全文获取类型
收费全文 | 937篇 |
免费 | 48篇 |
国内免费 | 23篇 |
专业分类
化学 | 848篇 |
晶体学 | 4篇 |
力学 | 20篇 |
数学 | 59篇 |
物理学 | 77篇 |
出版年
2024年 | 4篇 |
2023年 | 7篇 |
2022年 | 30篇 |
2021年 | 37篇 |
2020年 | 64篇 |
2019年 | 55篇 |
2018年 | 80篇 |
2017年 | 39篇 |
2016年 | 73篇 |
2015年 | 56篇 |
2014年 | 73篇 |
2013年 | 126篇 |
2012年 | 67篇 |
2011年 | 73篇 |
2010年 | 52篇 |
2009年 | 48篇 |
2008年 | 43篇 |
2007年 | 29篇 |
2006年 | 9篇 |
2005年 | 13篇 |
2004年 | 6篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 3篇 |
1999年 | 1篇 |
1994年 | 1篇 |
1991年 | 1篇 |
1986年 | 1篇 |
1985年 | 3篇 |
1976年 | 1篇 |
排序方式: 共有1008条查询结果,搜索用时 31 毫秒
991.
Yousef Fazaeli Amir R. Jalilian Mostafa M. Amini Ali Rahiminejad-kisomi Saeed Rajabifar Fatemeh Bolourinovin Sedigheh Moradkhani 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(1):17-24
[67Ga]labeled tetraphenyl porphyrin ([67Ga]-TPP) was prepared using freshly prepared [67Ga]GaCl3 and tetraphenyl porphyrin (TPPH2) for 30–60 min at 25 °C (radiochemical purity: >97 ± 1% ITLC, >98 ± 0.5% HPLC, specific activity: 13–14 GBq/mmol). Stability
of the complex was checked in final formulation and human serum for 24 h. The partition coefficient was calculated for the
compound (log P 1.89). The biodistribution of the labeled compound in vital organs of wild-type rats was studied using scarification studies
and SPECT imaging up to 24 h. A detailed comparative pharmacokinetic study performed for 67Ga cation and [67Ga]-TPP. The complex is mostly washed out from the circulation through kidneys and can be an interesting tumor imaging/targeting
agent due to low liver uptake and rapid excretion through the urinary tract. 相似文献
992.
Mehdi BazarganipourMinoo Sadri Fatemeh DavarMasoud Salavati-Niasari 《Polyhedron》2011,30(6):1103-1107
HgSe nanorods have been synthesized through a simple hydrothermal reduction approach. The nanorods formed were ≈45 nm average diameter and ≈3 μm nm in length. X-ray diffraction characterization suggested that the product consists of cubic phase pure HgSe. The as-prepared products were also characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). An X-ray energy dispersive spectroscopy (EDX) study further confirmed the composition and purity of the product. The synthesis procedure is simple and uses less toxic reagents than the previously reported methods. The results showed that the capping agent CTAB (cetyltrimethylammoniumbromide) plays a crucial role in the process. Other factors, such as the reaction time, temperature, different capping agent and the reductant type also have an influence on the morphology of the final products to some extent. 相似文献
993.
The activity of [Pd{C6H4(CH2N(CH2Ph)2)} (μ-Br)]2 complex was investigated in the Heck-Mizoroki C-C cross-coupling reaction. This complex is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides and also arenesulfonyl chlorides. The cross-coupled products were produced in excellent yields in short reaction time using a catalytic amount of [Pd{C6H4(CH2N(CH2Ph)2) (μ-Br)]2 complex in NMP at 130 °C. 相似文献
994.
A new method is presented for simultaneous preconcentration of trace Fe(III) and Cr(III) by using polyacrylic acid-alumina as a sorbent. The separation/preconcentration conditions of analytes were investigated, including effect of pH, flow rate, elution conditions, sample volume, and interfering ions. At pH 4, the maximum sorption capacities of Fe3+ and Cr3+ were 8.0 and 13.0 mg/g, respectively, by the column method. The linearity was maintained in the concentration range of 0.175-6.0 x 10(3) ng/mL for iron and 0.175-8.0 x 10(3) ng/mL for chromium in the original solution. The RSD values under optimum conditions were +/- 1.73 and +/- 1.28% for 2.0 microg/mL Fe and Cr, respectively. The preconcentration factor was 400 for both of the elements, and detection limits were 0.025 and 0.023 ng/mL for Fe and Cr in the original solutions. The proposed method was successfully applied to the determination of trace amounts of Fe and Cr in plant samples. 相似文献
995.
Fatemeh Abrishamian Shinichi Nagai Shinya Sato Masaaki Imai 《Optical and Quantum Electronics》2008,40(9):665-676
Spectral response of acoustically induced microbending through thin optical fiber is discussed from mode-coupling of core
and cladding modes. The thin fiber is analyzed in three-layered structure (core-cladding-air) to gain insights into acousto-optic
modulation. We explained the dependence of core and/or cladding diameters on acoustic source parameters from numerical calculations.
According to the calculations, we successfully fabricated all-optical tunable filter using this thin fiber that yields an
efficient mode-coupling at flexural wave frequencies less than 1MHz. To increase the acousto-optic effect, we used a specially
designed thin optical fiber (80 μm of cladding diameter) in the section where flexural wave is produced, and spliced both
ends of the thin fiber to the tapered 125 μm fibers. The frequency and voltage tuning of fabricated filter is also confirmed
by changing the driven frequency and applied voltage of the PZT, respectively. This result suggests a possibility of fiber-optic
device application as all-optical tunable filter at 1.55 μm. 相似文献
996.
