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941.
The C2H4 was investigated ab initio for the equilibrium distance of the centers, taking all 16 electrons into account, using the Allgemeines Programmsystem/SCF ? MO ? LC (LCGO ) Methode. A total energy of ?76.77 a.u. and an ionization energy of 10.55 eV were found. 相似文献
942.
Studies on Oxide Catalysts. XXIX. Spectroscopic and Catalytic Investigations on Ni2+-, Co2+-, Cr3+-, and Cu2+-exchanged Mordenites NiNaM, CoNaM, CrNaM und CuNaM (M = Mordenite) have been characterized by UV-VIS, EPR and i.r. spectroscopy and the results were compared with the catalytic activity and the activity-time-dependence in the cracking of n-octane and with the shape selectivity in the cracking of a n-octane and isooctane mixture. Water molecules acting as ligands of the exchanged cations are able to dissociate yielding Brönsted acidity. Brönsted sites may be regarded as catalytic active centers in the cracking reaction. Unreduced transition metal cations facilitate the “coking” of the mordenite. The unreduced chromium and cobalt cations for which a position within the main channel is expected, affect the diffusion of the branched paraffin molecule thus increasing shape selectivity. 相似文献
943.
Exposure of ent-kaura-2,16-dien-19-ol (1) or its succinate (2) to resuspended mycelia of G. fujikuroi has produced a complex mixture of acids which after methylation gave the esters of two C19 (24) and (30) and five C20 gibberellins (4, 11, 20, 32 and 33). The triester (32) and the lactone ester (24) have been prepared before from the esters of gibberellin A13 (8) and gibberellin A4 (26) respectively. The structures of the other metabolites were assigned on spectroscopic data and by chemical transformations. Thus the lactone diester (4) has been converted to the known keto triester (6). The epoxide (11) has been related to gibberellin A14 (14) and the aldehyde (33) has been related to gibberellin A13 trimethyl ester (8) by way of the triol (34). Selective de-epoxidation of the 16,17-epoxy function in diepoxides has provided a route from the dienes (20 and 24) to the epoxides (11 and 30) respectively, but not from the ester of gibberellin A5 (23) to that of gibberellin A6 (29). On the other hand the latter can be obtained by epoxidation of gibberellin A5 methyl ester trifluoroacetate. Backfeeding experiments carried out with the epoxy diacid (12), the diene diacid (21) and the derived diol (39) indicate pathways connecting the various metabolites. The natural gibberellins A5 and A6 were shown to be formed in some of the backfeeding experiments. 相似文献
944.
RECOVERY OF HAEMOPHILUS INFLUENZAE FROM ULTRAVIOLET AND X-RAY DAMAGE 总被引:14,自引:0,他引:14
Abstract— Results of experiments on reactivation of ultraviolet (u.v.)-irradiated Haemophilus influenzae and cellular reactivation of u.v.-damaged transforming deoxyribonucleic acid (DNA) and bacteriophage are reported. Liquid-holding recovery (LHR) is small for the u.v.-sensitive mutant BC100 which, relative to the wild type, also has greatly reduced host-cell reactivation (HCR) of u.v.-inactivated phage, and competent cultures show reduced competent cell reactivation (CCR) of u.v.-inactivated transforming DNA. BC100 cells can be transformed with DNA isolated from the wild type strain Rd to a u.v. resistance similar to that of Rd, and irradiation of the DNA reduces the transformation frequency for this marker (uvr). The u.v.-resistant mutant BC200 displays very little LHR under the usual conditions where reactivation occurs after plating. The colony-forming ability (cfa) of irradiated BC200 is greater than that of Rd, but HCR and CCR are the same on this mutant as on the wild type. The major difference between Rd and BC200 is the enhanced u.v. survival of cfa of the latter. It was determined that this difference reflects cell lysis of irradiated Rd and lack of lysis in BC200 cultures. That lysis is closely correlated with damage to the bacterial chromosome is suggested by the finding that the lytic response of Rd (as determined turbidimetrically) can be negated by the liquid-holding procedure, but lysis of BC100 (which lacks comparable DNA-repair ability) can be only partially inhibited by this procedure. LHR occurs when post-plating dark recovery is incomplete, is temperature-sensitive, and occurs unimpeded when post-u.v. protein synthesis is inhibited by chloramphenicol. It is suggested that enzymatically catalyzed reactivation of DNA occurs or is initiated during liquid-holding of u.v.-irradiated H. influenzae Rd and that the necessary enzyme(s) exists prior to appearance of u.v. lesions in the DNA. Results are reported for X-ray inactivation of transforming DNA as assayed on BC100, Rd and BC200 and of the cfa of the three strains. 相似文献
945.
