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81.
Adsorption of a reactive dye on chemically modified activated carbons--influence of pH 总被引:2,自引:0,他引:2
Orfão JJ Silva AI Pereira JC Barata SA Fonseca IM Faria PC Pereira MF 《Journal of colloid and interface science》2006,296(2):480-489
The surface chemistry of a commercial activated carbon with a slightly basic nature was modified by appropriate treatments in order to obtain two additional samples, respectively with acidic and basic properties, without changing its textural parameters significantly. Different techniques (N2 adsorption at 77 K, temperature programmed desorption, and determination of acidity, basicity, and pH at the point of zero charge) were used to characterize the adsorbents. Kinetic and equilibrium adsorption data of a selected textile reactive dye (Rifafix Red 3BN, C.I. reactive red 241) on the mentioned materials were obtained at the pH values of 2, 7, and 12. The kinetic curves are fitted using the second-order model. The respective rate constants seem to diminish progressively with the initial concentration for the more diluted solutions tested, reaching a constant value at higher concentrations, which depends on the experimental system under consideration (adsorbent and pH). In general, the Langmuir model provides the best fit for the equilibrium data. The different uptakes obtained are discussed in relation to the surface chemical properties of the adsorbents. It is shown that the adsorption of the reactive (anionic) dye on the basic sample (prepared by thermal treatment under H2 flow at 700 degrees C) is favored. This conclusion is explained on the basis of the dispersive and electrostatic interactions involved. Moreover, it is also shown that the optimal adsorption condition for all the activated carbons tested corresponds to solution pH values not higher than the pH(pzc) of the adsorbents, which may be interpreted by taking into account the electrostatic forces present. 相似文献
82.
A new method of polymer classification is described involving dynamic mechanical analysis of polymer properties as temperature is changed. The method is based on the chemometric analysis of the damping factor (tan delta) as a function of temperature. In this study four polymer groups, namely, polypropylene, low density polyethylene, polystyrene and acrylonitrile-butadiene-styrene, each characterised by different grades, were studied. The aim is to distinguish polymer groups from each other. The polymers were studied over a temperature range of -50 degrees C until the minimum stiffness was reached, tan delta values were recorded approximately every 1.5 degrees . Principal components analysis was performed to visualise groupings and also for feature reduction prior to classification and clustering. Several clustering and classification methods were compared including k-means clustering, hierarchical cluster analysis, linear discriminant analysis, k-nearest neighbours, and class distances using both Euclidean and Mahalanobis measures. It is demonstrated that thermal analysis together with chemometrics provides excellent discrimination, representing a new approach for characterisation of polymers. 相似文献
83.
A chiral separation method for glycidol enantiomers determination by normal-phase high-performance liquid chromatography coupled to atmospheric pressure chemical ionization mass spectrometry was developed. Two chiral stationary phases, amylose tris-(3,5-dimethylphenylcarbamate) (Chiralpak AD-H) and (S)-indoline-2-carboxylic acid and (R)-1-(α-naphthyl) ethylamine (SUMICHIRAL OA-4900) have been investigated. The effects of the mobile phase composition, elution program and column temperature were also studied. Under the best conditions: Chiralpak AD-H column, mobile phase composition n-hexane:ethanol (70:30, v/v), flow rate of 0.8 mL/min and 40 °C column temperature, a good resolution (Rs = 1.6) for both enantiomers has been achieved with an analysis time of 16 min. The method was found to be linear in the range from 100 to 500 ppm for both glycidol enantiomers with a good determination coefficient (r2 higher than 0.99) and good precision. Limits of detection of 31 and 50 ppm for (R)-(+)-glycidol and (S)-(−)-glycidol, respectively, were obtained. The method was applied to the determination of the enantiomeric excess and yield obtained in a asymmetric epoxidation process of allyl alcohol with a chiral titanium-tartrate complex as catalyst. 相似文献
84.
Luiz F.O. Faria Fábio R. Pereira 《Journal of Mathematical Analysis and Applications》2010,368(2):578-586
In this paper, the authors establish the existence of solutions for a class of elliptic exterior problems involving convection terms and nonlinear Robin boundary conditions. The proof of the result is made by combining Galerkin method with a priori estimates for this kind of problem. 相似文献
85.
Lilian R. Avila Emerson H. de Faria Katia J. Ciuffi Eduardo J. Nassar Paulo S. Calefi Miguel A. Vicente Raquel Trujillano 《Journal of colloid and interface science》2010,341(1):186-193
Functionalization of Brazilian São Simão kaolinite and Spanish Yunclillos saponite with the alkoxysilanes 3-aminopropyltriethoxysilane and 3-mercaptopropyltrimethoxysilane is reported. The resulting hybrids were characterized by X-ray diffraction, thermal analysis, infrared absorption spectroscopy, and scanning electron microscopy, which demonstrated the effectiveness of the interlamellar grafting process. The X-ray diffractograms revealed incorporation of the alkoxide molecules into the interlayer space of the clays. The displacement of the stretching bands of interlayer hydroxyls in the infrared spectra of the modified kaolinites and the increased intensity of the Mg–OH vibrations in the spectra of the modified saponites confirmed the functionalization of the clays. The thermal behavior of the organoclays confirmed the stability of the hybrids, which was dependent on the clay used for preparation of the materials. 相似文献
86.
