption spectral change and polarization change in the presence and absence of DNA revealed that interaction between the probe and DNA was via intercalation. Ionic strength experiment showed the existence of electrostatic interaction as well. Scatchard plots also confirmed the combined binding modes. The fluorescence enhancement of the probe was ascribed to highly hydrophobic environment when it bound the macromolecules such as DNA, RNA or denatured DNA. The binding constant between the probe and DNA was estimated as 3.13 × 10⁷ mol⁻¹ L. The emission intensity increase was proportional to the concentration of DNA. Based on this, the probe was used to determine the concentration of calf thymus DNA (ct-DNA). The corresponding linear response ranged from 2.50 × 10⁻⁷ to 4.75 × 10⁻⁶ mol L⁻¹, and detection limit was 1.93 × 10⁻⁸ mol L⁻¹ for ct-DNA.     

温度对铷原子D2线饱和吸收光谱的影响

从理论上分析了铷原子蒸汽温度对87Rb和85Rb D2线饱和吸收光谱在消除了多普勒背景情况下的光谱相对强度的影响.由于有效原子数密度、多普勒加宽、电极化率受温度变化的影响,每一条超精细谱线的相对强度随着温度的升高都会出现先增大后减小的变化趋势,相对强度最高时的温度称为最佳温度.对于87Rb或85Rb来说,不同超精细谱线最佳温度不同的主要原因是由于烧孔面积和跃迁几率不同造成的,而87Rb和85Rb不同超精细谱线最佳温度不同的主要原因是由于它们在自然界中丰度不同造成的.     

超短脉冲抽运下频率一致纠缠光源量子特性实验研究

利用自发参量下转换过程产生的频率纠缠光源在量子信息处理及相关领域中 具有十分重要的应用. 本文利用中心波长为792 nm, 脉冲宽度小于20 fs的脉冲激光源抽运满足II类准相位 匹配条件的周期极化磷酸氧钛钾晶体, 实验产生了偏振相互正交的频率一致纠缠光子对. 基于Hong-Ou-Mandel干涉仪的二阶量子符合干涉装置, 测量到该纠缠双光子对的干涉可见度约为42%, 表明其频率不可分特性较理想频率一致纠缠光源大大降低. 通过理论分析给出, 由于超短脉冲光源对应的宽频谱带宽影响, 相位匹配函数中的高阶色散项不再忽略, 从而导致纠缠光子对的频率不可分性减弱. 进一步利用实验参数给出的数值模拟结果与实验结果符合, 证实了脉冲抽运源带宽对频率一致纠缠光源的量子不可分特性的影响.关键词：频率一致纠缠Hong-Ou-Mandel干涉测量符合计数     

MnO2电沉积直立碳纳米管制备超级电容器

以直立碳纳米管为基底,以pH=6.0的0.1 mol/L Na2SO4为底液,采用电化学沉积法在0.2 mol/L Mn(CH3COO)2溶液中制备了直立碳纳米管与MnO2复合材料. SEM测试结果表明,复合材料表面呈现多孔状结构. 通过循环伏安、恒流充放电、交流阻抗等电化学方法对复合材料修饰电极进行电容性质测试. 结果表明,在1 mol/L KCl溶液中,0～0.6 V(vs.Ag/AgCl参比)电位窗口内此复合材料表现出优良的超电容性能. 直立碳纳米管电极的比电容为16 F/g,在碳纳米管表面沉积上MnO2修饰层后,复合材料电极的比电容增大至330 F/g,比电容量大幅提升近20倍. 同时扫描200圈后,直立碳纳米管与MnO2复合材料的循环伏安曲线变化很小,具有相当好的循环寿命和电容稳定性能.     

ADT-Type [FeFe]-hydrogenase biomimics featuring monodentate phosphines: formation,structures, and electrocatalysis

Transition Metal Chemistry - To further develop the diiron subsite biomimics of [FeFe]-hydrogenases, two new diiron azadithiolate (adt) complexes Fe2(μ-adtNPh)(CO)5(Ph2PX)...