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101.
Three new derivatives of dithizone are reported, with their electronic and i.r. spectra, acidity constants and partition coefficients between 0.5 M sodium perchlorate and chloroform or carbon tetrachloride. The extraction equilibria with Cd, Co(II), Hg(II), Ni, Pb, Tl(I), Zn and Bi and the spectrophotometric characteristics of the extractable metal chelates are described. Complete extraction of these complexes requires higher pH than that needed with dithizone itself. The 4,4′-dichloroisomer is more efficient than the 3,3′ and 5,5′-isomers, or dithizone itself, for the separation of cadmium from zinc or cobalt from nickel. 相似文献
102.
Fatma Taşdelen Ali Olgun Gülen Başcanbaz-Tunca 《Proceedings Mathematical Sciences》2007,117(3):387-399
We introduce certain linear positive operators and study some approximation properties of these operators in the space of
functions, continuous on a compact set, of two variables. We also find the order of this approximation by using modulus of
continuity. Moreover we define an rth order generalization of these operators and observe its approximation properties. Furthermore, we study the convergence
of the linear positive operators in a weighted space of functions of two variables and find the rate of this convergence using
weighted modulus of continuity. 相似文献
103.
smet Kaya Fatma Moral Didem Erdener 《Journal of polymer science. Part A, Polymer chemistry》2004,42(11):2717-2724
The reaction conditions of the oxidative polycondensation of 2‐[(pyridine‐2‐yl‐methylene) amino] phenol (2‐PMAP) with air O2, H2O2, and NaOCl were studied in an aqueous alkaline medium between 60 and 90 °C. Oligo‐2‐[(pyridine‐2‐yl‐methylene) amino] phenol (O‐2‐PMAP) was characterized with 1H NMR, Fourier transform infrared, ultraviolet–visible, size exclusion chromatography (SEC), and elemental analysis techniques. Moreover, solubility testing of the oligomer was performed in polar and nonpolar organic solvents. With the NaOCl, H2O2, and air O2 oxidants, the conversions of 2‐PMAP into O‐2‐PMAP were 98, 87, and 62%, respectively, in an aqueous alkaline medium. According to SEC, the number‐average molecular weight, weight‐average molecular weight, and polydispersity index of O‐2‐PMAP were 2262 g mol?1, 2809 g mol?1, and 1.24 with NaOCl, 3045 g mol?1, 3861 g mol?1, and 1.27 with air O2, and 1427 g mol?1, 1648 g mol?1, and 1.16 with air H2O2, respectively. Also, thermogravimetric analysis showed that O‐2‐PMAP was stable against thermooxidative decomposition. The weight loss of O‐2‐PMAP was 96.68% at 900 °C. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2717–2724, 2004 相似文献
104.
Ayça Tunçel Kasim Ocakoglu Suleyman Gokhan Colak Osman Yılmaz İsmail Öztürk Fatma Yurt 《Journal of Radioanalytical and Nuclear Chemistry》2018,315(3):487-492
Effective antimicrobial compounds are necessary due to increased resistance of antibiotics against microorganisms causing infectious diseases. In this study, imidazolium-TFSI salt [ITFSI: octyl-bis(3-methylimidazolium)-di(bis(trifluoromethane)sulfonimide)] was labeled with 131I with high efficiency. In vitro uptake experiments of 131I-ITFSI showed high uptake in gram-positive Staphylococcus aureus bacteria. 131I-ITFSI was also evaluated for comparison between bacterial infection and sterile inflammation by in vivo studies. The biodistribution results revealed that 131I-ITFSI might be used as a nuclear imaging agent for detection of bacterial infection. 相似文献
105.
Journal of Algebraic Combinatorics - We study those multiplicative subgroups of $${\mathbb F}_{2^n}^*$$ which are Sidon sets and/or sum-free sets in the group $$({\mathbb F}_{2^n},+)$$ . These... 相似文献
106.