β-Aminocrotonic esters are of great importance as stabilizers for the production of clearly transparent food packaging of PVC. For the purpose of studying the migration into foods a thin-layer Chromatographic and a polarographic method were elaborated. The TLC method consists of the visual comparison of the intensity of the spots after treatment with Fast Blue B salt. The polarographic determination is carried out after nitrosation of the stabilizer. By the TLC method 10?7 g of ester per spot are still detectable; the concentration which is still determinable by cathode-ray polarography is 5×10?7 g of ester and by conventional d.c. polarography 5×10?6g of ester per ml of final solution. After extraction with acetonitrile traces of the stabilizer which are migrated into edible oil are still determinable down to 2 ppm by the methods described. 相似文献
946.
A simple method for the determination of molybdenum and tungsten in sea and surface water is presented. Molybdenum and tungsten are concentrated on activated charcoal by adsorption as the ammonium pyrrolidine dithiocarbamate complex; the optimal pH for adsorption is 1.3. Mo and W are then determined by thermal neutron activation, forming 99Mo (T = 66.7 h) and 137W (T = 23.8 h), respectively. The 99mTc daughter of 99Mo is measured as soon as the equilibrium between 99mTc(T= 6 h) and 99Mo is established. The detection limits are 0.05 μg Mo l-1 and 0.05 μg W l-1 (or 0.001 μg W l-1 after a simple chemical separation). 相似文献
947.
The fractional dissociation,32Γ, of 32SF6 by the output of a pulsed TEA CO2 laser has been found to depend upon Φ, the total integrated laser intensity, as 32Γ ∞ Φm for both the P(20) and P(16) laser lines, where m ≈ 3 in the range 2 < Φ < 7.2 J/cm2 and increases from 3 to ≈ 4 as Φ is reduced from 2 to 0.9 J/cm2. 相似文献
948.
H. Thurn 《Colloid and polymer science》1959,165(1):57-73
Zusammenfassung Nach einem kurzen, allgemeinen Überblick über die wichtigsten Gesetzmäßigkeiten, die das dielektrische und mechanische Relaxationsverhalten der Hochpolymeren bestimmen, werden die bisher bekannt gewordenen Änderungen der dielektrischen und mechanischen Verlustkurven bei thermischer und mechanischer Vorbehandlung an Hand von Beispielen erläutert. Es zeigt sich, daß das experimentelle Material vielfach noch nicht ausreicht, um die einander teilweise widersprechenden Ergebnisse in allen Fällen befriedigend deuten zu können. Im einzelnen werden behandelt: Veränderung der Hauptkettenbeweglichkeit bei den amorphen Hochpolymeren, Veränderungen bei den Nebenmaxima der amorphen und partiell-kristallinen Hochpolymeren, Veränderungen der amorphen und kristallinen Hauptmaxima bei den partiell-kristallinen Hochpolymeren und Zeiteffekte beim Kristallisieren.Dem Leiter der Meß- und Prüfabteilung,K. Wolf, sowie meinen KollegenH. Hendus, K. Schmieder, G. Schnell undF. Würstlin danke ich für anregende Diskussionen und die Erlaubnis, noch unveröffentlichte Messungen zu zitieren.
K. Wolf undK. Schmieder bin ich für die kritische Durchsicht des Manuskriptes zu besonderem Dank verpflichtet. 相似文献
949.
From a biogenetic point of view, a great variety of related alkaloids isolated from the plant Daphniphyllaceae are related to one another by bond formation or fission. Thus, daphnialcohol acetate (6), a derivative of the degradation products of daphniphylline (1), was subjected to von Braun degradation followed by acid-catalyzed recyclization to give an isomer (8) of daphnialcohol, which has a new type of nitrogen heterocyclic skeleton. Furthermore, daphnilactone-B (3) was converted into a daphniphylline-type compound (19) via a plausible intermediate (21). 相似文献
950.
Studies of the application of an 8-hydroxyquinoline extraction and of a zinc oxide “collection” procedure for the separation of trace amounts of indium from zinc alloys are described and discussed. A combination of radio-chemical and polarographic determination were employed for this work. A polarographic method for the determination of indium in zinc and in zinc alloys of low aluminium content is presented 相似文献