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561.
Ouhib F Raynal M Jouvelet B Isare B Bouteiller L 《Chemical communications (Cambridge, England)》2011,47(38):10683-10685
Hydrogen bonded assemblies are usually decomposed by polar organic solvents. However, we have succeeded in preparing a strongly associated supramolecular polymer which forms viscous solutions in competitive solvents such as tetrahydrofuran. 相似文献
562.
Zakaria M. M. Mahmoud Awad A. Ibraheem M. El-Azab Farid 《Physics of Particles and Nuclei Letters》2014,11(3):219-231
Optical-model analysis of proton elastic scattering from 6He has been carried out for eight sets of elastic scattering data at energies, 24.5, 25.0, 36.2, 38.3, 40.9, 41.6, 71.0 and 82.3 MeV/n respectively. The vector analyzing power and differential cross section for the elastic scattering of 6He nucleus from polarized protons at 71 MeV have been analyzed in the framework of the optical model potentials. The data are, first, analyzed in term of phenomenological potentials using the Woods-Saxon form for the real and imaginary parts supplemented by a spin-orbit potential of Thomas form. The analysis has been also performed using microscopic complex potentials. 相似文献
563.
Farid Bozorgnia 《Numerical Methods for Partial Differential Equations》2015,31(3):923-949
Given a bounded open set , we present numerical approximations for two problems related to minimal partitioning of the first eigenvalues of the Dirichlet Laplacian. The first problem is about minimizing the sum of first eigenvalues of the Dirichlet Laplacian. This partitioning problem arises as a steady state of a reaction‐diffusion process. To do this, a new idea to approximate the second eigenfunction and second eigenvalue is presented. We use the qualitative properties of the minimization problem to construct a numerical algorithm to approximate optimal configurations. A rigorous analysis to show the convergence and the rate of convergence is given. Moreover, we discuss the numerical implementation of the resulting approach and present computational tests confirming the expected asymptotic behavior of optimal partitions with large numbers of partitions. © 2014 Wiley Periodicals, Inc. Numer Methods Partial Differential Eq 31: 923–949, 2015 相似文献
564.
Farid Taherkhani Hamed Akbarzadeh Mostafa Feyzi Hamid Reza Rafiee 《Journal of nanoparticle research》2015,17(1):29
Molecular dynamics simulation has been implemented for doping effect on melting temperature, heat capacity, self-diffusion coefficient of gold–copper bimetallic nanostructure with 55 total gold and copper atom numbers and its bulk alloy. Trend of melting temperature for gold–copper bimetallic nanocluster is not same as melting temperature copper–gold bulk alloy. Molecular dynamics simulation of our result regarding bulk melting temperature is consistence with available experimental data. Molecular dynamics simulation shows that melting temperature of gold–copper bimetallic nanocluster increases with copper atom fraction. Semi-empirical potential model and quantum Sutton–Chen potential models do not change melting temperature trend with copper doping of gold–copper bimetallic nanocluster. Self-diffusion coefficient of copper atom is greater than gold atom in gold–copper bimetallic nanocluster. Semi-empirical potential within the tight-binding second moment approximation as new application potential model for melting temperature of gold–copper bulk structure shows better result in comparison with EAM, Sutton–Chen potential, and quantum Sutton–Chen potential models. 相似文献
565.
Ahmed A. Al-Ghamdi Attieh A. Al-Ghamdi Omar A. Al-Hartomy Ahmed M. Nawar E. El-Gazzar Farid El-Tantawy F. Yakuphanoglu 《Journal of Sol-Gel Science and Technology》2013,67(2):368-375
A new Schottky photodiode of Ag/RuO2/p-Si/Al was successfully fabricated using spin-coating technique. The ruthenium oxide (RuO2) nanoparticles with an average size of 8 nm were synthesized using a sol–gel method. The crystal structure and morphology of the synthesized RuO2 were analyzed by means of X-ray diffraction, energy dispersive X-ray spectroscopy, transmission electron microscopy and selective area electron diffraction. The rectification ratio of the diode was found to be 112 at ±2 V. The ideality factor and barrier height values of the Ag/RuO2/p-Si/Al diode were obtained to be 1.47 and 0.55 eV, respectively. The Cheung–Cheung and Norde’s models were used to determine the diode parameters. The photoresponse behavior of the fabricated Ag/RuO2/p-Si/Al diode was studied under various illumination intensities. The transient photocurrent results indicate that photocurrent under illumination is higher than the dark current and this indicates that the fabricated diode behaves as a photodiode. The capacitance–voltage–frequency measurements indicate that the capacitance of the diode depends on voltage and frequency. The obtained results suggest that the new Ag/RuO2/p-Si/Al diode can be used an optical switching device for optical sensor applications and are also expected to be generated in the future study. 相似文献
566.
