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排序方式: 共有209条查询结果,搜索用时 23 毫秒
201.
202.
Umme S. Siddiqui Farah Khan Iqrar A. Khan Kabir-ud-Din 《Journal of solution chemistry》2012,41(7):1133-1143
The effect of adding aliphatic alcohols (C4OH, C5OH, C6OH) and corresponding amines (C4NH2, C5NH2, C6NH2) on a series of dicationic gemini surfactants with the general formula C14H29(CH3)2N+?C(CH2)s?CN+(CH3)2C14H29, 2Br? (14-s-14; s=4,5,6), in the absence and presence of KNO3, has been studied by viscosity measurements at 303.15?K. As the chain length of the additive increased, the viscosity increased with increasing additive concentration and the extent of the effect followed the sequence: C6OH>C5OH>C4OH; C6NH2>C5NH2>C4NH2. The simultaneous presence of salt and additives showed an increase in ?? r values due to a synergistic effect. However, for equal chain lengths in the additives, the effect was greater for the n-alcohols. The tendency for the micelles to grow from spherical to rod-like structures is mainly influenced by the spacer chain length. At 303.15?K, the micellar growth was more pronounced for the shorter spacer, i.e. s being 4, which can be interpreted in terms of the short spacer having a higher tendency for micellar growth. Contrary to the cationic geminis, no effect was observed with a conventional surfactant of equal chain length, TTAB, even in the presence of KNO3 at the same concentration used for the geminis. 相似文献
203.
Olsen CA Christensen C Nielsen B Farah MM Mohamed FM Witt M Clausen RP Kristensen JL Franzyk H Jaroszewski JW 《Organic letters》2006,8(15):3371-3374
[Structure: see text] Solid-phase synthesis is a rapidly developing area of organic chemistry, of particular importance for medicinal chemistry and chemical biology. Aziridines have previously only rarely been applied in solid-phase synthesis. In the present work, aminolysis of resin-bound, spring-loaded N-nitrobenzenesulfonyl-activated aziridine-2-carboxylic acids has been optimized and employed in the synthesis of a number of open-chain and heterocyclic scaffolds, including enantiopure products. 相似文献
204.
Farah Diana Mahad Abu Sahmah M. Supa’at Sevia Mahdaliza Idrus David Forsyth 《Optik》2012,123(2):95-99
Spectrum-slicing techniques employing incoherent light are an economic, practical and therefore attractive solution for future all-optical networks, especially for wavelength-division multiplexing (WDM) transmission systems in local area networks (LAN). However, spectrum-sliced methods exhibit a large excess intensity noise factor that limits the performance of the system. In this paper, we investigate noise suppression of spectrum-sliced incoherent light using a saturated semiconductor optical amplifier (SOA). The system incorporating the noise reducing SOA is modeled and simulated using OptSim software, and the results are compared to practical schemes from the literature. Performance comparisons are made with two different broadband sources test-beds. The characteristics of the SOA gain saturation are also presented. In both cases, it is found that a high degree of intensity noise is suppressed by the use of the non-linear gain saturation characteristics of the SOA so as to achieve better system performance. The position of a modulator in the system is also investigated in order to greatly reduce the excess intensity noise. 相似文献
205.
Saiful Izwan Abd Razak Farah Nuruljannah Dahli Izzati Fatimah Wahab Mohammed Rafiq Abdul Kadir Ida Idayu Muhamad Abdul Halim Mohd Yusof 《Soft Materials》2016,14(2):78-86
This paper reports for the first time a simple yet effective method for fabricating a conductive and highly porous scaffold material made up of polylactic acid (PLA) and conducting polyaniline (PANI). The electrical percolation state was successfully obtained at 3 wt% of PANI inclusions and reached a conductivity level of useable tissue engineering applications at 4 wt%. In addition, preliminary bioactivity test results indicated that the protonating agent could form a chelate at the scaffold surface leading to good in-vitro apatite forming ability during biomimetic immersion. This new conductive scaffold has potential as a suitable biomedical material that requires electrical conductivity. 相似文献
206.
