全文获取类型
收费全文 | 164篇 |
免费 | 10篇 |
专业分类
化学 | 156篇 |
晶体学 | 1篇 |
数学 | 10篇 |
物理学 | 7篇 |
出版年
2023年 | 1篇 |
2022年 | 3篇 |
2021年 | 7篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 2篇 |
2016年 | 5篇 |
2015年 | 11篇 |
2014年 | 4篇 |
2013年 | 6篇 |
2012年 | 15篇 |
2011年 | 23篇 |
2010年 | 10篇 |
2009年 | 8篇 |
2008年 | 13篇 |
2007年 | 7篇 |
2006年 | 10篇 |
2005年 | 9篇 |
2004年 | 7篇 |
2003年 | 3篇 |
2002年 | 3篇 |
2001年 | 5篇 |
2000年 | 1篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1985年 | 1篇 |
1981年 | 1篇 |
1977年 | 2篇 |
1955年 | 1篇 |
1927年 | 2篇 |
排序方式: 共有174条查询结果,搜索用时 15 毫秒
41.
Bonnet F Visseaux M Barbier-Baudry D Hafid A Vigier E Kubicki MM 《Inorganic chemistry》2004,43(12):3682-3690
The reaction of Ln(BH(4))(3)(THF)(3) or LnCl(3)(THF)(3) with 1 equiv of KCp*' ligand (Cp' = C(5)Me(4)n-Pr) afforded the new monocyclopentadienyl complexes Cp*'LnX(2)(THF)(n) (X = BH(4), Ln = Sm, n = 1, 1a, Ln = Nd, n = 2, 1b; X = Cl, Ln = Sm, n = 1, 3a) and [Cp*'LnX(2)](n') (X = BH(4), n' = 6, Ln = Sm, 2a, Ln = Nd, 2b; X = Cl, Ln = Nd, 4b). All these compounds were characterized by elemental analysis and (1)H NMR. Crystals of mixed borohydrido/chloro-bridged [Cp*'(6)Ln(6)(BH(4))(12-x))Cl(x)(THF)(n')] (x = 10, n' = 4, Ln = Sm, 2a', Ln = Nd, 2b'; x = 5, n = 2, Ln = Sm, 2a' ') were also isolated. Compounds 2a, 2b, 2a', 2b', and 2a' were structurally characterized; they all exhibit a hexameric structure in the solid state containing the [Cp*(3)Ln(3)X(5)(THF)] building block. The easy clustering of THF adducts first isolated is illustrative of the well-known bridging ability of the BH(4) group. Hexameric 2a was found to be unstable in the presence of THF vapors; this may be correlated to the opening of unsymmetrical borohydride bridges observed in the molecular structure. 相似文献
42.
Dr. Cécilia Ménard‐Moyon V. Venkatesh Dr. K. Vijaya Krishna Dr. Fanny Bonachera Prof. Sandeep Verma Dr. Alberto Bianco 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(33):11681-11686
In the context of designing novel amino acid nanostructures, the capacity of tyrosine alone to form well‐ordered structures under different conditions was explored. It was observed that Tyr can self‐assemble into well‐defined morphologies when deposited onto surfaces for transmission electron microscopy, atomic force microscopy, and scanning electron microscopy. The influence of various parameters that can modulate the self‐assembly process, including concentration of the amino acid, aging time, and solvent, was studied. Different supramolecular architectures, including nanoribbons, branched structures, and fern‐like arrangements were also observed. 相似文献
43.
Laura Trapiella-Alfonso Fanny d’Orlyé Anne Varenne 《Analytical and bioanalytical chemistry》2016,408(11):2669-2675
44.
45.
46.
Fanny Kieken Gaud Pinel Jean-Philippe Antignac Fabrice Monteau Anne Christelle Paris Marie-Agnès Popot Yves Bonnaire Bruno Le Bizec 《Analytical and bioanalytical chemistry》2009,394(8):2119-2128
Despite the worldwide existing regulation banning the use of the recombinant equine growth hormone (reGH) as growth promoter,
it is suspected to be used in horseracing to improve performances. Various analytical methods previously developed to screen
for its misuse have encountered some limitations in terms of detection timeframes, in particular during the first days following
reGH administration. A novel strategy involving the characterization of global metabolomic fingerprints in urine samples of
non-treated and reGH-treated horses by liquid chromatography–electrospray–high-resolution mass spectrometry (LC-ESI-HRMS)
is described and assessed in this paper in order to develop a new screening tool for growth hormone abuse in horseracing.