567.
Mehdi Bakavoli Farid Moeinpour Arezoo Sardashti‐Birjandi Abolghasem Davoodnia 《Journal of heterocyclic chemistry》2013,50(2):188-193
Reaction of 4‐chlorobenzonitrile oxide ( 2 ) which was generated in situ with acrylo nitrile ( 3 ), vinyl acetate ( 4 ) and allyl bromide ( 5 ) as dipolarphile afforded the new cycloadducts 6a , 7a , and 8a compounds, respectively. Reactivity and regiochemistry of these reactions were investigated using activation energy calculations and density functional theory‐based reactivity indexes. The theoretical 13C NMR chemical shifts of the cycloadducts which were obtained by gauge‐invariant atomic orbital method were comparable with the observed values. 相似文献
568.
Polarizability of noninteracting 2D Dirac electrons has a 1/square root(qv-omega) singularity at the boundary of electron-hole excitations. The screening of this singularity by long-range electron-electron interactions is usually treated within the random phase approximation. The latter is exact only in the limit of N-->infinity, where N is the "color" degeneracy. We find that the ladder-type vertex corrections become crucial close to the threshold as the ratio of the nth order ladder term to the same order random phase approximation contribution is ln(n)|qv-omega|/N(n). We perform an analytical summation of the infinite series of ladder diagrams which describe the excitonic effect. Beyond the threshold, qv>omega, the real part of the polarization operator is found to be positive leading to the appearance of a strong and narrow plasmon resonance. 相似文献
569.
This study investigated the impact of individual and combination of different sources of heating (passive solar heating, electric oil-heater, and solar air heater) in a pilot-scale building containing phase change material (PCM) for a potential reduction in energy consumption while maintaining thermal comfort. Unlike most of the recent simulations and modelling studies, this impact was tested experimentally using two identical control and test huts located at the University of Auckland. The control hut was equipped with standard gypsum boards while the test hut had gypsum boards containing PCM (PureTemp 20, PT20). The study found that combining both active and passive solar heating with a temperature-controlled electric oil heater demonstrated the ability to provide significant energy savings and maintain thermal comfort in the test hut, most notably overnight. The suggested combination was tested over different weather conditions and with different temperature constraints to maintain thermal comfort and achieve energy savings ranging from 33% to 87.5%. 相似文献
570.
Muhammad Rehan Malik Fatemah Farraj Al-Harbi Asif Nawaz Adnan Amin Arshad Farid Mohammed Al Mohaini Abdulkhaliq J. Alsalman Maitham A. Al Hawaj Yousef N. Alhashem 《Molecules (Basel, Switzerland)》2022,27(10)
In the present study, chitosan-decorated multiple nanoemulsion (MNE) was formulated using a two-step emulsification process. The formulated multiple nanoemuslion was evaluated physiochemically for its size and zeta potential, surface morphology, creaming and cracking, viscosity and pH. A Franz diffusion cell apparatus was used to carry out in vitro drug-release and permeation studies. The formulated nanoemulsion showed uniform droplet size and zeta potential. The pH and viscosity of the formulated emulsion were in the range of and suitable for topical delivery. The drug contents of the simple nanoemulsion (SNE), the chitosan-decorated nanoemulsion (CNE) and the MNE were 71 ± 2%, 82 ± 2% and 90 ± 2%, respectively. The formulated MNE showed controlled release of itraconazole as compared with that of the SNE and CNE. This was attributed to the chitosan decoration as well as to formulating multiple emulsions. The significant permeation and skin drug retention profile of the MNE were attributed to using the surfactants tween 80 and span 20 and the co-surfactant PEG 400. ATR-FTIR analysis confirmed that the MNE mainly affects the lipids and proteins of the skin, particularly the stratum corneum, which results in significantly higher permeation and retention of the drug. It was concluded that the proposed MNE formulation delivers drug to the target site of the skin and can be therapeutically used for various cutaneous fungal infections. 相似文献