Muhammad Saeed  Aswa Firdous  Muhammad Saleh Zaman  Fatima Izhar  Mubeshar Riaz  Sabah Haider  Muzamil Majeed  Shahzaib Tariq 《中国化学会会志》2023,70(4):789-824

Nowadays, desulfurization of fuel oil has raised concern globally because of strict industrial and environmental legislations. Albeit hydrodesulfurization (HDS) has been extensively used in oil refineries to produce low sulfur oil (< 10 ppm) but not been proven as effective method for the removal of dibenzothiophene (DBT), benzothiophene (TH) and their derivatives. Subsequently, adsorptive desulfurization (ADS) and oxidative desulfurization (ODS) methods have been developed to achieve high removal efficiency. In the past decade, metal–organic frameworks (MOFs) and its composites as oxidative catalysts, as well as adsorbents, have attracted the researchers owing to high surface area, tunable properties, and reusable. The present review comprises use of MOFs and their composites for the removal of sulfur from fuel oil via ODS and ADS processes. Additionally, physicochemical properties of MOFs, mechanism, pros and cons of both process, regeneration, and future challenges have been discussed briefly. Moreover, current limitations and future prospective are also discussed.  相似文献   

    

Fatima Doganc;Hakan Göker; 《Magnetic resonance in chemistry : MRC》2024,62(11):765-774

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Fatima Ijaz  Syed Salman Shafqat  Hafiz Adnan Ahamd  Munawar Ali Munawar  Misbahul Ain Khan 《Journal of heterocyclic chemistry》2019,56(4):1231-1238

Derivatives of ninhydrin are extensively used in the field of forensic sciences as important latent fingerprint reagents. Many works have been performed upon their synthesis and reactivity, but there are many spaces to work on the compounds of quinoline‐2,3,4(1H)‐triones—analogues of ninhydrin, in both dimensions: synthesis and reactivity, and according to the best of our knowledge, not a single detailed or short compiled article has been published for these compounds. This review briefly summarizes the chemistry of quinoline‐2,3,4(1H)‐triones.  相似文献   

    

Annemarie Marckwordt  Fatima El&#x;Ouahabi  Hadis Amani  Sergey Tin  Narayana V. Kalevaru  Paul C. J. Kamer  Sebastian Wohlrab  Johannes G. de&#x;Vries 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(11):3524-3528

Use of ZrO₂/SiO₂ as a solid acid catalyst in the ring‐opening of biobased γ‐valerolactone with methanol in the gas phase leads to mixtures of methyl 2‐, 3‐, and 4‐pentenoate (MP) in over 95 % selectivity, containing a surprising 81 % of M4P. This process allows the application of a selective hydroformylation to this mixture to convert M4P into methyl 5‐formyl‐valerate (M5FV) with 90 % selectivity. The other isomers remain unreacted. Reductive amination of M5FV and ring‐closure to ?‐caprolactam in excellent yield had been reported before. The remaining mixture of 2‐ and 3‐MP was subjected to an isomerising methoxycarbonylation to dimethyl adipate in 91 % yield.  相似文献   

    

Dr. Jakob-Jonathan Maudrich  Max Widemann  Fatima Diab  Ralf H. Kern  Dr. Peter Sirsch  Dr. Christian P. Sindlinger  Dr. Hartmut Schubert  Prof. Dr. Lars Wesemann 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(70):16081-16087

Organodihydridoelement anions of germanium and tin were reacted with metallocene dichlorides of Group 4 metals Ti, Zr and Hf. The germate anion [Ar*GeH₂]⁻ reacts with hafnocene dichloride under formation of the substitution product [Cp₂Hf(GeH₂Ar*)₂]. Reaction of the organodihydridostannate with metallocene dichlorides affords the reduction products [Cp₂M(SnHAr*)₂] (M=Ti, Zr, Hf). Abstraction of a hydride substituent from the titanium bis(hydridoorganostannylene) complex results in formation of cation [Cp₂M(SnAr*)(SnHAr*)]⁺ exhibiting a short Ti–Sn interaction. (Ar*=2,6-Trip₂C₆H₃, Trip=2,4,6-triisopropylphenyl).  相似文献   

    

Abdulmumeen A. Hamid  Olapeju O. Aiyelaagbe  Arvind S. Negi  Fatima Kaneez  Suaib Luqman  Stephen O. Oguntoye 《Natural product research》2019,33(2):296-301

