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991.
Rahim Hekmatshoar Sodeh Sadjadi Samaheh Sadjadi Majid M. Heravi Yahya S. Beheshtiha Fatemeh F. Bamoharram 《合成通讯》2013,43(11):1708-1716
An efficient synthetic method of six- and five-member nitrogen heterocyclic compounds was developed. Nitrogen heterocyclic compounds were prepared by condensation of the β-dicarbonyl compounds with the corresponding β- or γ-amino alcohols, subsequent cyclization, and spontaneous aromatization in the presence of a catalytic amount of Keggin-type heteropoly acids under very mild conditions. 相似文献
992.
Three-component, one-pot synthesis of 4,6-diarylpyrimidin-2(1H)-ones and 9-phenyl-8-oxa-10,12-diaza-tricyclo[7.3.1.02,7]trideca-2(7),3,5-trien-11-one by condensing acetophenone derivatives, aldehydes, and urea in the presence of trimethylsilyl chloride using a catalytic amount of H6P2W18O62-18H2O under solvent-free conditions is reported. 相似文献
993.
Angel Rodriguez-Lafuente Fatemeh S. Mirnaghi Janusz Pawliszyn 《Analytical and bioanalytical chemistry》2013,405(30):9723-9727
The use of thin-film solid-phase microextraction (SPME) as the sampling preparation step before direct analysis in real time (DART) was evaluated for the determination of two prohibited doping substances, cocaine and methadone, in urine samples. Results showed that thin-film SPME improves the detectability of these compounds: signal-to-blank ratios of 5 (cocaine) and 13 (methadone) were obtained in the analysis of 0.5 ng/ml in human urine. Thin-film SPME also provides efficient sample cleanup, avoiding contamination of the ion source by salt residues from the urine samples. Extraction time was established in 10 min, thus providing relatively short analysis time and high throughput when combined with a 96-well shaker and coupled with DART technique. Figure
Schematic protocol for determination of cocaine and methadone in urine by thin-film SPME and DART-MS analysis 相似文献
994.
Fatemeh Hesami Gholam Hossein Rounaghi Massoumeh Mohajeri Somayeh Tarahomi 《Journal of solution chemistry》2011,40(8):1408-1417
The complexation reactions of 4′-nitrobenzo-15-crown-5 (4′NB15C5) with Zn2+, Mn2+, Cr3+ and Sn4+ cations were studied in acetonitrile–ethanol (AN–EtOH) binary solvent mixtures at different temperatures by the electrical
conductometry method. The stability constants of the resulting 1:1 complexes were determined from computer fitting of the
conductance versus mole ratio data. The results show that the selectivity order of 4′NB15C5 for the metal cations in the AN–EtOH
(mol-%AN=76) binary solvent at 298.15 K is: Cr3+>Mn2+≈Zn2+>Sn4+, but the selectivity order changes with the composition of the mixed solvents. A nonlinear relationship was observed between
the stability constants (log 10
K
f) of these complexes and the composition of the AN–EtOH binary solvents. The corresponding thermodynamic parameters (DHco, DSco)(\Delta H_{\mathrm{c}}^{\mathrm{o}}, \Delta S_{\mathrm{c}}^{\mathrm{o}}) were obtained from the temperature dependence of the stability constants using van’t Hoff plots. The results show that the
values and also the sign of these parameters are influenced by the nature and composition of the mixed solvents. 相似文献
995.
Yousef Fazaeli Amir R. Jalilian Mostafa M. Amini Ali Rahiminejad-kisomi Saeed Rajabifar Fatemeh Bolourinovin Sedigheh Moradkhani 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(1):17-24
[67Ga]labeled tetraphenyl porphyrin ([67Ga]-TPP) was prepared using freshly prepared [67Ga]GaCl3 and tetraphenyl porphyrin (TPPH2) for 30–60 min at 25 °C (radiochemical purity: >97 ± 1% ITLC, >98 ± 0.5% HPLC, specific activity: 13–14 GBq/mmol). Stability
of the complex was checked in final formulation and human serum for 24 h. The partition coefficient was calculated for the
compound (log P 1.89). The biodistribution of the labeled compound in vital organs of wild-type rats was studied using scarification studies
and SPECT imaging up to 24 h. A detailed comparative pharmacokinetic study performed for 67Ga cation and [67Ga]-TPP. The complex is mostly washed out from the circulation through kidneys and can be an interesting tumor imaging/targeting
agent due to low liver uptake and rapid excretion through the urinary tract. 相似文献
996.
