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排序方式: 共有1005条查询结果,搜索用时 31 毫秒
181.
HERAVI Majid M. BEHESHTIA Yahya S. KHORSHIDI Maliheh BAGHERNEJAD Bita BAMOHARRAM Fatemeh F. 《中国化学》2009,27(3):569-572
A simple, clean and environmentally benign route to the synthesis of 3-cyanopyridines is described via a one-pot multi-component reaction of 3,4-dimethoxyacetophenone, malonitrile or ethylcyanoacetate, aldehyde and ammonium acetate using heteropolyacids as heterogeneous and recyclable catalysts in very good yields. 相似文献
182.
Babak Mokhtarani Ali Sharifi Hamid Reza Mortaheb Mojtaba Mirzaei Morteza Mafi Fatemeh Sadeghian 《The Journal of chemical thermodynamics》2009,41(12):1432-1438
Densities and viscosities of 1-butyl-3-methylimidazolium nitrate [Bmim][NO3], and its binaries with alcohol (ethanol, 1-propanol, or 1-butanol) were measured at different temperatures. The densities and viscosities of pure ionic liquid were correlated successfully by empirical equations. The Vogel–Fulcher–Tammann equations can fit the experimental data of viscosities for pure IL. Excess molar volume and viscosity deviations were calculated for the binaries. The excess molar volumes have negative deviations from the ideal solution. 相似文献
183.
Younes Ghasemi Sara Rasoul-Amini Mohammad Hossein Morowvat Mohammad Bagher Ghoshoon Mohammad Javad Raee Soraya Khoubani Narges Negintaji Fatemeh Nouri Rezvan Parvizi 《Chemistry of Natural Compounds》2009,45(6):824-828
A unicellular microalga, Chlorella vulgaris, was isolated from rice field and applied in the biotransformation experiment
of hydrocortisone (1). This strain has not been previously tested for hydrocortisone bioconversion. Fermentation was carried out in BG-11 medium
supplemented with 0.05% substrate at 25°C for 14 days incubation. The products obtained were chromatographically purified
followed by their characterization using spectroscopic methods. 11β,17α,20β,21-Tetrahydroxypregn-4-en-3-one (2), 11β,17β-dihydroxyandrost-4-en-3-one (3), and 11β-hydroxyandrost-4-ene-3,17-dione (4) were the main bioproducts in the hydrocortisone bioconversion. Bioreaction characteristics observed were 20-ketone reduction
for accumulation of compound 2 and side chain degradation of the substrate to prepare compounds 3 and 4. Time course study showed the accumulation of the product 2 from the second day of the fermentation and 3 as well as 4 from the third day. All the metabolites reached their maximum concentration in seven days. Microalgal 18S rRNA gene was also
amplified by PCR. PCR products were sequenced to confirm their authenticity as 18S rRNA gene of microalgae. The result of
PCR blasted with other sequenced microalgae in NCBI showed 100% homology to the 18S small subunit rRNA of six strains of Chlorella
vulgaris. 相似文献
184.
185.
Wilkes JG Rafii F Sutherland JB Rushing LG Buzatu DA 《Rapid communications in mass spectrometry : RCM》2006,20(16):2383-2386
Pyrolysis mass spectrometry (PyMS) was investigated as a rapid tool to distinguish potential bioterror hoax materials from samples containing pathogenic bacteria. A pyrolysis time-of-flight (TOF) mass spectrometer equipped with an alternative ionization technique, metastable atom bombardment (MAB), was used to produce sample spectra. These spectra were analyzed by principal component and discriminant analysis for pattern recognition. Materials investigated were two strains of Vibrio parahaemolyticus, one of which produced the tdh toxin, two Salmonella enterica serotypes, a biological mosquito control product containing spores of Bacillus thuringiensis, and several white to off-white powders (which could be used as hoax materials), such as flour, corn starch, methyl cellulose, and xanthan gum. PyMS distinguished bacterial samples from hoax materials. Furthermore, pattern analysis differentiated Vibrios from Salmonellae, Salmonella enterica Anatum from S. enterica Heidelberg, and the two V. parahaemolyticus strains from each other. The B. thuringiensis mixture was distinguished from other bacteria and powders, suggesting that PyMS with pattern recognition may differentiate samples containing pathogens, including Bacillus spp., from nonbiological agents and that it can be a rapid method for detection of bacteria. MS data acquisition took only 7 min for each sample. 相似文献
186.
