全文获取类型
收费全文 | 150篇 |
免费 | 4篇 |
国内免费 | 3篇 |
专业分类
化学 | 86篇 |
力学 | 16篇 |
数学 | 36篇 |
物理学 | 19篇 |
出版年
2023年 | 3篇 |
2022年 | 4篇 |
2021年 | 7篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 4篇 |
2017年 | 1篇 |
2016年 | 4篇 |
2015年 | 3篇 |
2014年 | 10篇 |
2013年 | 18篇 |
2012年 | 5篇 |
2011年 | 16篇 |
2010年 | 8篇 |
2009年 | 5篇 |
2008年 | 14篇 |
2007年 | 9篇 |
2006年 | 8篇 |
2005年 | 4篇 |
2004年 | 7篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1981年 | 1篇 |
排序方式: 共有157条查询结果,搜索用时 78 毫秒
11.
Faruk Civan 《Transport in Porous Media》2007,67(2):329-334
An Arrhenius-type asymptotic-exponential function is derived to describe the temperature dependence of the power needed for
detachment of fine particles from pore walls in porous media. 相似文献
12.
Fevzihan Basarir Farid Sayar Irani Arif Kosemen B. Tugba Camic Faruk Oytun Bahadir Tunaboylu Hee Jeong Shin Ki Young Nam Hyosung Choi 《Materials Today Chemistry》2017
Organic photovoltaics (OPVs) are considered as a future alternative for conventional silicon based solar cells, owing to their low cost, ease of production and high-throughput. The transparent conducting electrode (TCE) is a fundamental component of OPVs. Traditionally, indium tin oxide (ITO) has been mainly utilized as a TCE in OPV applications due to its relatively high transparency and low sheet resistance. However, increasing demand for the optoelectronic devices has led to large fluctuations in ITO prices in the past decade and ITO is known to account more than 50% of the total cost of OPV devices. Thus, it is believed that development of solution-processable alternative materials is of great importance in reducing the cost of OPVs. Numerous materials, including silver nanowires, carbon nanotubes, graphene and conducting polymers, have been offered as replacements for ITO. This article reviews recent progress on fabrication of TCE via solution based coating techniques of silver nanowires (Ag NWs). In addition, performance of the Ag NWs based TCE in OPVs is summarized. Finally, we explore the future outlook for Ag NWs based TCE at the end of the review. 相似文献
13.
Ali Coruh Faruk Yilmaz Busra Sengez Mustafa Kurt Mehmet Cinar Mehmet Karabacak 《Structural chemistry》2011,22(1):45-56
This work presents the synthesis and characterization of a novel compound, 4-(thiophene-3-ylmethoxy)phthalonitrile (TMP).
The spectroscopic properties of the compound were examined by FT-IR, FT-Raman, NMR, and UV techniques. FT-IR and FT-Raman
spectra in solid state were observed in the region 4000–400 cm−1 and 3500–50 cm−1, respectively. The 1H and 13C NMR spectra were recorded in CDCl3 solution. The UV absorption spectrum of the compound that dissolved in THF was recorded in the range of 200–800 nm. The structural
and spectroscopic data of the molecule in the ground state were calculated using density functional theory (DFT) employing
B3LYP exchange correlation and the 6-311++G(d,p) basis set. The vibrational wavenumbers were calculated and scaled values
were compared with experimental FT-IR and FT-Raman spectra. The complete assignments were performed on the basis of the experimental
results and total energy distribution (TED) of the vibrational modes, calculated with scaled quantum mechanics (SQM) method.
Isotropic chemical shifts (13C NMR and 1H NMR) were calculated using the gauge-invariant atomic orbital (GIAO) method. A study on the electronic properties, such
as HOMO and LUMO energies, were performed by time-dependent DFT (TD-DFT) approach. The HOMO and LUMO analyses have been used
to elucidate information regarding charge transfer within the molecule. Comparison of the calculated frequencies, NMR chemical
shifts, absorption wavelengths with the experimental values revealed that DFT method produces good results. 相似文献
14.
In the present paper, we consider the classical Widder transform, the Hν-transform, the Kν-transform, and the Yν-transform. Some identities involving these transforms and many others are given. By making use of these identities, a number of new Parseval-Goldstein type identities are obtained for these and other well-known integral transforms. 相似文献
15.