Chloroform extract from the leaves of Turraea vogelii Hook f. ex Benth demonstrated cytotoxic activity against a chronic myelogenous leukemia cell, K-562 with IC₅₀ of 14.27 μg/mL, while chloroform, ethyl acetate and methanol extracts from the stem of the plant inhibited K-562 cells growth with IC₅₀ of 19.50, 24.10 and 85.40 μg/mL respectively. Bioactive chloroform extract of Turraea vogelii leaves affords two triterpenoids: oleana-12,15,20-trien-3β-ol (1), and oleana-11,13-dien-3β,16α,28-triol (2), with six fatty esters, ethyl hexaeicos-5-enoate (3), 3-hydroxy-1,2,3-propanetriyltris(tetadecanoate) (4), 1,2,3-propanetriyl(7Z,7′Z,7′′Z)tris(-7-hexadecenoate) (5), 1,2,3-propanetriyl(5Z,5′Z,5′′Z)tris(-5-hexadecenoate) (6), 1,2,3-propanetriyltris(octadecanoate) (7), and 2β-hydroxymethyl tetraeicosanoate (8). Tetradecane (9), four fatty acids: hexadecanoic acid (10), tetradecanoic acid (11), (Z)-9-eicosenoic acid (12), and ethyl tetradec-7-enoate (13) were isolated from chloroform extract of Turraea vogelii stem. 1,2,3-propanetriyltris(heptadecanoate) (14), (Z)-9-octadecenoic acid (15) and (Z)-7-tetradecenoic acid (16) were isolated from ethyl acetate extract while (Z)-5-pentadecenoic acid (17) was obtained from methanol extract of the plant stem. Compounds 1, 2, 5, 6, 11, 12, 15, 16 and 17 exhibited pronounced antiproliferative activity against K-562 cell lines.  相似文献   

    

Itidal Belaidi  Fatima Khelfaoui  Nadhir Attaf  Assia Azzizi  Mohammed Salah Aida 《physica status solidi (a)》2019,216(22)

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Qinghua Wang  Bingtao Gao  Michaella Raglione  Huixin Wang  Baojia Li  Fatima Toor  Mark A. Arnold  Hongtao Ding 《Laser u0026amp; Photonics Reviews》2019,13(11)

Development of terahertz (THz) sources, detectors, and optical components has been an active area of research across the globe. The interest in THz optoelectronics is driven by the various applications they have enabled, such as ultrawide‐band communication systems, air‐ and space‐borne astronomy, atmospheric monitoring, small‐scale radar, airport security scanners, ultrafast nanodevices, and biomedical imaging and sensing. Here, the aim is to provide a comprehensive review of THz bandpass metamaterials focusing on several areas. First, the design fundamentals and geometrical patterns of THz bandpass metamaterials are summarized. Second, fabrication methods of THz bandpass metamaterials are reviewed, including typical micro‐ and nanofabrication techniques and laser micromachining techniques. More importantly, different engineering methods are reviewed for tuning and modulation of the THz transmission resonance for these metamaterials. Both passive and active modulation methods are included in this discussion; the passive method involves changes in the geometrical pattern of the filter material, and the active method performs in situ modulation of properties by applying an external physical field. Finally, the potential applications and prospects for future research of THz bandpass metamaterials are discussed.  相似文献   

    

Vinicius O. Aguiar  Maria de Fatima V Marques 《Macromolecular Symposia》2018,381(1):1800122

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Sadia Naureen  Fatima Ijaz  Areesha Nazeer  Faryal Chaudhry  Munawar Ali Munawar  Misbahul Ain Khan 《合成通讯》2017,47(16):1478-1484

An efficient, convenient green approach for the synthesis of indole-based 2,4,5-trisubstituted and 1,2,4,5-tetrasubstituted imidazoles by multicomponent reaction of substituted 2-arylindole-3-carbaldehydes, benzil, substituted anilines, and ammonium acetate using catalytic amino acid (glycine) in ethanol is described. Several amino acids have also been evaluated as organic catalysts for these reactions. The structures of the compounds have been established on the basis of infrared, mass, and ¹H NMR spectral data. The mild reaction conditions, inexpensive/economical reagents, and good yield show the usefulness of this approach.  相似文献