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51.
Marie-Camille Jodin-Caumon Bernard Humbert Nsoki Phambu Fabien Gaboriaud 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,72(5):959-964
Lengths, strengths and valences of OH bonds in the two aluminium hydroxides gibbsite and bayerite were determined on the basis of vibrational spectral data. The uncoupled OD stretching modes in the range 2400–2800 cm−1 were recorded by means of infrared diffuse reflectance, thereby avoiding effects of surface, vibrational coupling or particle shape. The assignment of the corresponding Raman spectra resulted in the determination of harmonic wavenumbers, force constants and anharmonicity coefficients of bulk OH groups in the two minerals. OH bond lengths deduced from these data varied from 0.964 Å to 0.975 Å in gibbsite and 0.962 Å to 0.973 Å in bayerite. These lengths appear to correspond to weak H-bonds contrary to previously recognized data from X-ray diffraction and neutron diffraction studies. Finally, bond valences were calculated on the basis of these new bond lengths and discussed as a function of crystallographic structures and the nature of hydrogen bonding in these two structures. 相似文献
52.
Fabien Cornillier Fayez F. Boctor Gilbert Laporte Jacques Renaud 《European Journal of Operational Research》2008
In the multi-period petrol station replenishment problem (MPSRP) the aim is to optimize the delivery of several petroleum products to a set of petrol stations over a given planning horizon. One must determine, for each day of the planning horizon, how much of each product should be delivered to each station, how to load these products into vehicle compartments, and how to plan vehicle routes. The objective is to maximize the total profit equal to the revenue, minus the sum of routing costs and of regular and overtime costs. This article describes a heuristic for the MPSRP. It contains a route construction and truck loading procedures, a route packing procedure, and two procedures enabling the anticipation or the postponement of deliveries. The heuristic was extensively tested on randomly generated data and compared to a previously published algorithm. Computational results confirm the efficiency of the proposed methodology. 相似文献
53.
Jul Philipp und P. Schwebel 《Fresenius' Journal of Analytical Chemistry》1881,20(1):137-138
Ohne Zusammenfassung 相似文献
54.
55.
Luminita Danaila Fabien Anselmet Tongming Zhou 《Flow, Turbulence and Combustion》2004,72(2-4):287-310
For moderate Reynolds numbers, the isotropic relation between second-order and third-order moments for velocity increments (Kolmogorov's equation) is not respected, reflecting a non-negligible correlation between the scales responsible for the injection, transfer and dissipation of the turbulent energy. For (shearless) grid turbulence, there is only one dominant large-scale phenomenon, which is the non-stationarity of statistical moments resulting from the decay of energy downstream of the grid. In this case, the extension of Kolmogorov's analysis, as carried out by Danaila, Anselmet, Zhou and Antonia, J. Fluid Mech. 391, 1999 359-369) is quite straightforward. For shear flows, several large-scale phenomena generally coexist with similar amplitudes. This is particularly the case for wall-bounded flows, where turbulent diffusion and shear effects can present comparable amplitudes. The objective of this work is to quantify, in a fully developed turbulent channel flow and far from the wall, the influence of these two effects on the scale-by-scale energy budget equation. A generalized Kolmogorov equation is derived. Relatively good agreement between the new equation and hot-wire measurements is obtained in the outer region (40 < x + 3 < 150) of the channel flow, for which the turbulent Reynolds number is R λ≈ 36. 相似文献
56.
Aubert T Ledneva AY Grasset F Kimoto K Naumov NG Molard Y Saito N Haneda H Cordier S 《Langmuir : the ACS journal of surfaces and colloids》2010,26(23):18512-18518
Metal atom clusters constitute very promising candidates as luminophores for applications in biotechnology because they are nanosized entities offering robust luminescence in the near-infrared field (NIR). However, they cannot be used as prepared for biological applications because of potential toxic effects and quenching of the clusters' luminescence in aqueous media, and they therefore need to be dispersed in a biocompatible matrix. We describe herein the encapsulation of octahedral rhenium clusters, denoted as A(4)[Re(6)Q(8)L(6)] (A = Cs or K, Q = S or Se, and L = OH or CN), in silica nanoparticles by a water-in-oil microemulsion process, paying particular attention to the clusters' stability. The obtained A(4)[Re(6)Q(8)L(6)]@SiO(2) nanoparticles are 30 nm in size with good monodispersity and a perfectly spherical shape, as shown by scanning electron microscopy (SEM). The presence of cluster units inside the silica matrix was evidenced by scanning transmission electron microscopy in annular dark-field mode (ADF-STEM). From the point of view of their optical properties, the A(4)[Re(6)Q(8)L(6)]@SiO(2) nanoparticles show red and NIR emission under UV excitation, even when dispersed in water. The evolution of the structural and luminescence properties of clusters before and after encapsulation was followed by Raman and photoluminescence spectroscopy. 相似文献
57.