The kinetics of the oxidation of [Ni(II)(H2L1)](ClO4)2, (H2L1 = 3,8-dimethyl-4,7-diaza-3,7-decadiene-2,9-dione dioxime) and [Ni(II)(HL2)]ClO4, (H2L2 = 3,9-dimethyl-4,8-diaza-3,8-undecadiene-2,10-dione dioxime) by peroxodisulfate anion (PDS) in aqueous media at 298.0 K have been studied. The kinetics of oxidation of both Ni(II) complexes was found to be first order in the complex concentration. The dependence of the pseudo-first-order rate constant, k obs, for both complexes showed first-order dependence on PDS concentration. The kinetics of oxidation of [Ni(II)(H2L1)]2+ complex showed a complex dependence on [H+] over the pH range of 4.98–7.50, whereas that of [Ni(II)(HL2)]+ is independent of pH over the pH range of 5.02–7.76. The value of k obs, for both complexes, decreased with increasing ionic strength consistent with the involvement of oppositely charged ions in the rate-determining step. The effect of ionic strength is more pronounced for [Ni(II)(H2L1)]2+–PDS reaction than for [Ni(II)(HL2)]+–PDS reaction, confirming the higher charges of the latter. 相似文献
207.
Hidayat Hussain Natalia Root Farah Jabeen Ahmed Al-Harrasi Ahmed Al-Rawahi Manzoor Ahmad Zahid Hassan Ghulam Abbas Fazal Mabood Afzal Shah Amin Badshah Amjad Khan Riaz Ahmad Ivan R. Green Siegfried Draeger Barbara Schul Karsten Krohn 《中国化学快报》2014,25(12):1577-1579
A new metabolite,named seimatoric acid(1),representing a new oxobutanoic acid derivative has been isolated from Seimatosporium sp., in addition to four known compounds viz.,2-hydroxymethyl-4β,5α,6β-trihydroxycyclohex-2-enone(2),(-)-phyllostine(3),(+)-epiepoxydon(4) and(+)-epoxydon monoacetate(5).Similarly one new benzoic acid derivative,named colletonoic acid(6) was isolated from the ethyl acetate fraction of Colletotrichum sp.The structures of the new compounds were elucidated by detailed ~1 H NMR,~(13)C NMR,COSY,HMQC.HMBC spectroscopic analysis,and HR-E1-MS.Seimatoric acid(1)was also isolated from another taxonomical unidentified fungal strain 4295 in ourgroup.The structures of the known compounds were elucidated by their spectral data comparison to literature data.Preliminary studies showed that colletonoic acid(6) showed good antibacterial,antifungal,and antialgal activities. 相似文献
208.
Ilijas Farah 《Transactions of the American Mathematical Society》2004,356(6):2197-2239
We isolate a class of ideals on that includes all analytic P-ideals and all ideals, and introduce `Luzin gaps' in their quotients. A dichotomy for Luzin gaps allows us to freeze gaps, and prove some gap preservation results. Most importantly, under PFA all isomorphisms between quotient algebras over these ideals have continuous liftings. This gives a partial confirmation to the author's rigidity conjecture for quotients . We also prove that the ideals and have the Radon-Nikodým property, and (using OCA) a uniformization result for -coherent families of continuous partial functions.
209.
We prove real Paley-Wiener type theorems for the Dunkl transform ℱ
D
on the space
of tempered distributions. Let T∈S′(ℝ
d
) and Δ
κ
the Dunkl Laplacian operator. First, we establish that the support of ℱ
D
(T) is included in the Euclidean ball
, M>0, if and only if for all R>M we have lim
n→+∞
R
−2n
Δ
κ
n
T=0 in S′(ℝ
d
). Second, we prove that the support of ℱ
D
(T) is included in ℝ
d
∖B(0,M), M>0, if and only if for all R<M, we have lim
n→+∞
R
2n
ℱ
D
−1(‖y‖−2n
ℱ
D
(T))=0 in S′(ℝ
d
). Finally, we study real Paley-Wiener theorems associated with
-slowly increasing function.
相似文献