Special Pore-Space-Partition CoFePBA Hollow Framework Realizing High-Performance Glucose Sensing

In this work for the first time pore-space-partition (PSP)-CoFePBA hollow framework is elaborately designed and successfully obtained via self-template internal dissolution strategy. As is demonstrated by our previous report, Prussian blue analogue (PBA) with hollow morphology is very beneficial to improve sensing performance. As expected, the PSP-CoFePBA hollow framework in this work exhibits far superior glucose sensing performance compared with classic CoFePBA nanoparticles and nanoboxes as well as most of reported PBA-based glucose sensors. Herein, very high sensitivity of 1184.18 μA mM⁻¹ cm⁻² and 267.63 μA mM⁻¹ cm⁻² in the concentration range of 5–325 μM and 325–1025 μM, respectively, as well as low detection limit of 0.4 μM (S/N=3) and high stability can be observed. In a word, this work proposes and develops a simple and general synthetic strategy for constructing PBA-based hollow material, that will be very helpful in this field.     

N-fold generalized Darboux transformation and breather–rogue waves on the constant/periodic background for a generalized mixed nonlinear Schrödinger equation

Nonlinear Dynamics - In this paper, a generalized mixed nonlinear Schrödinger equation, which arises in several physical applications including fluid mechanics (for the weakly nonlinear...     

以5-(6-羧酸-2-萘基)-间苯二羧酸为配体构筑的两个镉的金属-有机骨架化合物的合成、晶体结构及荧光性质

在溶剂热条件下,以不对称三羧酸5-（6-羧酸-2-萘基）-间苯二羧酸（H3L）为配体合成了2个镉的金属-有机骨架化合物:{[Cd₃L₂（H₂O）₃]·6DMF}_n（1）和{[Cd₃L₂（H₂O）₄]·3DMA}_n（2）。通过X射线单晶衍射,粉末衍射,热重和红外光谱进行了结构表征。结构分析表明,1和2形成3,6-连接的三维结构,其拓扑符号分别为:（4⁵.6⁴.8⁶）（4³）₂和(6¹².8³)（6³）₂。此外,还对2个化合物进行了荧光分析。     

Novel lead(II) carboxylate-arsonate hybrids

Hydrothermal reactions of lead(II) acetate with phenylarsonic acid (H₂L¹) (or 4-hydroxy-3-nitrophenylarsonic acid, H₃L²) and 5-sulfoisophthalic acid monosodium salt (NaH₂SIP) (or 1,3,5-benzenetricarboxylic acid (H₃BTC)) as the second metal linkers afforded three novel mixed-ligand lead(II) carboxylate-arsonates, namely, Pb₅(SIP)₂(L¹)₂(H₂O) 1, Pb₃(SIP)(L²)(H₂O) 2 and Pb(H₂L²)(H₂BTC) 3. The structure of 1 features a complicated 3D network composed of 2D double layers of lead(II) sulfoisophthalate bridged by 1D chains of lead(II) arsonates along b-axis, forming large tunnels along b-axis which are occupied by phenyl rings of the arsonate ligands. In 2, the Pb(II) ions are bridged by {L²}³⁻ anions into a 2D double layer whereas the interconnection of the Pb(II) ions via bridging and chelating SIP anions gave a 2D double layer. The cross-linkage of the above two building units leads to a complicated 3D network. In 3, the interconnection of the Pb(II) ions via bridging {H₂L²}⁻ and {H₂BTC}⁻ anions leads to a 1D double chain down a-axis. These 1D chains are further interconnected via hydrogen bonds among non-coordination carboxylate groups and arsonate oxygens into a 3D supramolecular architecture.     

