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101.
S. Boileau R. Ben Khalifa A. Jallouli L. Lestel D. Teyssi 《Macromolecular Symposia》1995,98(1):687-687
Polycarbosilane networks were prepared from well-defined α, ω-difunctional oligomers: X-[Si(CH3)2-CH2-CH2]n-X with X = H ( 1 ) and X = CH=CH2 ( 2 ). Crosslinking reactions were performed by hydrosilylation of tetramethyltetravinylcyclotetrasiloxane (V4) or of tetravinylsilane with SiH end groups of 1 . Hydrosilylation of Si-CH=CH2 end groups of 2 with tetramethyltetrahydrocyclotetrasiloxane (D4H) was also successfully tried. Some physicochemical properties of these new networks will be presented.1) Interpenetrating networks based on polysiloxanes and polycarbonates were synthesized by the in situ method: a polysiloxane bearing various proportions of room temperature crosslinkable -Si(OEt)3 side groups was mixed with bis(allyl ethylene glycol) biscarbonate and a free-radical initiator. After the formation of the first network at room temperature, the cross-linking of the polycarbonate network was performed by raising the temperature up to 80°C. Various chemical modifications of the polysiloxane component in the IPN were performed in order to improve the degree of interpenetration as estimated from turbidity, density, refractive index and DSC measurements.2) 相似文献
102.
Imen Ben Atitallah Georgia Antonopoulou Ioanna Ntaikou Amaia Soto Beobide Vassilios Dracopoulos Tahar Mechichi Gerasimos Lyberatos 《Molecules (Basel, Switzerland)》2022,27(4)
The effect of different pretreatment approaches based on alkali (NaOH)/hydrogen peroxide (H2O2) on willow sawdust (WS) biomass, in terms of delignification efficiency, structural changes of lignocellulose and subsequent fermentation toward ethanol, was investigated. Bioethanol production was carried out using the conventional yeast Saccharomyces cerevisiae, as well as three non-conventional yeasts strains, i.e., Pichia stipitis, Pachysolen tannophilus, Wickerhamomyces anomalus X19, separately and in co-cultures. The experimental results showed that a two-stage pretreatment approach (NaOH (0.5% w/v) for 24 h and H2O2 (0.5% v/v) for 24 h) led to higher delignification (38.3 ± 0.1%) and saccharification efficiency (31.7 ± 0.3%) and higher ethanol concentration and yield. Monocultures of S. cerevisiae or W. anomalus X19 and co-cultures with P. stipitis exhibited ethanol yields in the range of 11.67 ± 0.21 to 13.81 ± 0.20 g/100 g total solids (TS). When WS was subjected to H2O2 (0.5% v/v) alone for 24 h, the lowest ethanol yields were observed for all yeast strains, due to the minor impact of this treatment on the main chemical and structural WS characteristics. In order to decide which is the best pretreatment approach, a detailed techno-economical assessment is needed, which will take into account the ethanol yields and the minimum processing cost. 相似文献
103.
In this paper the effective mass approximation and the k·p multi-band models, describing quantum evolution of electrons in
a crystal lattice, are discussed. Electrons are assumed to move in both a periodic potential and a macroscopic one. The typical
period e{\epsilon} of the periodic potential is assumed to be very small, while the macroscopic potential acts on a much bigger length scale.
Such homogenization asymptotic is investigated by using the envelope-function decomposition of the electron wave function.
If the external potential is smooth enough, the k·p and effective mass models, well known in solid-state physics, are proved
to be close (in the strong sense) to the exact dynamics. Moreover, the position density of the electrons is proved to converge
weakly to its effective mass approximation. 相似文献
104.
We describe a protocol for distilling maximally entangled bipartite states between random pairs of parties from those sharing a tripartite W state |W=(1/sqrt[3])(|100+|010+|001)(ABC), and show that the total distillation rate E(t)(infinity) [the total number of Einstein-Podolsky-Rosen (EPR) pairs distilled per W, irrespective of who shares them] may be done at a higher rate than EPR distillation between specified pairs of parties. Specifically, the optimal rate for distillation to specified parties has been previously shown to be 0.92 EPR pairs per W, while our protocol can asymptotically distill 1 EPR pair per W between random pairs of parties, which we conjecture to be optimal. We thus demonstrate a tradeoff between overall distillation rate and final distribution of EPR pairs. We further show that there exist states with fixed lower-bounded E(t)(infinity), but arbitrarily small distillable entanglement for specified parties. 相似文献
105.
