全文获取类型
收费全文 | 1064篇 |
免费 | 94篇 |
国内免费 | 5篇 |
专业分类
化学 | 846篇 |
晶体学 | 14篇 |
力学 | 18篇 |
数学 | 121篇 |
物理学 | 164篇 |
出版年
2023年 | 29篇 |
2022年 | 31篇 |
2021年 | 45篇 |
2020年 | 63篇 |
2019年 | 54篇 |
2018年 | 22篇 |
2017年 | 30篇 |
2016年 | 52篇 |
2015年 | 61篇 |
2014年 | 45篇 |
2013年 | 56篇 |
2012年 | 66篇 |
2011年 | 79篇 |
2010年 | 38篇 |
2009年 | 42篇 |
2008年 | 44篇 |
2007年 | 40篇 |
2006年 | 44篇 |
2005年 | 23篇 |
2004年 | 16篇 |
2003年 | 18篇 |
2002年 | 18篇 |
2001年 | 13篇 |
2000年 | 10篇 |
1999年 | 11篇 |
1998年 | 13篇 |
1996年 | 5篇 |
1995年 | 7篇 |
1994年 | 4篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 8篇 |
1990年 | 8篇 |
1989年 | 11篇 |
1988年 | 9篇 |
1987年 | 6篇 |
1986年 | 5篇 |
1985年 | 9篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 10篇 |
1981年 | 8篇 |
1980年 | 8篇 |
1979年 | 4篇 |
1977年 | 15篇 |
1976年 | 8篇 |
1975年 | 10篇 |
1974年 | 6篇 |
1973年 | 8篇 |
1937年 | 5篇 |
排序方式: 共有1163条查询结果,搜索用时 15 毫秒
41.
Fabian Gerson Axel Lamprecht Markus Scholz Heinz Troxler Dieter Lenoir 《Helvetica chimica acta》1996,79(1):307-318
The radical anions of 5H-dibenzo[a,d]cycloheptene ( 9 ), 5 H-dibenzo[c,f][1,2]diazepine ( 10 ), 5,6-dihydrodibenzo[a,e]cyclooctene ( 11 ), 5,6-dihydrodibenzo[c,g][1,2]diazocine ( 12 ), and (E)-2,2,5,5-tetramethyl-3,4-diphenylhex-3-ene ( 13 ) were characterized by ESR and ENDOR spectroscopy. Their hyperfine data were compared with those previously reported for radical anions also containing the stilbene or the azobenzene π-system. Whereas the π-spin distribution in the radical anions of the stilbene series is only moderately sensitive to deviations of the π-system from planarity, the radical anions of the azobenzene series respond to steric strain by shifting the π-spin population from the benzene rings to the azo group. This finding is impressively demonstrated by the similar hyperfine data for 9 · ? and 11 · ? which contrast with the strongly highly hindered 13 · ?. A. plausible interpretation is readily provided by the electron affinities of the constituent π-moieties in stilbene and azobenzene. While those of benzene and ethene are both comparatively low, the azo group has a considerably higher electron affinity. 相似文献
42.
43.
Fabian Gyger André Sackmann Michael Hübner Pascal Bockstaller Dagmar Gerthsen Henning Lichtenberg Jan‐Dierk Grunwaldt Nicolae Barsan Udo Weimar Claus Feldmann 《Particle & Particle Systems Characterization》2014,31(5):591-596
Pd@SnO2 and SnO2@Pd core@shell nanocomposites are prepared via a microemulsion approach. Both nanocomposites exhibit high‐surface, porous matrices of SnO2 shells (>150 m2 g?1) with very small SnO2 crystallites (<10 nm) and palladium (Pd) nanoparticles (<10 nm) that are uniformly distributed in the porous SnO2 matrix. Although similar by first sight, Pd@SnO2 and SnO2@Pd are significantly different in view of their structure with Pd inside or outside the SnO2 shell and in view of their sensor performance. As SMOX‐based sensors (SMOX: semiconducting metal oxide), both nanocomposites show a very good sensor performance for the detection of CO and H2. Especially, the Pd@SnO2 core@shell nanocomposite is unique and shows a fast response time (τ90 < 30 s) and a very good response at low temperature (<250 °C), especially under humid‐air conditions. Extraordinarily high sensor signals are observed when exposing the Pd@SnO2 nanocomposite to CO in humid air. Under these conditions, even commercial sensors (Figaro TGS 2442, Applied Sensor MLC, E2V MICS 5521) are outperformed. 相似文献
44.
45.
Inside Back Cover: Multiple and Highly Selective Alkyne–Isonitrile C−C and C−N Couplings at Group 4 Metallocenes (Chem. Eur. J. 27/2016) 下载免费PDF全文
46.
47.
48.
49.
Fabian Gaufillet éric Akmansoy 《Applied Physics A: Materials Science & Processing》2012,109(4):1071-1074
We have designed a flat graded index lens made from a metallic graded 2D photonic crystal. The gradient of index has been obtained by varying the filling factor of a flat slab of photonic crystal in the direction perpendicular to that of the propagation of the electromagnetic field. This gradient has been designed in such a way that the flat slab focuses a plane wave. With applications in the microwave range in view, we considered a photonic crystal which consists of copper strips. 相似文献
50.
Fabian Ebner Philipp Mainik Dr. Lutz Greb 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(16):5120-5124
Structural constraint represents an attractive tool to modify p-block element properties without the need for unusual oxidation or valence states. The recently reported methyl-calix[4]pyrrolato aluminate established the effect of forcing a tetrahedral aluminum anion into a square-planar coordination mode. However, the generality of this structural motif and any consequence of ligand modification remained open. Herein, a systematic ligand screening was launched, and the class of square-planar aluminum anions was extended by two derivatives that differ in the meso-substitution at the calix[4]pyrrolato ligand. Strikingly, this modification provoked opposing trends in the preference for a Lewis acidic binding mode with σ-donors versus the aluminum-ligand cooperative binding mode with carbonyls. Insights into the origin of these counterintuitive experimental observations were provided by computation and bond analysis. Importantly, this rationale might allow to exploit mode-selective binding for catalytic rate control. 相似文献