首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   152083篇
  免费   32161篇
  国内免费   10995篇
化学   123879篇
晶体学   1429篇
力学   9261篇
综合类   631篇
数学   15162篇
物理学   44877篇
  2024年   663篇
  2023年   5413篇
  2022年   5083篇
  2021年   6475篇
  2020年   8370篇
  2019年   6439篇
  2018年   5637篇
  2017年   4047篇
  2016年   10376篇
  2015年   10180篇
  2014年   10789篇
  2013年   12876篇
  2012年   12807篇
  2011年   11139篇
  2010年   9960篇
  2009年   9677篇
  2008年   7856篇
  2007年   7010篇
  2006年   5815篇
  2005年   4878篇
  2004年   3625篇
  2003年   2836篇
  2002年   2563篇
  2001年   2110篇
  2000年   1846篇
  1999年   2166篇
  1998年   1896篇
  1997年   1840篇
  1996年   2007篇
  1995年   1673篇
  1994年   1560篇
  1993年   1395篇
  1992年   1174篇
  1991年   1062篇
  1990年   855篇
  1989年   647篇
  1988年   579篇
  1987年   482篇
  1986年   455篇
  1985年   420篇
  1984年   348篇
  1977年   337篇
  1976年   397篇
  1975年   488篇
  1974年   516篇
  1972年   387篇
  1971年   375篇
  1970年   554篇
  1969年   437篇
  1968年   466篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
101.
Letk and s be two positive integers with s≥3. LetG be a graph of ordernsk. Writen =qk + r, 0 ≤rk - 1. Suppose thatG has minimum degree at least (s - l)k. Then G containsk independent cyclesC 1,C 2,...,C k such thatsl(C i ) ≤q for 1 ≤ir arndsl(C i ) ≤q + 1 fork -r <ik, where l(Ci) denotes the length ofC i .  相似文献   
102.
The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and 13C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (Tg) for the in situ blends, contrary to an increase of Tg with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007  相似文献   
103.
All-optical wavelength conversion of 10-Gb/s signal based on four-wave mixing is experimentally demonstrated in a 30-m-long dispersion-flattened microstructure fiber with small positive dispersion. For an average pump power of 26 dBm, the conversion efficiency was around -19.5 dB with the fluctuation less than ±1.4 dB, covering a conversion bandwidth of 20 nm. The eye diagram of the converted signal shows good eye opening.  相似文献   
104.
The aim of this paper is to investigate the asymptotic behavior of solutions for a class of three-species predator-prey reaction-diffusion systems with time delays under homogeneous Neumann boundary condition. Some simple and easily verifiable conditions are given to the rate constants of the reaction functions to ensure the convergence of the time-dependent solution to a constant steady-state solution. The conditions for the convergence are independent of diffusion coefficients and time delays, and the conclusions are directly applicable to the corresponding parabolic-ordinary differential system and to the corresponding system without time delays.  相似文献   
105.
Amphiphilic diblock copolymer polycaprolactone‐block‐poly(glycidyl methacrylate) (PCL‐b‐PGMA) was synthesized via enzymatic ring‐opening polymerization (eROP) and atom transfer radical polymerization (ATRP). Methanol first initiated eROP of ?‐caprolactone (?‐CL) in the presence of biocatalyst Novozyme‐435 under anhydrous conditions. The resulting monohydroxyl‐terminated polycaprolactone (PCL–OH) was subsequently converted to a bromine‐ended macroinitiator (PCL–Br) for ATRP by esterification with α‐bromopropionyl bromide. PCL‐b‐PGMA diblock copolymers were synthesized in a subsequent ATRP of glycidyl methacrylate (GMA). A kinetic analysis of ATRP indicated a living/controlled radical process. The macromolecular structures were characterized for PCL–OH, PCL–Br, and the block copolymers by means of nuclear magnetic resonance, gel permeation chromatography, and infrared spectroscopy. Differential scanning calorimetry and wide‐angle X‐ray diffraction analyses indicated that the copolymer composition (?‐CL/GMA) had a great influence on the thermal properties. The well‐defined, amphiphilic diblock copolymer PCL‐b‐PGMA self‐assembled into nanoscale micelles in aqueous solutions, as investigated by dynamic light scattering and transmission electron microscopy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5037–5049, 2007  相似文献   
106.
In this research, a simple, sensitive chemiluminescence (CL) method for the determination of humic acid (HA) in water samples was first developed based on the redox reaction between humic acid and cerium(IV) in the acidic condition. Different with the former redox CL reaction which occurred in alkaline solution, no enhancers were needed and neither precipitation nor a second contamination would occur in the present CL system. Comparing with other spectrometric methods, we find that the proposed analysis system had better applicability and accuracy. Under the optimal experiment conditions, the CL peak height was linear with the concentration of HA in the range of 0.03 to 10.0 microg mL(-1). The detection limit is 0.01 microg mL(-1) (S/N = 3), and the relative standard deviation was 2.3% for 0.5 microg mL(-1) HA solution with eleven repeated measurements. The present CL method was successfully applied to the determination of HA in tap water, spring water and river water samples with good recovery from 90.0 to 110.0%. A possible CL mechanism was proposed based on the results of UV and fluorescence spectrometry and the CL spectrum of HA. It was speculated that the semi-quinone radicals in the excited state were the emitters.  相似文献   
107.
For any Sturm-Liouville problem with a separable boundary condition and whose leading coefficient function changes sign (exactly once), we first give a geometric characterization of its eigenvalues λn using the eigenvalues of some corresponding problems with a definite leading coefficient function. Consequences of this characterization include simple proofs of the existence of the λn's, their Prüfer angle characterization, and a way for determining their indices from the zeros of their eigenfunctions. Then, interlacing relations among the λn's and the eigenvalues of the corresponding problems are obtained. Using these relations, a simple proof of asymptotic formulas for the λn's is given.  相似文献   
108.
针对一般的非线性规划问题,利用某些Lagrange型函数给出了一类Lagrangian对偶问题的一般模型,并证明它与原问题之间存在零对偶间隙.针对具体的一类增广La- grangian对偶问题以及几类由非线性卷积函数构成的Lagrangian对偶问题,详细讨论了零对偶间隙的存在性.进一步,讨论了在最优路径存在的前提下,最优路径的收敛性质.  相似文献   
109.
110.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号