This paper presents a chemometrics-assisted optimization study to improve the separation of tocopherol (-T) and tocotrienol (-TT) homologues on a C30 stationary phase in reversed-phase HPLC. The HPLC settings were optimized using a central composite design and the response surface methodology. Flow rate, column temperature, and mobile phase composition were chosen as independent variables. Peak resolution (Rs), analysis time (tR), and peak symmetries of the tocopherol isomers were chosen as response variables. Optimum performance in terms of Rs was obtained at a flow rate of 0.31 mL min?1, a temperature of 8.70 °C, and % B content (methyl tert-butyl ether: methanol: water, 80:18:2, v/v/v) in the mobile phase of 38.12%. The analysis of variance and regression analysis gave adjusted R2 values of 0.9841 for Rs, 0.9850 for tR-(α-T), 0.9853 for tR-(β-T), and 0.9204 for the peak symmetry of β-T. This confirms the good agreement of experimental data with predicted values. The close eluting peaks of β-/γ-tocol could be baseline separated at the optimized conditions at a minimized analysis time. Empirical second-order polynomial models were derived that gave statistically high significances (P?<?0.0001). Hence, the models can be successfully employed to predict the optimum separation conditions of co-eluting peaks of β-/γ-tocols. The optimized method was successfully applied to determine the individual tocol homologues in various cold pressed edible oils. Total contents ranged from 15 to almost 2600 mg tocol kg?1 oil. 相似文献
107.
Aïcha Arfaoui Fatma Saâdi Asma Bourafai Aziez Hammouda Chebbi Catherine Fressigné Julien Legros 《合成通讯》2018,48(6):705-713
An efficient coupling reaction of allyl bromides with various alcohols as nucleophiles activated by triethylamine, leading to functionalized vinyl ethers in good yields and with full stereoselectivity. 相似文献
108.
Balram P. Baranwal Talat Fatma Rinkoo D. Gupta Tarkeshwar Gupta 《Transition Metal Chemistry》2007,32(4):501-506
Oxo-centered, trinuclear, mixed-ligand complexes of chromium(III) have been synthesized by stepwise substitutions of acetate
ions of [Cr3O(OOCMe)4(OOCR)3] · 3MeOH (1) and the isolated products of the type [Cr3O(OOCMe)2 (SB)(OOCR)3]PF6 · 3MeOH (2), [Cr3O(OOCMe)(SB)2(OOCR)3]PF6 · 3MeOH (3) and [Cr3O(SB)3(OOCR)3]PF6 · 3MeOH (4) [where R = C13H27 and HSB = C6H4(OH)CHNC6H4Cl] have been characterized by a full battery of complementary physico–chemical methods including spectral (infrared, electronic,
FAB mass and powder XRD) studies, elemental and thermogravimetric analyses, molar conductance and magnetic susceptibility
measurements. The infrared spectra suggest the bridging nature of both carboxylate and Schiff base anions along with ν
asym(Cr3O) vibrations in the complexes. The trinuclear nature of the complexes has been assessed from FAB mass data. Electronic spectra
and magnetic moment values were consistent with chromium(III) ion present in an octahedral environment which was supported
by their powder X-ray diffraction data. Cyclic voltammetric data of complex (4) indicate a reversible oxidation wave and an irreversible reduction wave in the range − 1.2–0.6 V. The decomposition pathway
of all the complexes has been discussed on the basis of thermogravimetric analysis data. Conductance data indicate the monocationic
nature of the complexes and their plausible structure has been established on the basis of above physico–chemical studies. 相似文献
109.
A photocatalytic degradation method was developed for polychlorobiphenyl (PCB) and organochloride pesticide (OCP) discrimination and quantification. A mixture of Aroclor 1260 and p,p′-DDT was irradiated at 254 nm by UV lamp (40 W) in the presence of TiO2 (30 mg mL−1 non-aqueous solution). Comparison of gas chromatograms showed that p,p′-DDT signals decreased significantly after irradiation, while Aroclor 1260s chromatograms did not show any difference before and after irradiation. Detection limits were 0.30 mg L−1 and 0.15 mg L−1 for p,p′-DDT and Aroclor 1260, respectively. The method was applied to spiked egg samples, the recoveries were found as 72% for DDT and 82.01% for Aroclor 1260. 相似文献
110.
A method was described for the determination of the elements Cr, Mn, Fe, Co, Ni, Cu, Cd, Pb, and Bi in waters by flame atomic absorption spectrometry (FAAS) after separation and preconcentration on Amberlite XAD-16 resin with sodium tetraborate using a chromatographic column. Parameters influencing the analytical performance, including pH and the volume of sample, amount of analyte and interfering effect of co-existing ions, were studied in detail. The recovery values were quantitative (> or = 95%), and the relative standard deviation (RSD) and detection limit (DL) varied in the range of 1.1-2.4% (n=10) and 0.002-0.177 microg m(-1) (3s, n=20), respectively. After being optimized, the proposed method was applied to the drinking water, waste water and artificial sea water samples. Recovery values of the elements investigated, were quantitative for tap water and synthetic sea water, except for Mn, Co and Ni (including also Cd for synthetic sea water). Recovery values of Cd, Pb, Cu and Co were found to be 95, 102, < or = 87, and < or = 83%, respectively, for the waste water samples. 相似文献