Mehdi BazarganipourMinoo Sadri Fatemeh DavarMasoud Salavati-Niasari 《Polyhedron》2011,30(6):1103-1107
HgSe nanorods have been synthesized through a simple hydrothermal reduction approach. The nanorods formed were ≈45 nm average diameter and ≈3 μm nm in length. X-ray diffraction characterization suggested that the product consists of cubic phase pure HgSe. The as-prepared products were also characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). An X-ray energy dispersive spectroscopy (EDX) study further confirmed the composition and purity of the product. The synthesis procedure is simple and uses less toxic reagents than the previously reported methods. The results showed that the capping agent CTAB (cetyltrimethylammoniumbromide) plays a crucial role in the process. Other factors, such as the reaction time, temperature, different capping agent and the reductant type also have an influence on the morphology of the final products to some extent. 相似文献
997.
The activity of [Pd{C6H4(CH2N(CH2Ph)2)} (μ-Br)]2 complex was investigated in the Heck-Mizoroki C-C cross-coupling reaction. This complex is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides and also arenesulfonyl chlorides. The cross-coupled products were produced in excellent yields in short reaction time using a catalytic amount of [Pd{C6H4(CH2N(CH2Ph)2) (μ-Br)]2 complex in NMP at 130 °C. 相似文献
998.
A new method is presented for simultaneous preconcentration of trace Fe(III) and Cr(III) by using polyacrylic acid-alumina as a sorbent. The separation/preconcentration conditions of analytes were investigated, including effect of pH, flow rate, elution conditions, sample volume, and interfering ions. At pH 4, the maximum sorption capacities of Fe3+ and Cr3+ were 8.0 and 13.0 mg/g, respectively, by the column method. The linearity was maintained in the concentration range of 0.175-6.0 x 10(3) ng/mL for iron and 0.175-8.0 x 10(3) ng/mL for chromium in the original solution. The RSD values under optimum conditions were +/- 1.73 and +/- 1.28% for 2.0 microg/mL Fe and Cr, respectively. The preconcentration factor was 400 for both of the elements, and detection limits were 0.025 and 0.023 ng/mL for Fe and Cr in the original solutions. The proposed method was successfully applied to the determination of trace amounts of Fe and Cr in plant samples. 相似文献
999.
Fatemeh Abrishamian Shinichi Nagai Shinya Sato Masaaki Imai 《Optical and Quantum Electronics》2008,40(9):665-676
Spectral response of acoustically induced microbending through thin optical fiber is discussed from mode-coupling of core
and cladding modes. The thin fiber is analyzed in three-layered structure (core-cladding-air) to gain insights into acousto-optic
modulation. We explained the dependence of core and/or cladding diameters on acoustic source parameters from numerical calculations.
According to the calculations, we successfully fabricated all-optical tunable filter using this thin fiber that yields an
efficient mode-coupling at flexural wave frequencies less than 1MHz. To increase the acousto-optic effect, we used a specially
designed thin optical fiber (80 μm of cladding diameter) in the section where flexural wave is produced, and spliced both
ends of the thin fiber to the tapered 125 μm fibers. The frequency and voltage tuning of fabricated filter is also confirmed
by changing the driven frequency and applied voltage of the PZT, respectively. This result suggests a possibility of fiber-optic
device application as all-optical tunable filter at 1.55 μm. 相似文献
1000.
Fatemeh Abrishamian 《Optics Communications》2008,281(13):3561-3566
We report results of experiments examining cross-phase modulation effect on fiber grating coupler (FGC). All-optical switching are observed in both cases of high pump pulses emitted from high-power Nd:YAG laser and mode-locked EDF laser. Based on coherent detection using a lock-in amplifier, the red-shift of the Bragg wavelength for a FGC was estimated to be 0.04-0.06 nm/1.5-1.7 kW peak power of EDF pump light at 1.55 μm. To avoid mixture of pump pulse and signal light at 1.55 μm, we have also performed the experiment using high power Nd:YAG laser as a pump power. For a Nd:YAG laser, the red-shift of Bragg wavelength is estimated to be 0.06 nm at maximum pump power of 2.1 kW. A simple model for the proposed detection scheme is given and the resultant red-shift is analyzed numerically. 相似文献