Study of the plasma equilibrium in Damavand tokamak via numerical solution of the Grad-Shafranov equation

In this work we study the Damavand tokamak plasma equilibrium with an elongated ross section and fixed boundary conditions. These equilibria are characterized by three parameters such as elongation, triangularity and magnetic axis shift. An iterative scheme f the moment’s method is used to solve the Grad-Shafranov equation in flux coordinate system. Magnetic flux surface contours and main equilibrium parameters have been btained by applying the geometry and boundary conditions of the Damavand tokamak.     

Rational design of a BiFeWO6 nanostructure for supercapacitor applications

Journal of Solid State Electrochemistry - Scientists are increasingly interested in improving electroactive technologies for supercapacitor applications, since energy storage devices have improved...     

A model of multiphase flow and transport in porous media applied to gas migration in underground nuclear waste repository

We prove existence of solutions for a new model of two compressible and partially miscible phase flow in porous media, applied to gas migration in an underground nuclear waste repository. This model, modeling fully and partially water saturated situations, consist of a coupled system of quasilinear parabolic partial differential equations. We seek a new set of variables in order to obtain a system which belongs to the class of equations considered by Alt and Luckhaus such that it would be possible to use their existence theorem. A simulation of a numerical test case is performed in order to numerically demonstrate the ability of this model to take in account the appearance of one phase. To cite this article: F. Smaï, C. R. Acad. Sci. Paris, Ser. I 347 (2009).     

New data about the reaction of benzyolacetonitrile with malononitrile and its self‐condensation

The reactions of benzoylacetonitrile with malononitrile in refluxing pyridine and its self condensation under fusion conditions in the presence of ammonium acetate and in refluxing pyridine were reinvestigated. New data were found and plausible mechanisms to account for the formation of the products are suggested.     

Kinetic determinations of accurate relative oxidation potentials of amines with reactive radical cations

Accurate oxidation potentials for organic compounds are critical for the evaluation of thermodynamic and kinetic properties of their radical cations. Except when using a specialized apparatus, electrochemical oxidation of molecules with reactive radical cations is usually an irreversible process, providing peak potentials, E(p), rather than thermodynamically meaningful oxidation potentials, E(ox). In a previous study on amines with radical cations that underwent rapid decarboxylation, we estimated E(ox) by correcting the E(p) from cyclic voltammetry with rate constants for decarboxylation obtained using laser flash photolysis. Here we use redox equilibration experiments to determine accurate relative oxidation potentials for the same amines. We also describe an extension of these experiments to show how relative oxidation potentials can be obtained in the absence of equilibrium, from a complete kinetic analysis of the reversible redox kinetics. The results provide support for the previous cyclic voltammetry/laser flash photolysis method for determining oxidation potentials.     

Optical conductivity of a two-dimensional electron liquid with spin-orbit interaction

The interplay of electron-electron interactions and spin-orbit coupling leads to a new contribution to the homogeneous optical conductivity of the electron liquid. The latter is known to be insensitive to many-body effects for a conventional electron system with parabolic dispersion. The parabolic spectrum has its origin in the Galilean invariance which is broken by spin-orbit coupling. This opens up a possibility for the optical conductivity to probe electron-electron interactions. We analyze the interplay of interactions and spin-orbit coupling and obtain optical conductivity beyond RPA.