对氨基马尿酸铽二元、三元配合物的合成、表征及荧光光谱研究

在乙醇溶液中以邻菲咯啉(phen)、2,2’-联吡啶(bipy)和对氨基马尿酸(PAH,HL)为配体与铽离子(Tb(Ⅲ))合成了二元和三元稀土配合物。通过元素分析、差热-热重分析、紫外光谱、红外光谱分析,确定了配合物的组成为TbL₃(1)、TbL₃·phen·H₂O(2)和TbL₃·bipy·H₂O(3),并讨论了配合物1～3的谱学性质和荧光性能。推测出羧基中的氧原子以桥式双齿的形式与稀土离子配位。由红外光谱和热分析测试确定的配合物1及配合物2中的水分子未参与配位。研究表明,铽配合物在489,583和621 nm处出现发射峰,它们分别归属于5D₄→7F₆,5D₄→7F₅,5D₄→7F₄和5D₄→7F₃的跃迁。其中544 nm处5D₄→7F₅跃迁的强度最强,配体的共平面性和共轭性越大,配合物的荧光性能越高,三元配合物TbL₃·phen·H₂O和TbL₃·bipy·H₂O的荧光强度优于二元配合物TbL₃的荧光强度。     

Low resistance dye-sensitized solar cells based on all-titanium substrates using wires and sheets

Low resistance dye-sensitized solar cells (DSSCs) based on all-titanium substrates were proposed in this paper. To minimize the internal resistance of DSSCs, the titanium wires and titanium sheets were used as the substrates of the photoanode and the counter electrode, respectively. Compared with the FTO substrate, titanium wires could absorb much diffused light by back reflection since the reflectivity in the titanium sheet was highly increased up to 53.12%. Furthermore, the transmittance of the front cover was increased by 13.2% using the super white glass instead of FTO substrate. The thickness of TiO₂ thin film coated on titanium wire was optimized to achieve a high cell performance. The efficiency of 5.6% for the cell was obtained with a J_sc of 15.41 mA cm⁻², V_oc of 0.59 V, and FF of 0.62. The results showed that the titanium-based DSSCs had superiority for producing the large-scale DSSCs without metal grid line.     

PERMANENCE AND GLOBAL STABILITY OF A FEEDBACK CONTROL SYSTEM WITH DELAYS

This paper considers a feedback control systems of differential equations with delays. By applying the differential inequality theorem, sufficient conditions for the permanence of the system are obtained. Also, by constructing a suitable Lyapunov functional, a criterion for the global stability of the model is obtained.     

快速凝固Cu-Pb过偏晶合金的性能表征

研究了Cu-Pb过偏晶合金的急冷快速凝固组织特征,定量表征了快速凝固Cu-Pb过偏晶合金的电阻率和力学性能,理论分析了冷却速率和组织形态对合金性能的影响规律. 研究结果表明,在急冷快速凝固条件下,Cu-Pb过偏晶合金中的(Cu)相和(Pb)相均以枝晶方式生长,晶体形态以均匀细小的等轴晶为特征. 随着冷却速率增大,一方面,凝固组织显著细化,晶界增多,对自由电子的散射作用增强,合金电阻率显著增大;另一方面,细晶强化作用增强,合金的抗拉强度呈线性升高,同时,伴随着晶体缺陷数量的增多,合金的伸长率降低. 关键词： Cu-Pb过偏晶合金 快速凝固 电阻率 力学性能     

Generation of time-dependent ultra-short optical pulse trains in the presence of self-steepening effect

Starting from the extended nonlinear Schr?dinger equation in which the self-steepening effect is included, the evolution and the splitting processes of continuous optical wave whose amplitude is perturbed into time related ultra-short optical pulse trains in an optical fibre are numerically simulated by adopting the split-step Fourier algorithm. The results show that the self-steepening effect can cause the characteristic of the pulse trains to vary with time, which is different from the self-steepening-free case where the generated pulse trains consist of single pulses which are identical in width, intensity, and interval, namely when pulses move a certain distance, they turn into the pulse trains within a certain time range. Moreover, each single pulse may split into several sub-pulses. And as time goes on, the number of the sub-pulses will decrease gradually and the pulse width and the pulse intensity will change too. With the increase of the self-steepening parameter, the distance needed to generate time-dependent pulse trains will shorten. In addition, for a large self-steepening parameter and at the distance where more sub-pulses appear, the corresponding frequency spectra of pulse trains are also wider.     