Journal of Solid State Electrochemistry - Transparent thin films of pure ZnO, Ca-doped ZnO (CZO), and Ga-doped ZnO (GZO) were deposited on glass by RF magnetron sputtering. The influence of calcium... 相似文献
106.
Dr. Haoxuan Li Haifei Wen Dr. Zhijun Zhang Dr. Nan Song Prof. Ryan T. K. Kwok Prof. Jacky W. Y. Lam Prof. Lei Wang Prof. Dong Wang Prof. Ben Zhong Tang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(46):20551-20555
Using reverse thinking of the aggregation-induced emission (AIE) principle, we demonstrate an ingenious and universal protocol for amplifying molecular motions to boost photothermal efficiency of fibers. Core–shell nanofibers having the olive oil solution of AIE-active molecules as the core surrounded by PVDF-HFP shell were constructed by coaxial electrospinning. The molecularly dissolved state of AIE-active molecules allows them to freely rotate and/or vibrate in nanofibers upon photoexcitation and thus significantly elevates the proportion of non-radiative energy dissipation, affording impressive heat-generating efficiency. Photothermal evaluation shows that the core–shell nanofibers with excellent durability can reach up to 22.36 % of photothermal conversion efficiency, which is 26-fold as the non-core–shell counterpart. Such a core–shell fiber can be used for photothermal textiles and solar steam generation induced by natural sunlight with green and carbon-zero emission. 相似文献
107.
Ben’ko E. M. Lunin V. V. 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2018,92(9):1794-1798
Russian Journal of Physical Chemistry A - A comparative study of the sorption properties of lignocellulosic plant materials (aspen and pine wood and wheat straw) is performed using the cationic dye... 相似文献
108.
In several applications, underestimation of functions has proven to be a helpful tool for global optimization. In protein–ligand
docking problems as well as in protein structure prediction, single convex quadratic underestimators have been used to approximate
the location of the global minimum point. While this approach has been successful for basin-shaped functions, it is not suitable
for energy functions with more than one distinct local minimum with a large magnitude. Such functions may contain several
basin-shaped components and, thus, cannot be underfitted by a single convex underestimator. In this paper, we propose using
an underestimator composed of several negative Gaussian functions. Such an underestimator can be computed by solving a nonlinear
programming problem, which minimizes the error between the data points and the underestimator in the L
1 norm. Numerical results for simulated and actual docking energy functions are presented. 相似文献
109.
In hydraulic turbines, the tip-leakage vortex is responsible for flow instabilities and for promoting erosion due to cavitation. To better understand the tip vortex flow, Reynolds-averaged Navier–Stokes (RANS) and large eddy simulation (LES) computations are carried out to simulate the flow around a NACA0009 blade including the gap between the tip and the wall. The main focus of the study is to understand the influence of the gap width on the development of the tip vortex, as for instance its trajectory. The RANS computations are performed using the open source solver OpenFOAM 2.1.0, two incidences and five gaps are considered. The LESs are achieved using the YALES2 solver for one incidence and two gaps.The validation of the results is performed by comparisons with experimental data available downstream the trailing edge. The position of the vortex core, the mean velocity and the mean axial vorticity fields are compared at three different downstream locations. The results show that the mean behaviour of the tip vortex is well captured by the RANS and LES computations compared to the experiment. The LES results are also analysed to bring out the influence of the gap width on the development of the tip-leakage vortex. Finally, a law that matches the vortex trajectory from the leading edge to the mid-chord is proposed. Such a law can be helpful to determine, in case of cavitation, if the tip vortex will interact with the walls and cause erosion. 相似文献
110.
Doble N Yoon G Chen L Bierden P Singer B Olivier S Williams DR 《Optics letters》2002,27(17):1537-1539
Ophthalmic instrumentation equipped with adaptive optics offers the possibility of rapid and automated correction of the eye's optics for improving vision and for improving images of the retina. One factor that limits the widespread implementation of adaptive optics is the cost of the wave-front corrector, such as a deformable mirror. In addition, the large apertures of these elements require high pupil magnification, and hence the systems tend to be physically large. We present what are believed to be the first closed-loop results when a compact, low-cost, surface micromachined, microelectromechanical mirror is used in a vision adaptive-optics system. The correction performance of the mirror is shown to be comparable to that of a Xinetics mirror for a 4.6-mm pupil size. Furthermore, for a pupil diameter of 6.0-mm, the residual rms error is reduced from 0.36 to 0.12 microm and individual photoreceptors are resolved at a pupil eccentricity of 1 degrees from the fovea. 相似文献