We report on full-dimensional vibrational quantum dynamics of the highly excited ammonia isotopologue NHD(2) using a newly developed potential energy surface and the MCTDH program package. The calculations allow to realistically simulate an infrared laser induced stereomutation reaction at the pyramidal nitrogen atom in the femtosecond time domain. Our results allow for a thorough qualitative and quantitative understanding of infrared photoinduced stereomutation kinetics, the underlying quantum dynamics, and the reaction mechanisms. Comparison is made with a previous, reduced dimensionality study of the same reaction [R. Marquardt, M. Quack, I. Thanopulos, and D. Luckhaus, J. Chem. Phys. 118, 643 (2003)], and it is shown that slight variances of reduced spaces lead to significantly different kinetics. Because the quantum dynamics depends subtly on variances of reduced spaces, reduced dimensionality treatments are not reliable even for qualitative predictions of the stereomutation kinetics. The first direct comparison between the Multiconfigurational Time Dependent Hartree [M. H. Beck, A. Ja?ckle, G. A. Worth et al., Phys. Rep. 324, 1 (2000)] and Unimolecular Reactions Induced by Monochromatic Infrared Radiation [M. Quack and E. Sutcliffe, QCPE Bulletin 6, 98 (1986)] program packages on a specific, four dimensional quantum dynamical problem allows for their full validation in the present work. 相似文献
58.
Fabien Durola Jean-Pierre Sauvage Oliver S. Wenger 《Coordination chemistry reviews》2010,254(15-16):1748-1759
The use of 8,8′-diaryl-substituted 3,3′-biisoquinolines allows the construction of new multi-component assemblies that are inaccessible with the 2,9-diaryl-substituted 1,10-phenanthroline ligands previously developed by the Sauvage group. This is due to the sterically non-hindering nature of the new chelates, which makes three-component entanglements around octahedral metal centres such as iron(II), cobalt(II) and ruthenium(II) readily possible. Among the newly synthesized molecular assemblies are [3]rotaxanes and [3]pseudorotaxanes in which two molecular strings pass through a single macrocycle, as well as molecular shuttles that exhibit greatly improved shuttling kinetics when compared to previously investigated molecular machines that are based on copper(I)/copper(II) redox chemistry. 相似文献
59.
Magali Bonne Stéphane Pronier Fabien Can Xavier Courtois Sabine Valange Jean-Michel Tatibouët Sébastien Royer Patrice Marécot Daniel Duprez 《Solid State Sciences》2010,12(6):1002-1012
Recently titania synthesis was reported using various structuration procedures, leading to the production of solid presenting high surface area but exhibiting moderate thermal stability. The study presents the synthesis of TiO2/SiO2 nanocomposites, a solid that can advantageously replace bulk titania samples as catalyst support. The silica host support used for the synthesis of the nanocomposite is a SBA-15 type silica, having a well-defined 2D hexagonal pore structure and a large pore size. The control of the impregnation media is important to obtain dispersed titania crystals into the porosity, the best results have been obtained using an impregnation in an excess of solvent. After calcination at low temperature (400 °C), nanocomposites having titania nanodomains (~2–3 nm) located inside the pores and no external aggregates visible are obtained. This nanocomposite exhibits high specific surface area (close to that of the silica host support, even with a titania loading of 55 wt.%) and a narrow pore size distribution. Surprisingly, the increase in calcination temperature up to 800 °C does not allow to detect the anatase to rutile transition. Even at 800 °C, the hexagonal mesoporous structure of the silica support is maintained, and the anatase crystal domain size is evaluated at ~10 nm, a size close to that of the silica host support porosity (8.4 nm). Comparison of their physical properties with the results presented in literature for bulk samples evidenced that these TiO2/SiO2 solids are promising in term of thermal stability. 相似文献
60.
Dr. Jérôme Fortage Dr. Fabien Tuyèras Dr. Philippe Ochsenbein Dr. Fausto Puntoriero Dr. Francesco Nastasi Prof. Dr. Sebastiano Campagna Dr. Sophie Griveau Dr. Fethi Bedioui Dr. Ilaria Ciofini Dr. Philippe P. Lainé 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(36):11047-11063
This study evaluates the impact of the extension of the π‐conjugated system of pyridiniums on their various properties. The molecular scaffold of aryl‐substituted expanded pyridiniums (referred to as branched species) can be photochemically bis‐cyclized into the corresponding fused polycyclic derivatives (referred to as pericondensed species). The representative 1,2,4,6‐tetraphenylpyridinium ( 1H ) and 1,2,3,5,6‐pentaphenyl‐4‐(p‐tolyl)pyridinium ( 2Me ) tetra‐ and hexa‐branched pyridiniums are herein compared with their corresponding pericondensed derivatives, the fully fused 9‐phenylbenzo[1,2]quinolizino[3,4,5,6‐def]phenanthridinium ( 1H f ) and the hitherto unknown hemifused 9‐methyl‐1,2,3‐triphenylbenzo[h]phenanthro[9,10,1‐def]isoquinolinium ( 2Me f ). Combined solid‐state X‐ray crystallography and solution NMR experiments showed that stacking interactions are barely efficient when the pericondensed pyridiniums are not appropriately substituted. The electrochemical study revealed that the first reduction process of all the expanded pyridiniums occurs at around ?1 V vs. SCE, which indicates that the lowest unoccupied molecular orbital (LUMO) remains essentially localized on the pyridinium core regardless of pericondensation. In contrast, the electronic and photophysical properties are significantly affected on going from branched to pericondensed pyridiniums. Typically, the number of absorption bands increases with extended activity towards the visible region (down to ca. 450 nm in MeCN), whereas emission quantum yields are increased by three orders of magnitude (at ca. 0.25 on average). A relationship is established between the observed differential impact of the pericondensation and the importance of the localized LUMO on the properties considered: predominant for the first reduction process compared with secondary for the optical and photophysical properties. 相似文献