热带对流活动日变化的模拟研究

利用一个云分辨与海洋的耦合模式,模拟研究了热带对流活动的日变化.通过对模拟结果的分析,揭示了热带地区不同海温日变化条件下,对流活动的云物理特征.利用热带海洋与全球大气响应观测实验（TOGA COARE）的观测资料作为模式的初始与边界场,来驱动耦合模式.对热带海表温度按照其日变化幅度的大小进行了分类,分为强、弱海表温度日变化两种类型,并在此基础上进行了合成分析.结果表明：1）在弱的海表温度日变化下,云中的云冰含量大于云水含量,说明云中以层状云为主;而在强的海温日变化下,云中的云水含量大于云冰含量,说明云中以 关键词： 热带对流日变化 地面降水率 云冰含量 云水含量     

一个新四维自治超混沌系统及其电路实现

提出了一个新的四维超混沌系统,并对该系统的基本动力学特性进行了深入研究,得到该系统的LE,LE维数,给出了Poincare映射图、LE谱、分岔图以及时域图和相图.利用Mutisim软件设计了该新混沌系统的振荡电路并进行了仿真实验.经过数值仿真和电路系统仿真证实该系统与以往发现的混沌吸引子并不拓扑等价,属于新的混沌系统. 关键词： 超混沌系统 Lyapunov指数 Poincare截面图 电路实现     

Convergence Properties of a Self-adaptive Levenberg-Marquardt Algorithm Under Local Error Bound Condition

We propose a new self-adaptive Levenberg-Marquardt algorithm for the system of nonlinear equations F(x) = 0. The Levenberg-Marquardt parameter is chosen as the product of ‖F_k‖^δ with δ being a positive constant, and some function of the ratio between the actual reduction and predicted reduction of the merit function. Under the local error bound condition which is weaker than the nonsingularity, we show that the Levenberg-Marquardt method converges superlinearly to the solution for δ∈ (0, 1), while quadratically for δ∈ [1, 2]. Numerical results show that the new algorithm performs very well for the nonlinear equations with high rank deficiency. This work is supported by Chinese NSFC grants 10401023 and 10501013, Research Grants for Young Teachers of Shanghai Jiao Tong University, and E-Institute of Shanghai Municipal Education Commission, N. E03004.     

Mappings of finite distortion: the degree of regularity

This paper investigates the self-improving integrability properties of the so-called mappings of finite distortion. Let K(x)1 be a measurable function defined on a domain ΩRⁿ, n2, and such that exp(βK(x))L_loc¹(Ω), β>0. We show that there exist two universal constants c₁(n),c₂(n) with the following property: Let f be a mapping in W_loc^1,1(Ω,Rⁿ) with |Df(x)|ⁿK(x)J(x,f) for a.e. xΩ and such that the Jacobian determinant J(x,f) is locally in L¹ log^−c₁(n)βL. Then automatically J(x,f) is locally in L¹ log^c₂(n)βL(Ω). This result constitutes the appropriate analog for the self-improving regularity of quasiregular mappings and clarifies many other interesting properties of mappings of finite distortion. Namely, we obtain novel results on the size of removable singularities for bounded mappings of finite distortion, and on the area distortion under this class of mappings.     

金属有机物化学气相沉积法生长Ga2（1-x）In2xO3薄膜的结构及光电性能研究

采用金属有机物化学气相沉积（MOCVD）法在蓝宝石（0001）衬底上制备出了Ga_2（1-x）In_2xO₃（x=01—09）薄膜,研究了薄膜的结构、电学和光学特性以及退火处理对薄膜性质的影响.测量结果表明：当In组分x=02时,样品为单斜β-Ga₂O₃结构;x=05的样品,薄膜呈现非晶结构,退火处理后薄膜结构得到明显的改善 关键词： 金属有机物化学气相沉积 2（1-x）In_2xO₃薄膜')" href="#">Ga_2（1-x）In_2xO₃薄膜 蓝宝石衬底 退火