Anwar Gavili Taghi Dallali Isfahani Fatemeh Zabihi Iraj Hadi 《Heat and Mass Transfer》2013,49(10):1433-1445
The heat transfer and fluid flow behavior of water based Al2O3 nanofluids are numerically investigated inside a two-sided lid-driven differentially heated rectangular cavity. Physical properties which have major effects on the heat transfer of nanofluids such as viscosity and thermal conductivity are experimentally investigated and correlated and subsequently used as input data in the numerical simulation. Transport equations are numerically solved with finite volume approach using SIMPLEC algorithm. It was found that not only the thermal conductivity but also the viscosity of nanofluids has a key role in the heat transfer of nanofluids. The results show that at low Reynolds number, increasing the volume fraction of nanoparticles increases the viscosity and has a deteriorating effect on the heat transfer of nanofluids. At high Reynolds number, the increase in the viscosity is compensated by force convection and the increase in the volume fraction of nanoparticles which results in an increase in heat transfer is in coincidence with experimental results. 相似文献
187.
Vahid Khakyzadeh Mohammad Ali Zolfigol Fatemeh Derakhshan-Panah Majid Jafarian Mir Vahid Miri Maryam Gilandoust 《Molecular diversity》2018,22(2):335-342
The aim of this work is to introduce, model, and optimize a new non-acid-catalyzed system for a direct N\(=\)N–C bond formation. By reacting naphthols or phenol with anilines in the presence of the sodium nitrite as nitrosonium (\(\hbox {NO}^{+})\) source and triethylammonium acetate (TEAA), a N\(=\)N–C group can be formed in non-acid media. Modeling and optimization of the reaction conditions were investigated by response surface method. Sodium nitrite, TEAA, and water were chosen as variables, and reaction yield was also monitored. Analysis of variance indicates that a second-order polynomial model with F value of 35.7, a P value of 0.0001, and regression coefficient of 0.93 is able to predict the response. Based on the model, the optimum process conditions were introduced as 2.2 mmol sodium nitrite, 2.2 mL of TEAA, and 0.5 mL \(\hbox {H}_{2}\hbox {O}\) at room temperature. A quadratic (second-order) polynomial model, by analysis of variance, was able to predict the response for a direct N=N–C group formation. Predicted response values were in good agreement with the experimental values. Electrochemistry studies were done to introduce new Michael acceptor moieties. Broad scope, high yields, short reaction time, and mild conditions are some advantages of the presented method. 相似文献
188.
Iman Evazzade Mahmood Rezaee Roknabadi Mohammad Behdani Fatemeh Moosavi Daxing Xiong Kun Zhou Sergey V. Dmitriev 《The European Physical Journal B - Condensed Matter and Complex Systems》2018,91(7):163
We numerically analyze the interaction of small-amplitude phonon waves with standing gap discrete breather (DB) in strained graphene. To make the system support gap DB, strain is applied to create a gap in the phonon spectrum. We only focus on the in-plane phonons and DB, so the issue is investigated under a quasi-one-dimensional setup. It is found that, for the longitudinal sound waves having frequencies below 6 THz, DB is transparent and thus no radiation of energy from DB takes place; whereas for those sound waves with higher frequencies within the acoustic (optical) phonon band, phonon is mainly transmitted (reflected) by DB, and concomitantly, DB radiates its energy when interacting with phonons. The latter case is supported by the fact that, the sum of the transmitted and reflected phonon energy densities is noticeably higher than that of the incident wave. Our results here may provide insight into energy transport in graphene when the spatially localized nonlinear vibration modes are presented. 相似文献
189.
Fatemeh Ostovari 《Chinese Journal of Physics (Taipei)》2018,56(1):86-90
Magnetic properties of pure and Fe doped rutile TiO2 and TiO2-ε are investigated using the first principle density functional theory. The results show that the considered systems are ferromagnetic. Furthermore, the origin of ferromagnetism is discussed and it is found that the double exchange and super-exchange are the main interactions in these compounds. Based on the calculations, the magnitude of the magnetic moment depends on the concentration of impurities and oxygen vacancies and the largest magnetic moment corresponds to the FexTi1-xO2-ε. Moreover, using a model based on the bound magnetic polarons, the coexistence of ferromagnetic and paramagnetic phases can occur in FexTi1-xO2 containing different impurity ions such as Fe+2 and Fe+3 with different Curie temperatures. The finding may presents the potential application of the considered system as diluted magnetic semiconductor. 相似文献
190.
The potential of nonharmonic systems has several applications in the field of quantum physics. The photonadded coherent states for annharmonic oscillators in a nonlinear Kerr medium can be used to describe some quantum systems. In this paper, the phase properties of these states including number-phase Wigner distribution function,Pegg-Barnett phase distribution function, number-phase squeezing and number-phase entropic uncertainty relations are investigated. It is found that these states can be considered as the nonclassical states. 相似文献