A flow injection/conductometric method is proposed for determing ammonia in solutions obtained from Kjeldahl digestion. The method is based on diffusion of ammonia through a PTFE membrane from an alkaline (NaOH/EDTA) medium to a deionized water stream. The change in conductance of the deionized water stream is proportional to the ammonia concentration present in the digest. The effects of flow parameters, temperature and potential interferences are reported. Approximately 100 samples can be injected per hour; the precision is about 1%. Results for total nitrogen in vegetable tissues, animal feeds and fertilizers are in good agreement with those obtained by the usual distillation/titration method. 相似文献
87.
Luiz H. C. Mattoso Roberto M. Faria Luis O. S. Bulhes Alan G. MacDiarmid 《Journal of polymer science. Part A, Polymer chemistry》1994,32(11):2147-2153
High molecular weight poly(o-methoxyaniline) was synthesized using a novel method in which the polymerization occurs in the presence of a neutral salt. The molecular weight of the polymer was greatly affected by the quenching procedure employed to conclude the polymerization. Conventional doping of the base form of poly(o-methoxyaniline) produced a yellow coloration of the doping solution and polymer degradation. It was found that the molecular weight of the polymer decreased significantly after washing or doping with certain aqueous acid media. The gelation conditions of N-methyl pyrrolidinone (NMP) solutions and film preparation were also investigated for polymers of various molecular weights. The gelation time in NMP decreased drastically with the increase in the polymer molecular weight (the same for solution concentration and temperature), until a critical point was reached after which its decrease was very slow. Flexible, free-standing, and stretchable films were readily obtained from the higher molecular weight polymers. Good quality doped gel films with conductivity of up to 1 S/cm were obtained under optimized doping conditions. © 1994 John Wiley & Sons, Inc. 相似文献
88.
Faria Luis F. Figueiredo Gimenes Maria Antonieta P. Nobrega Ronaldo Pereira Nei 《Applied biochemistry and biotechnology》2002,98(1-9):449-458
Oxygen availability is the most important environmental parameter in the production of xylitol by yeasts, directly affecting
yields and volumetric productivity. This work evaluated the cell behavior in fermentations carried out with different dissolved
oxygen concentrations (0.5–30.0% of saturation), as well as a limited oxygen restriction (0% of saturation), at several oxygen
volumetric transfer coefficients (12 ≤ k
L
a ≤ 70 h−1). These experiments allowed us to establish the specific oxygen uptake rate limits to ensure high yields and volumetric productivity.
When oxygen availability was limited, the specific oxygen uptake rate values were between 12 and 26 mg of O2/of g cell·h, resulting in a yield of 0.71 g of xylitol/xylose consumed, and 0.85 g/[L·h] for the volumetric productivity.
According to the results, the effective control of the specific oxygen uptake rate makes it possible to establish complete
control over this fermentative process, for both cell growth and xylitol production. 相似文献
89.
Hanane Boumeriame Eliana S.Da Silva Alexey S.Cherevan Tarik Chafik Joaquim L.Faria Dominik Eder 《Journal of Energy Chemistry》2022,(1):406-431
The high energy demand we currently face in society and the subsequent large consumption of fossil fuels cause its depletion and increase the pollution levels.The quest for the production of clean energy from renewable and sustainable sources remains open.The conversion of solar energy into hydrogen via the water-splitting process,assisted by pho tores pons ive semiconductor catalysts,is one of the most promising technologies.Significant progress has been made on water splitting in the past few years and a variety of photocatalysts active not only under ultra-violet(UV) light but especially with the visible part of the electromagnetic spectrum have been developed.Layered double hydroxides(LDH)-based materials have emerged as a promising class of nanomaterials for solar energy applications owing to their unique layered structure,compositional flexibility,tunable bandgaps,ease of synthesis and low manufacturing costs.This review covers the most recent research dedicated to LDH materials for photocatalytic water-splitting applications and encompasses a range of synthetic strategies and post-modifications used to enhance their performance.Moreover,we provide a thorough discussion of the experimental conditions crucial to obtaining improved photoactivity and highlight the impact of some specific parameters,namely,catalysts loading,cocatalysts,sacrificial agents,and irradiation sources.This review provides the necessary tools to select the election technique for adequately enhancing the photoactivity of LDH and modified LDH-based materials and concludes with a critical summary that outlines further research directions. 相似文献
90.
Edson de Faria 《Proceedings of the American Mathematical Society》1998,126(1):67-74
Using general bounds on the conformal distortion of univalent maps, we prove a strong version of Sullivan's sector theorem, which gives certain sufficient conditions for an arbitrarily long composition of univalent Herglotz functions to map the upper half-plane into a proper sub-sector.