首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   963篇
  免费   24篇
  国内免费   5篇
化学   502篇
晶体学   2篇
力学   67篇
数学   220篇
物理学   201篇
  2023年   8篇
  2022年   14篇
  2021年   17篇
  2020年   19篇
  2019年   23篇
  2018年   19篇
  2017年   20篇
  2016年   52篇
  2015年   24篇
  2014年   32篇
  2013年   51篇
  2012年   68篇
  2011年   86篇
  2010年   49篇
  2009年   43篇
  2008年   59篇
  2007年   69篇
  2006年   41篇
  2005年   41篇
  2004年   40篇
  2003年   42篇
  2002年   24篇
  2001年   11篇
  2000年   10篇
  1999年   8篇
  1998年   4篇
  1997年   8篇
  1996年   10篇
  1995年   12篇
  1994年   11篇
  1993年   8篇
  1992年   6篇
  1991年   6篇
  1990年   4篇
  1989年   5篇
  1988年   3篇
  1987年   1篇
  1986年   8篇
  1985年   6篇
  1984年   4篇
  1983年   3篇
  1982年   2篇
  1981年   4篇
  1980年   2篇
  1979年   2篇
  1978年   3篇
  1977年   5篇
  1976年   1篇
  1974年   3篇
  1973年   1篇
排序方式: 共有992条查询结果,搜索用时 46 毫秒
151.
We show that every n‐vertex planar graph admits a simultaneous embedding without mapping and with fixed edges with any ‐vertex planar graph. In order to achieve this result, we prove that every n‐vertex plane graph has an induced outerplane subgraph containing at least vertices. Also, we show that every n‐vertex planar graph and every n‐vertex planar partial 3‐tree admit a simultaneous embedding without mapping and with fixed edges.  相似文献   
152.
Improving our comprehension of diverse CO2 activation pathways is of vital importance for the widespread future utilization of this abundant greenhouse gas. CO2 activation by uranium(III) complexes is now relatively well understood, with oxo/carbonate formation predominating as CO2 is readily reduced to CO, but isolated thorium(III) CO2 activation is unprecedented. We show that the thorium(III) complex, [Th(Cp′′)3] ( 1 , Cp′′={C5H3(SiMe3)2‐1,3}), reacts with CO2 to give the mixed oxalate‐carboxylate thorium(IV) complex [{Th(Cp′′)22‐O2C{C5H3‐3,3′‐(SiMe3)2}]}2(μ‐κ22‐C2O4)] ( 3 ). The concomitant formation of oxalate and carboxylate is unique for CO2 activation, as in previous examples either reduction or insertion is favored to yield a single product. Therefore, thorium(III) CO2 activation can differ from better understood uranium(III) chemistry.  相似文献   
153.
In this paper, we introduce some integral transforms that map slice monogenic functions to monogenic functions. We then show that one of these integral transforms, which is based on the Cauchy formula of slice monogenic functions, is useful to define a functional calculus depending on a parameter for n‐tuples of bounded operators. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
154.
155.
156.
We report the first-principle calculation and analysis of the vibrationally resolved steady-state absorption and fluorescence spectra, and of the zero-time fluorescence spectrum of a sizable molecule, coumarin C153, in two different solvents. Our approach, bringing together the most recent developments in the fields of time-dependent density functional theory and of polarizable continuum solvent models, with an efficient method for the computation of vibrational contributions to transition intensities, allows a remarkable agreement with experiments, both concerning the line shapes and the solvatochromic and Stokes shifts. The method is also able to nicely describe the solvent relaxation effect on the fluorescence spectra, perfectly reproducing the energy shift between zero-time and steady-state fluorescence.  相似文献   
157.
Mutations of the human transthyretin (TTR) gene have attracted medical interest as a cause of amyloidosis. Recently, we have described in detail an electrophoretic procedure with PAGE followed by IEF in urea gradients for the study of the microheterogeneity of TTR monomers (Altland, K., Winter, P., Sauerborn, M. K., Electrophoresis 1999, 20, 1349-1364). In this paper, we present a study on 49 different mutations of TTR including 33 that result in electrically neutral amino acid substitutions. The aims of the investigation were to test the sensitivity of the procedure to detect TTR variants in patients with TTR amyloidosis and their relatives and to identify some common characteristics that could explain the amyloidogenicity of these variants. We found that all tested amyloidogenic mutations could be detected by our method with the exception of those for which the corresponding variant was absent in plasma samples. Most of the electrically neutral amyloidogenic TTR variants had in common a reduced conformational stability of monomers by the activity of protons and urea. For three variants, e.g. TTR-F64L, TTR-I107V and TTR-V122I, the monomers had a conformational stability close to that of normal monomers but we found experimental and structural arguments for a weakening of the monomer-monomer contact. All types of amyloidogenic mutations affected the stability of TTR tetramers.  相似文献   
158.
A high-performance liquid chromatographic method for the simultaneous determination of di(2-ethylhexyl)phthalate (DEHP) and its major metabolite mono(2-ethylhexyl)phthalate (MEHP) in seminal plasma was developed and validated. The method involves liquid-liquid extraction followed by isocratic reversed-phase chromatography with diode-array detection. The recovery, selectivity, linearity, precision and accuracy of the method were evaluated from the analysis of spiked seminal plasma samples. The effect of mobile-phase composition and pH on the retention of the target analytes was investigated. The limits of detection were 0.010 and 0.015 microg/mL, for DEHP and MEHP, respectively. This method was used to analyze real samples in support of clinical studies on these potential endocrine disruptors.  相似文献   
159.
In the recent paper [Adv. Applied Math., 38 (2007), 210–226] it is proved that the special matchings of permutations generate a Coxeter group. In this paper we generalize this result to a class of Coxeter groups which includes many Weyl and affine Weyl groups. Our proofs are simpler, and shorter, than those in [loc. cit.] All authors are partially supported by EU grant HPRN-CT-2001-00272. Received: 30 October 2006  相似文献   
160.
In this paper, we present a practical approach for the characterization of critical points on conical intersection seams as either local minima or saddle points using second-derivative technology. The utility of this methodology is illustrated by the analysis of seven S0/S1 (2Ag/1Ag) conical intersection points involved in the photochemistry of butadiene. The characterization of critical points on the crossing seam requires second derivatives computed in curvilinear coordinates. Using such coordinates, we can represent the branching space and the intersection space to second order. Although these curvilinear coordinates are conceptually important, they also give rise to two additional practical applications. First, such coordinates yield information on the nature of vibrational modes that are stimulated following radiationless decay at a crossing point. Second, the second-order force field is directly comparable to experimental spectroscopic data for Jahn-Teller systems. We will illustrate the latter idea for the cyclopentadienyl radical.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号