Two new coordination polymers based on tartaric acid ligand: Syntheses,crystal structure and thermal stability

Two new coordination polymers [Cd₃(D-Tar)₃]_n (1) and [Pb(meso-Tar)]_n (2) (H₂Tar = tartaric acid) have been synthesized by hydrothermal reaction and characterized by single crystal X-ray diffraction analysis and IR spectra. 1 crystallizes in the C222₁ chiral space group and shows a 3D (4,4)-connected net with the (4.6.8⁴)₄(4.6².8².10)(4.6².8³)(4.6³.8²)(4.6³.8²)₄(4.8⁵)₂ topology. 2 possesses a 3D (4,4)-connected net with the (4³.6².8) topology. In addition, the thermogravimetric analyses (TGA) results for polymers are discussed.     

温度对铷原子D2线饱和吸收光谱的影响

从理论上分析了铷原子蒸汽温度对87Rb和85Rb D2线饱和吸收光谱在消除了多普勒背景情况下的光谱相对强度的影响.由于有效原子数密度、多普勒加宽、电极化率受温度变化的影响,每一条超精细谱线的相对强度随着温度的升高都会出现先增大后减小的变化趋势,相对强度最高时的温度称为最佳温度.对于87Rb或85Rb来说,不同超精细谱线最佳温度不同的主要原因是由于烧孔面积和跃迁几率不同造成的,而87Rb和85Rb不同超精细谱线最佳温度不同的主要原因是由于它们在自然界中丰度不同造成的.     

超短脉冲抽运下频率一致纠缠光源量子特性实验研究

利用自发参量下转换过程产生的频率纠缠光源在量子信息处理及相关领域中 具有十分重要的应用. 本文利用中心波长为792 nm, 脉冲宽度小于20 fs的脉冲激光源抽运满足II类准相位 匹配条件的周期极化磷酸氧钛钾晶体, 实验产生了偏振相互正交的频率一致纠缠光子对. 基于Hong-Ou-Mandel干涉仪的二阶量子符合干涉装置, 测量到该纠缠双光子对的干涉可见度约为42%, 表明其频率不可分特性较理想频率一致纠缠光源大大降低. 通过理论分析给出, 由于超短脉冲光源对应的宽频谱带宽影响, 相位匹配函数中的高阶色散项不再忽略, 从而导致纠缠光子对的频率不可分性减弱. 进一步利用实验参数给出的数值模拟结果与实验结果符合, 证实了脉冲抽运源带宽对频率一致纠缠光源的量子不可分特性的影响. 关键词： 频率一致纠缠 Hong-Ou-Mandel干涉测量 符合计数     

通信波长频率一致纠缠光源的频谱测量

本文利用光栅单色仪实现了对超短脉冲抽运周期极化磷酸氧钛钾晶体产生的通信波长频率一致纠缠光子源的频谱特性分析.测量到双光子的联合频谱呈正关联分布,为频率一致纠缠光源.信号光、闲置光中心波长分别为1574.4 nm和1574.9 nm,频谱宽度分别为35.3 nm和37.6 nm,双光子符合包络宽度约为3 nm.根据单光子频谱宽度与双光子符合包络宽度的比值可以得到双光子的频率纠缠参量R约为12,表征了信号光子与闲置光子之间具有较高的频率纠缠度.     

利用共振无源腔分析和抑制飞秒脉冲激光噪声的理论和实验研究

理论分析了共振无源腔对飞秒脉冲激光的强度和相位噪声的转化模型,分析表明,通过测量无源腔透射场或者反射场相对于输入场强度噪声的变化,可以间接得到输入场飞秒脉冲激光的相位噪声.在此基础上设计了精细度约为1500、自由光谱区为75 MHz的八镜环形共振无源腔,并测量了钛宝石锁模激光经过该共振无源腔后透射场和反射场强度噪声的变化.实验观察到,飞秒脉冲激光经过无源腔透射后,强度噪声特性得到较好改善,在探测频率2 MHz附近达到散粒噪声极限.同时,结合共振无源腔对激光强度和相位噪声的转化模型,间接给出了钛宝石锁模激光的相位噪声及无源腔对相位噪声的有效抑制作用.