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81.
Zahra Talebpour Mehregan Safari Fatemeh Molaabaci Ali Alizadeh Hassan Y. Aboul-Enein 《Chromatographia》2010,72(7-8):707-712
A novel poly(methyl methacrylate–ethyleneglycol dimethacrylate–acrylic acid) film has been introduced for coating on stir bars to sorptive extraction (SBSE). The effects of different contents of porogen, monomer, cross-linker, modifier and initiator during the solvent or bulk polymerization step on the mechanical property and solvent resistant of prepared sorptive stir bars were investigated. The evaluation of results were caused to obtain the four prepared sorptive stir bars with good mechanical stability and excellent resistance to organic solvents. The extraction efficiency of these prepared sorptive stir bars were investigated by liquid desorption-liquid chromatography-ultraviolet detection (LD-LC-UV) using N-Nitrosodiphenylamine as target analyte. SBSE assays showed the sorptive stir bar that prepared using solution polymerization method had the better recovery for N-Nitrosodiphenylamine in water samples. This sorptive stir bar showed good linearity and acceptable recoveries, as well as advantages such as sensitivity, simplicity, low cost and high feasibility. Based on atomic force microscopy (AFM) results, the average pore size of optimum prepared stir bar using solvent polymerization method was obtained ~9 nm. The thermal gravity (TG) and differential scanning calorimetric (DSC) results showed this polyacrylate film has high thermal stability. 相似文献
82.
Nano-sized Cu6Sn5 alloy powders were prepared by a co-precipitation reductive route using a hydrothermal method at 80 °C. The nano-size and morphology of the synthesized Cu6Sn5 alloy powders were evaluated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The obtained morphologies, chemical compositions are comparatively discussed. A variety of synthesis parameters, such as time, capping agent and sort of reductant, has an effect on the morphology of the obtained materials, and will be particularly highlighted. 相似文献
83.
84.
Let \(\mathcal{{A}}\) be a Banach algebra and let \(\mathcal{{X}}\) be an introverted closed subspace of \(\mathcal{{A}}^*\) . Here, we give necessary and sufficient conditions for that the dual algebra \(\mathcal{{X}}^*\) of \(\mathcal{{X}}\) or the topological centers \({\mathfrak {Z}}_t^{(1)}(\mathcal{{X}}^{*})\) and \({\mathfrak {Z}}_t^{(2)}(\mathcal{{X}}^{*})\) of \(\mathcal{{X}}^*\) are Banach \(*\) -algebras. We finally apply these results to the Banach space \(L_0^\infty (G)\) of all equivalence classes of essentially bounded functions vanishing at infinity on a locally compact group \(G\) . 相似文献
85.
A palladium catalyst was synthesized using N‐benzyl DABCO chloride and palladium chloride. The structure of this catalyst was characterized and then the catalyst was used in Suzuki cross‐ coupling reaction of different aryl halides with arylboronic acids. All substrates afforded the corresponding products in good to high yields in the presence of low amounts of the catalyst. Under the heating conditions employed, cheaper and more available aryl chlorides gave relatively high yields in the Suzuki reaction. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
86.
Palladium nanoparticles immobilized on sepiolite–cyclodextrin nanosponge hybrid: Efficient heterogeneous catalyst for ligand‐ and copper‐free C─C coupling reactions
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A novel hybrid system composed of sepiolite clay and cyclodextrin nanosponge (CDNS) was prepared via reaction of Cl‐functionalized sepiolite with amine‐functionalized CDNS. CDNS–sepiolite was then applied for immobilization of Pd(0) nanoparticles. The resulting hybrid system, Pd@CDNS‐sepiolite, was characterized using various techniques and successfully used as an efficient and heterogeneous catalyst for ligand‐ and copper‐free Sonogashira and Heck coupling reactions under mild reaction conditions. Recycling experiments confirmed that Pd@CDNS‐sepiolite was recyclable and could be used for several consecutive reaction runs with slight Pd leaching and loss of catalytic activity. 相似文献
87.
The catalytic activity of ortho‐palladated [Pd{C6H2(CH2CH2NH2)‐(OMe)2,3,4}(m‐Br)]2, a complex of homoveratrylamine in the copper‐free Sonogashira coupling reaction has been investigated. This complex is a catalyst that is efficient, stable and non‐sensitive to air and moisture in the Sonogashira reaction. In this homogeneous catalytic system, various aryl halides were efficiently coupled with phenylacetylene in mostly moderate to good yields in N‐methylpyrrolidone at 100 °C under copper‐free conditions. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
88.
Condensation of aldehydes, isonitriles and 2‐aminopyridines in the presence of H3PMo12O40 affords different derivatives of 3‐aminoimidazo[1,2‐a]pyridine in good to excellent yields. 相似文献
89.
In this work we use the vapor-sorption equilibrium data to show the degree of solvent upturn in each solvent-polymer system. For this purpose, 23 isothermal data sets for four polymer + solvent binaries, one block copolymer + solvent binary and for the corresponding polymer pairs have been used in the temperature range of 25-70 °C. Solvents studied are benzene, carbon tetrachloride, chloroform and pentane. Homopolymers studied are polyisobutylene, poly(ε-caprolactone), poly(ethylene oxide), n-heptadecane, polystyrene, poly(vinyl chloride), poly(vinyl methyl ether), and n-tetracosane.According to these data sets, solvent weight fraction in the polymer is plotted against solvent-vapor activity that is calculated assuming an ideal gas phase of pure solvent vapor neglecting the vapor pressure of the polymer. We use the Flory-Huggins theory to obtain dimensionless interaction parameter, χ. Also the Zimm-Lundberg clustering theory and non-ideality thermodynamic factor, Γ are used to interpret the equilibrium data. 相似文献
90.
Column preconcentration and electrothermal atomic absorption spectrometric determination of rhodium in some food and standard samples
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Mohammad Ali Taher Fatemeh Pourmohammad Hamid Fazelirad 《Journal of separation science》2015,38(23):4153-4158
In the present work, an electrothermal atomic absorption spectrometric method has been developed for the determination of ultra‐trace amounts of rhodium after adsorption of its 2‐(5‐bromo‐2‐pyridylazo)‐5‐diethylaminophenol/tetraphenylborate ion associated complex at the surface of alumina. Several factors affecting the extraction efficiency such as the pH, type of eluent, sample and eluent flow rates, sorption capacity of alumina and sample volume were investigated and optimized. The relative standard deviation for eight measurements of 0.1 ng/mL of rhodium was ±6.3%. In this method, the detection limit was 0.003 ng/mL in the original solution. The sorption capacity of alumina and the linear range for Rh(III) were evaluated as 0.8 mg/g and 0.015–0.45 ng/mL in the original solution, respectively. The proposed method was successfully applied for the extraction and determination of rhodium content in some food and standard samples with high recovery values. 相似文献