The strategy involves a limited sample preparation of the urine samples and the use of appropriate software for data processing
and analysis. As preliminary work, reproducibility of both sample preparation and mass spectrometry (MS) measurements was
evaluated in order to demonstrate the reliability of the method. Application of the developed protocol on two horses demonstrated
the suitability of the developed strategy and preliminary results showed significant modifications of the metabolome after
treatment with reGH.
相似文献
47.
Xue-Mei Gao Fanny Shuk Fan Lai Chun-Feng Qiao Xin Liu Kathy Qian Luo Hong-Xi Xu 《Tetrahedron letters》2010,51(18):2442-2446
Four novel polyisoprenylated benzophenone derivatives, paucinones A-D (1-4), were isolated from the leaves of the plant Garcinia paucinervis. Paucinones A-C (1-3) contained an unexpected cyclohexane-spiro-tetrahydrofuran moiety. A 1-methylene-3,3-dimethylcyclohexane group never reported before was found in the structure of paucinone D (4). The structures of these compounds were elucidated with spectroscopic evidences. The relative stereochemistries of 1-4 were determined by NOESY correlations. These compounds showed significant cytotoxicities against HeLa cells. 相似文献
48.
M. Eugenia Sesto Cabral Fanny I. Schabes E. Elizabeth Sigstad 《Thermochimica Acta》2010,497(1-2):14-20
The effect of the CHCl3 and MeOH extracts from aerial parts from the Northwestern Argentina endemic species Ixorhea tschudiana Fenzl. on germination of the dicot tomato and the monoct onion and on soil microbial activity was studied by calorimetric and calorespirometric experiments. The CHCl3 extract inhibited seedling growth of tomato which increased with increasing concentrations. Seeds imbibed with 250 mg dm?3 extract germinated 24 h later than control and those imbibed with 100 and 500 mg dm?3 extract. This was reflected in the calculated low specific seedling growth rate (pSGΔHB) as determined from calorespirometric experiments. On the other hand, seedlings obtained in 500 mg dm?3 extract showed shorter and thicker hairy roots than control with significantly higher pSGΔHB. Probably, the extract induces inhibition of water uptake by seedling roots. Germination was reduced 50% in onion seeds imbibed with 500 mg dm?3 CHCl3 extract which apparently is due to higher rate of imbibition during the first stages as determined for calorimetry. On the other hand, 83 and 250 mg kg?1 of the MeOH and CHCl3 extract seem to selectively inhibit the growth of certain microorganisms and to enhance the activity of soil actinomycetes. Two actinobacteria were isolated from soil treated with these concentrations of both extracts: Kocuria sp. and Kocuria rosea; this latter species is known as a keratinolytic agent and seems to degrade complex carbon compounds of the soil and those incorporated by the MeOH extract. Both Kocuria specie seem to be beneficial for the soil converting substrate into biomass and thus I. tschudiana could be used as a soil phytoremediator. 相似文献
49.
50.
Anosov representations of word hyperbolic groups into higher-rank semisimple Lie groups are representations with finite kernel and discrete image that have strong analogies with convex cocompact representations into rank-one Lie groups. However, the most naive analogy fails: generically, Anosov representations do not act properly and cocompactly on a convex set in the associated Riemannian symmetric space. We study representations into projective indefinite orthogonal groups \(\mathrm {PO}(p,q)\) by considering their action on the associated pseudo-Riemannian hyperbolic space \(\mathbb {H}^{p,q-1}\) in place of the Riemannian symmetric space. Following work of Barbot and Mérigot in anti-de Sitter geometry, we find an intimate connection between Anosov representations and a natural notion of convex cocompactness in this setting. 相似文献