全文获取类型
收费全文 | 750篇 |
免费 | 52篇 |
国内免费 | 2篇 |
专业分类
化学 | 576篇 |
晶体学 | 7篇 |
力学 | 23篇 |
数学 | 80篇 |
物理学 | 118篇 |
出版年
2023年 | 9篇 |
2022年 | 8篇 |
2021年 | 11篇 |
2020年 | 21篇 |
2019年 | 14篇 |
2018年 | 24篇 |
2017年 | 5篇 |
2016年 | 38篇 |
2015年 | 22篇 |
2014年 | 28篇 |
2013年 | 37篇 |
2012年 | 62篇 |
2011年 | 81篇 |
2010年 | 39篇 |
2009年 | 47篇 |
2008年 | 64篇 |
2007年 | 69篇 |
2006年 | 56篇 |
2005年 | 54篇 |
2004年 | 25篇 |
2003年 | 29篇 |
2002年 | 23篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 4篇 |
1991年 | 3篇 |
1988年 | 3篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1981年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有804条查询结果,搜索用时 281 毫秒
81.
Functionnalized E,Z dienes (?) 2 have been prepared in a highly stereo- and enantioselective manner using chiral pentadienyl iron tricarbonyl complexes 1. 相似文献
82.
83.
Budarin V Clark JH Deswarte FE Hardy JJ Hunt AJ Kerton FM 《Chemical communications (Cambridge, England)》2005,(23):2903-2905
Expansion of native corn starch produces a high surface area mesoporous material capable of acting as a novel stationary phase for separating various mixtures of compounds. 相似文献
84.
Necessary and Sufficient Conditions to be an Eigenvalue for Linearly Recurrent Dynamical Cantor Systems 总被引:2,自引:0,他引:2
Bressaud Xavier; Durand Fabien; Maass Alejandro 《Journal London Mathematical Society》2005,72(3):799-816
Necessary and sufficient conditions are given for linearly recurrentCantor dynamical systems to have measurable and continuous eigenfunctions.Also an example of a linearly recurrent system with a nontrivialKronecker factor and a trivial maximal equicontinuous factoris constructed explicitly. 相似文献
85.
86.
Bruneval F Vast N Reining L Izquierdo M Sirotti F Barrett N 《Physical review letters》2006,97(26):267601
State-of-the-art theoretical methods fail in describing the optical absorption spectrum, band gap, and optical onset of Cu(2)O. We have extended a recently proposed self-consistent quasiparticle approach, based on the GW approximation, to the calculation of optical spectra, including excitonic effects. The band structure compares favorably with our present angle-resolved photoemission measurements. The excitonic effects based on these realistic band structure and screening provide a reliable optical absorption spectrum, which allows for a revised interpretation of its main structures. 相似文献
87.
Weissker HC Serrano J Huotari S Bruneval F Sottile F Monaco G Krisch M Olevano V Reining L 《Physical review letters》2006,97(23):237602
We present an investigation of the dynamic structure factor and of the dielectric function epsilonM(Q,omega) of the prototypical semiconductor silicon for finite momentum transfer, combining inelastic x-ray scattering experiments and ab initio calculations. In contrast with optical spectra, for finite momentum transfer time-dependent density-functional theory in the adiabatic local-density approximation together with lifetime broadening describes the physics of valence excitations correctly. Major structures in the spectra, governed by short-range crystal and exchange-correlation local-field effects, are strongly influenced by a mixing of transitions of positive and negative energies, in striking difference to spectra for vanishing momentum transfer. This mixing gives rise to a pronounced Fano asymmetry. 相似文献
88.
We have investigated the vapor phase growth of Au on SrTiO3(001)-(2 x 1) substrates by UHV scanning tunneling microscopy. Submonolayer (ML) coverages below 300 degrees C wet the surface as disordered metastable 2D islands. Beyond 0.75 ML fcc nanocrystals with a (111) interface are nucleated and ripen by dewetting the surrounding layer. Some multiply twinned fivefold symmetric clusters are also created. Above 400 degrees C dewetting occurs for all coverages and the surface is only populated by nanocrystals and fivefold clusters. A planar ground state configuration for small Au clusters and a higher interface energy for crystals than for wetted 2D ML films explains these results. 相似文献
89.
Bi-isoquinoline can be used as a building block to prepare a new family of non-sterically hindering chelates, including a macrocyclic system; the endocyclic nature of the ligands has been confirmed by the X-ray structure of an octahedral tris-chelate iron(II) complex, which shows that the three chelates are easily accommodated in the coordination sphere of the metal in spite of their crescent shape. 相似文献
90.
Michel F Hamman S Thomas F Philouze C Gautier-Luneau I Pierre JL 《Chemical communications (Cambridge, England)》2006,(39):4122-4124
In copper(ii) complexes of tripodal ligands, the protonation state of the phenol moiety, and its position (axial vs. equatorial), are easily assessed by (19)F NMR. 相似文献