Shale-Gas Permeability and Diffusivity Inferred by Improved Formulation of Relevant Retention and Transport Mechanisms 总被引:5,自引:0,他引:5
A theoretically improved model incorporating the relevant mechanisms of gas retention and transport in gas-bearing shale formations
is presented for determination of intrinsic gas permeability and diffusivity. This is accomplished by considering the various
flow regimes according to a unified Hagen–Poiseuille-type equation, fully compressible treatment of gas and shale properties,
and numerical solution of the non-linear pressure equation. The present model can accommodate a wide range of fundamental
flow mechanisms, such as continuum, slip, transition, and free molecular flow, depending on the prevailing flow conditions
characterized by the Knudsen number. The model indicates that rigorous determination of shale-gas permeability and diffusivity
requires the characterization of various important parameters included in the present phenomenological modeling approach,
many of which are not considered in previous studies. It is demonstrated that the improved model matches a set of experimental
data better than a previous attempt. It is concluded that the improved model provides a more accurate means of analysis and
interpretation of the pressure-pulse decay tests than the previous models which inherently consider a Darcian flow and neglect
the variation of parameters with pressure. 相似文献
16.
The temperature independent esr spectrum of di-i-Propyl-t-butylmethyl radical, derived from photolysis of oxalate ester, indicates a frozen “cogwhell” conformation for this specie. The neo-pentyl substituted oxalate esters are suggested to qive β-hydrogen abstraction on presence of di-t-butylperoxide on photolysis. 相似文献
17.
18.
The methodology and numerical solution of problems concerning transport processes via the method of differential quadrature are presented. Application of the method is demonstrated by solving a simple one-dimensional, time-dependent (transient) diffusion process involving an irreversible reaction without any flux across the end boundary. In addition, the same technique is used (for the first time to the authors' knowledge) to solve a steady-state problem. For this purpose, a convection-diffusion problem involving an irreversible reaction is considered. The demonstration is carried out in two ways, (1) using the Bellman et al. technique which employs approximation formulas for higher order partial derivatives derived by iterating the linear quadrature approximation for the first order partial derivative, and (2) using individual quadratures to approximate the partial derivatives of first, as well as higher orders, as suggested by Mingle. Both approaches give the same results; however, the latter saves an appreciable amount of iterative computing effort despite the fact that it requires separate weighting coefficients for each individual quadrature. Since the technique of differential quadrature can produce solutions with sufficient accuracy even when using as few as three discrete points, both the programming task and computational effort are alleviated considerably. For these reasons the differential quadrature approach appears to be very practical in solving a variety of problems related to transport phenomena. 相似文献
19.
Civan F 《Journal of colloid and interface science》2005,285(1):429-432
The validity of the Vogel-Tammann-Fulcher type asymptotic exponential functions for representing the temperature dependence of various properties, such as the particle-particle pull-off adherence forces in ice and hydrates and the annealing effect on polystyrene latex films, is demonstrated. The parameters of this equation are determined using the reported experimental data. The applications show that such functions yield accurate correlations of the experimental property data measured at various temperatures. 相似文献
20.
Alemdar Bayraktar Abdurrahman ahin D. Mehmet
zcan Faruk Yildirim 《Applied Mathematical Modelling》2010,34(1):92-121
In the present paper, the numerical damage assessment of the masonry bell tower called “Haghia Sophia” in Trabzon, Turkey is performed by nonlinear 3D finite element modeling. The behavior of bell tower is determined under several different conditions: nonlinear static analysis containing dead and wind loads and nonlinear seismic analysis. In addition to, an assessment of the tower’s stability with respect to the tilt of the tower is carried out by means of a nonlinear analysis. In the nonlinear dynamic analysis, the east–west component of 1992 Erzincan earthquake is used. Cracking and crushing of the masonry have been taken into account, as well as the influence of material nonlinearity. The numerical analysis has given a valuable picture of possible damage evolution, providing useful hints for the prosecution of structural monitoring. The displacement and stress fields, as well as the distribution of cracking have been calculated and compared to the actual distribution of fractures in the tower. It is seen from the numerical results that there is a good agreement with present damages of the bell tower. 相似文献