Fatemeh Abrishamian 《Optics Communications》2008,281(13):3561-3566
We report results of experiments examining cross-phase modulation effect on fiber grating coupler (FGC). All-optical switching are observed in both cases of high pump pulses emitted from high-power Nd:YAG laser and mode-locked EDF laser. Based on coherent detection using a lock-in amplifier, the red-shift of the Bragg wavelength for a FGC was estimated to be 0.04-0.06 nm/1.5-1.7 kW peak power of EDF pump light at 1.55 μm. To avoid mixture of pump pulse and signal light at 1.55 μm, we have also performed the experiment using high power Nd:YAG laser as a pump power. For a Nd:YAG laser, the red-shift of Bragg wavelength is estimated to be 0.06 nm at maximum pump power of 2.1 kW. A simple model for the proposed detection scheme is given and the resultant red-shift is analyzed numerically. 相似文献
997.
A rapid and efficient one-pot method for the synthesis of 4,6-diarylpyrimidin-2(1H)-ones and related heterocycles is described. The condensation of acetophenone derivatives, aldehydes and urea in the presence of sulfamic acid was employed to synthesize a variety of pyrimidinones in moderate to excellent yields. The scope and limitations of this method are described. 相似文献
998.
Fatemeh Ahangari 《理论物理通讯》2018,69(5):477-505
Problems of thermodynamic phase transition originate inherently in solidification, combustion and various other significant fields. If the transition region among two locally stable phases is adequately narrow, the dynamics can be modeled by an interface motion. This paper is devoted to exhaustive analysis of the invariant solutions for a modified Kuramoto-Sivashinsky equation in two spatial and one temporal dimensions is presented. This nonlinear partial differential equation asymptotically characterizes near planar interfaces, which are marginally long-wave unstable. For this purpose, by applying the classical symmetry method for this model the classical symmetry operators are attained.Moreover, the structure of the Lie algebra of symmetries is discussed and the optimal system of subalgebras, which yields the preliminary classification of group invariant solutions is constructed. Mainly, the Lie invariants corresponding to the infinitesimal symmetry generators as well as associated similarity reduced equations are also pointed out. Furthermore,the nonclassical symmetries of this nonlinear PDE are also comprehensively investigated. 相似文献
999.
Parya?Siahcheshm Fatemeh?GoharpeyEmail author Reza?FoudaziView authors OrcID profile 《Rheologica Acta》2018,57(11):729-743
We studied the influence of nanoparticles with different surface modifications on the interfacial tension and relaxation of model polymer blend after cessation of different strains. The droplet retraction experiments were carried out on a model system composed of polydimethylsiloxane (PDMS) as the suspending fluid and polyisobutylene (PIB) as droplet at room temperature in the presence of hydrophobic and hydrophilic nanosilica. Different weight fractions of particles were dispersed in the PIB droplet before forming a dispersed droplet by using a microsyringe in shear cell. We found that applied strain, nanoparticle concentration and their thermodynamically preferred localization affect both nominal interfacial tension and droplet retraction process. By addition of nanoparticles at a concentration as low as 0.2%wt, the nominal interfacial tension decreases from 3.12?±?0.15 mN/m for neat PIB-PDMS interface depending on the surface characteristics of nanosilica. Hydrophilic nanosilica has the most effect on nominal interfacial tension and decreases it as low as 0.2?±?0.21 mN/m at 1 wt.% loading under a strain of 7. The results show that the retraction process in this system is mainly controlled by interfacial phenomena rather than bulk rheological properties. Additionally, the shape evolution of droplets changes and the retraction rate slows down in the presence of nanoparticles. 相似文献
1000.
Yaser Ghazi Akbar Vaseghi Sepideh Ahmadi Fatemeh Haddadi 《Journal of fluorescence》2018,28(2):633-638
Gene expression analysis is considered to be extremely important in many different biological researches. DNA-based diagnostic test, which contributes to DNA identification, has higher specificity, cost, and speed than some biochemical and molecular methods. In this study, we try to use the novel nano technology approach with Multiplex RT-PCR and Gold nano particular probes (GNPs-probes) in order to get gene expression in Curcumas melons. We used Agrobacterium tumefactions for gene transfer and GUS reporter gene as a reporter. After cDNA synthesis, Multiplex PCR and Multiplex RT-PCR techniques were used. Finally, probes were designed for RNA of GUS and Actin genes, and then the analysis of the gene expression using the probes attached to GNPs was carried out and the color changes in the GNPs were applied. In the following, probes hybridization was checked with DNA between 400 to 700 nm wavelengths and the highest rate was observed in the 550 to 650 nm. The results show that the simultaneous use of GNP-attached detectors and Multiplex RT-PCRcan reduce time and costmore considerably than somelaboratory methods for gene expiration investigation. Additionally, it can be seen thatthere is an increase in sensitivity and specificity of our investigation. Based on our findings, this can bea novel study doneusingMultiplex RT-PCRand unmodified AuNPs for gene transfer and expression detection to plants. We can claim that this assay has a remarkable advantage including rapid, cost-effectiveness, specificity and accuracy to detect transfer and expression genes in plants. Also,we can use this technique from other gene expressionsin many different biology samples. 相似文献