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901.
Since the grand partition function for the so-called q-particles (i.e., quons), , cannot be computed by using the standard 2nd quantisation technique involving the full Fock space construction for , and its q-deformations for the remaining cases, we determine such grand partition functions in order to obtain the natural generalisation of the Plank distribution to . We also note the (non) surprising fact that the right grand partition function concerning the Boltzmann case (i.e., ) can be easily obtained by using the full Fock space 2nd quantisation, by considering the appropriate correction by the Gibbs factor in the n term of the power series expansion with respect to the fugacity z. As an application, we briefly discuss the equations of the state for a gas of free quons or the condensation phenomenon into the ground state, also occurring for the Bose-like quons . 相似文献
902.
Rosario Sergio Cataliotti Francesco Antolini Assuntina Morresi Fabio Santinelli Sergio Santini 《Journal of Raman spectroscopy : JRS》1988,19(6):423-428
Vibrational spectra of 2-cyanothiophene in the solid state reveal that the crystals are ordered below the freezing point and have an orthorhombic C2v unit cell. Intermolecular forces between the two molecules occupying the Bravais unit are not strong enough to promote the separation of all the Davidov doublets of the phonon states. 相似文献
903.
Aihemaiti Kayishaer Mattia Annatelli Chloe M Hansom Louis M. M. Mouterde Aurélien A. M. Peru Fabio Aricò Florent Allais Sami Fadlallah 《Macromolecular rapid communications》2024,45(2):2300483
This study focuses on the synthesis of fully renewable polycarbonates (PCs) starting from cellulose-based platform molecules levoglucosenone (LGO) and 2,5-bis(hydroxymethyl)furan (BHMF). These unique bio-based PCs are obtained through the reaction of a citronellol-containing triol (Triol-citro) derived from LGO, with a dimethyl carbonate derivative of BHMF (BHMF-DC). Solvent-free polymerizations are targeted to minimize waste generation and promote an eco-friendly approach with a favorable environmental factor (E-factor). The choice of metal catalyst during polymerization significantly influences the polymer properties, resulting in high molecular weight (up to 755 kDa) when Na2CO3 is employed as an inexpensive catalyst. Characterization using nuclear magnetic resonance confirms the successful incorporation of the furan ring and the retention of the terminal double bond of the citronellol pendant chain. Furthermore, under UV irradiation, the presence of both citronellol and furanic moieties induces singular structural changes, triggering the formation of three distinct structures within the polymer network, a phenomenon herein occurs for the first time in this type of polymer. These findings pave the way to new functional materials prepared from renewable monomers with tunable properties. 相似文献
904.
Domenica Francesca Mariniello Valentino Allocca Vito DAgnano Riccardo Villaro Luigi Lanata Michela Bagnasco Luigi Aronne Andrea Bianco Fabio Perrotta 《Molecules (Basel, Switzerland)》2022,27(24)
COVID-19 is an infective disease resulting in widespread respiratory and non-respiratory symptoms prompted by SARS-CoV-2 infection. Interaction between SARS-CoV-2 and host cell receptors prompts activation of pro-inflammatory pathways which are involved in epithelial and endothelial damage mechanisms even after viral clearance. Since inflammation has been recognized as a critical step in COVID-19, anti-inflammatory therapies, including both steroids and non-steroids as well as cytokine inhibitors, have been proposed. Early treatment of COVID-19 has the potential to affect the clinical course of the disease regardless of underlying comorbid conditions. Non-steroidal anti-inflammatory drugs (NSAIDs), which are widely used for symptomatic relief of upper airway infections, became the mainstay of early phase treatment of COVID-19. In this review, we discuss the current evidence for using NSAIDs in early phases of SARS-CoV-2 infection with focus on ketoprofen lysine salt based on its pharmacodynamic and pharmacokinetic features. 相似文献
905.
906.
Fluid interface detection technique based on neighborhood particles centroid deviation (NPCD) for particle methods
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Particle‐based CFD methods are powerful approaches to investigate free surface, multiphase flows, and fluid structure interaction problems because of their ability of tracking moving fluid interface even with huge deformations or fragmentation and merging. However, many fluid interface particle detection techniques are simple to implement but with low accuracy or provide relatively good detection results at complicated implementation cost or higher computational time. In case of incompressible flow simulation methods solving the Poisson equation of pressure, such as the moving particle semi‐implicit method, boundary particles detection techniques' accuracy affects precision and stability of pressure computation and interaction between fluid phases. In the present work, a new fluid interface particle detection technique is proposed to improve the accuracy of the boundary particles detection and keep the implementation easy. Denominated as the neighborhood particles centroid deviation technique, it is a two‐criteria technique based on the particle number density and the neighborhood particles weighted geometric center deviation. Compared with other techniques, the proposed neighborhood particles centroid deviation technique shows the best results by eliminating false interface particles inside the fluid domain and keeping the interface particles layer thin and regular. As a result, relatively stable pressure time histories and more consistent pressure and velocity fields are achieved. Copyright © 2016 John Wiley & Sons, Ltd. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
907.
908.
Peter Wick Anna E. Louw‐Gaume Melanie Kucki Harald F. Krug Kostas Kostarelos Bengt Fadeel Kenneth A. Dawson Anna Salvati Ester Vzquez Laura Ballerini Mauro Tretiach Fabio Benfenati Emmanuel Flahaut Laury Gauthier Maurizio Prato Alberto Bianco 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(30):7846-7850
909.
Fabio Podestà 《Results in Mathematics》1991,19(1-2):147-156
The notion of affine Kähler immersions has been recently introduced by Nomizu-Pinkall-Podestà ([N-Pi-Po]). This work is aimed at giving some results towards the classification of non degenerate affine Kähler hypersurfaces with symmetric and parallel Ricci tensor; this problem generalizes the classical results due to Nomizu-Smyth ([N-S]) in the theory of Kählerian hypersurfaces. In a second section we deal with the case of “semisymmetric” affine Kähler immersions, when the curvature tensor R satisfies R · R = 0 and the Ricci tensor is symmetric, providing a complete classification; for affine Kähler curves we prove that the conditions above are actually equivalent to saying that the immersion is isometric for a suitable Kähler metric in C2. 相似文献
910.
The title compound 3 was obtained during the rearrangement of isoxazol-5-yl hydrazine 1 to 1-aminopyrazolone 2 at 115°. X-ray analysis of the corresponding benzylidene derivative allowed us to achieve the structure assignment. 相似文献