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71.
M. T. Viciosa J. Quiles Hoyo M. Dionísio J. L. Gómez Ribelles 《Journal of Thermal Analysis and Calorimetry》2007,90(2):407-414
Temperature modulated differential scanning calorimetry (TMDSC) is used to study the kinetics of the free radical isothermal polymerization of triethyleneglycol dimethacrylate (TEGDMA). Azo-bis-isobutironitrile was used as initiator. The polymerization’s temperature is lower than the final glass transition temperature of the polymer network. The measurement of the average heat flow released and the heat capacity during the reaction allows identifying the different stages of the reaction. The presence of double peaks in the heat flow is ascribed to the autoacceleration. The influence of temperature, measuring conditions and oxygen are described. Vitrification is detected by the drop in heat capacity. It occurs at increasing conversion rates for increasing temperatures. After vitrification, the diffusion-controlled reaction continues. 相似文献
72.
In recent publications, it has been shown that high-order harmonic generation can be manipulated by employing a time delayed attosecond-pulse train superposed to a strong, near-infrared laser field. It is an open question, however, which is the most adequate way to approximate the attosecond-pulse train in a semianalytic framework. Employing the strong-field approximation and saddle-point methods, we make a detailed assessment of the spectra obtained by modeling the attosecond-pulse train by either a monochromatic wave or a Dirac-Delta comb. These are the two extreme limits of a real train, which is composed by a finite set of harmonics. Specifically, in the monochromatic limit, we find the downhill and uphill sets of orbits reported in the literature, and analyze their influence on the high-harmonic spectra. We show that, in principle, the downhill trajectories lead to stronger harmonics, and pronounced enhancements in the low plateau region. These features are analyzed in terms of quantum interference effects between pairs of quantum orbits, and compared to those obtained in the Dirac-Delta limit. 相似文献
73.
We continue the studies on the so–called genuine Bernstein–Durrmeyer operators U
n
by establishing a recurrence formula for the moments and by investigating the semigroup T(t) approximated by U
n
. Moreover, for sufficiently smooth functions the degree of this convergence is estimated. We also determine the eigenstructure
of U
n
, compute the moments of T(t) and establish asymptotic formulas.
Received: January 26, 2007. 相似文献
74.
Hubert de Fraysseix 《Discrete Applied Mathematics》2007,155(9):1079-1095
Using a general resolution of barycentric systems we give a generalization of Tutte's theorem on convex drawing of planar graphs. We deduce a characterization of the edge coverings into pairwise non-crossing paths which are stretchable: such a system is stretchable if and only if each subsystem of at least two paths has at least three free vertices (vertices of the outer face of the induced subgraph which are internal to none of the paths of the subsystem). We also deduce that a contact system of pseudo-segments is stretchable if and only if it is extendible. 相似文献
75.
Ivan Nunes da Silva Wagner Caradori do AmaralLucia Valeria de Arruda 《Applied Mathematical Modelling》2007
This paper presents an efficient approach based on recurrent neural network for solving nonlinear optimization. More specifically, a modified Hopfield network is developed and its internal parameters are computed using the valid subspace technique. These parameters guarantee the convergence of the network to the equilibrium points that represent an optimal feasible solution. The main advantage of the developed network is that it treats optimization and constraint terms in different stages with no interference with each other. Moreover, the proposed approach does not require specification of penalty and weighting parameters for its initialization. A study of the modified Hopfield model is also developed to analyze its stability and convergence. Simulation results are provided to demonstrate the performance of the proposed neural network. 相似文献
76.
Detection of hepatocarcinoma in rats by integration of the fluorescence spectrum: Experimental model
J. C. Marcassa J. Ferreira S. Zucoloto O. de Castro e Silva Jr. L. G. Marcassa V. S. Bagnato 《Laser Physics》2006,16(5):827-832
The incorporation of spectroscopic techniques into diagnostic procedures may greatly improve the chances for precise diagnostics. One promising technique is fluorescence spectroscopy, which has recently been used to detect many different types of diseases. In this work, we use laser-induced tissue fluorescence to detect hepatocarcinoma in rats using excitation light at wavelengths of 443 and 532 nm. Hepatocarcinoma was induced chemically in Wistar rats. The collected fluorescence spectrum ranges from the excitation wavelength up to 850 nm. A mathematical procedure carried out on the spectrum determines a figure of merit value, which allows the detection of hepatocarcinoma. The figure of merit involves a procedure which evaluates the ratio between the backscattered excitation wavelength and the broad emission fluorescence band. We demonstrate that a normalization allowed by integration of the fluorescence spectra is a simple operation that may allow the detection of hepatocarcinoma. 相似文献
77.
M. A. Rizzutto N. Added M. H. Tabacniks F. R. Espinoza-Qui?ones S. M. Palacio R. M. Galante R. M. Galante N. Rossi R. A. Welter A. N. Módenes 《Journal of Radioanalytical and Nuclear Chemistry》2006,269(3):727-731
Summary Kulcsszavak (angolul, ha nem azonos az elozovel) 相似文献
78.
Rafael Tiedra de Aldecoa 《Annales Henri Poincare》2006,7(1):105-124
Although many physical arguments account for using a modified definition of time delay in multichannel-type scattering processes,
one can hardly find rigorous results on that issue in the literature. We try to fill in this gap by showing, both in an abstract
setting and in a short-range case, the identity of the modified time delay and the Eisenbud-Wigner time delay in waveguides.
In the short-range case we also obtain limiting absorption principles, state spectral properties of the total Hamiltonian,
prove the existence of the wave operators and show an explicit formula for the S-matrix. The proofs rely on stationary and commutator methods.
Communicated by Yosi Avron
submitted 12/04/05, accepted 13/05/05 相似文献
79.
Zbigniew Jaskólski 《Communications in Mathematical Physics》1991,139(2):353-375
Following the general scheme of the convariant path integral quantization of gauge systems, two alternative formulations of
the first quantized closed bosonic string in a position representation are presented. In both approaches the covariant path
integral representations of the propagator and of the higher order off-shell amplitudes are constructed. For a wide class
of gauges the explicit formulae for off-shell amplitudes are obtained. This paper is the continuation of our previous work
where the corresponding problems in the open string case were considered [20]. 相似文献
80.
Venzo de Sabbata P. I. Pronin C. Sivaram 《International Journal of Theoretical Physics》1991,30(12):1671-1678
We consider the possibility of finding experimental evidence of the fifth force with the measurement of a phase shift of neutron beams via an interferometric apparatus and also a possible rotation of the polarization plane of polarized neutron beams when torsion is introduced in a gravitational field. 相似文献