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41.
Alessandro B. Tossi Helmut Görner Dietrich Schulte-Frohlinde 《Photochemistry and photobiology》1989,50(5):585-597
The reactions of polyuridylic acid [poly(U)] with Ru(bpy)3(3+) [Ru(III)] and SO4.-, following UV and visible light irradiation of Ru(bpy)3(2+) [Ru(II)] in the presence of S2O8(2-), were studied in an argon-saturated aqueous solution using time-resolved absorption and conductivity methods. The kinetics of the Ru(III) conversion to Ru(II) in the presence of poly(U) was monitored spectroscopically either in the absence of SO4.- [rapid mixing with Ru(III)] or in its presence (after laser flash excitation, lambda exc = 353 nm). The conversion of Ru(III) to Ru(II) is complete at a [nucleotide]/[sensitizer] (N/S) ratio greater than or equal to 10 (rate constant k = 12 s-1) for rapid mixing and at N/S greater than or equal to 6 (k = 15 s-1 at N/S = 10) after laser pulsing. Conductivity measurements following the laser pulse revealed a fast conductivity increase (risetime less than 10 micros), due to the formation of charged species and protons. A slower increase in the 0.1-0.5 s range was observed for poly(U) but it is considerably smaller for poly(dU) and absent in uracil containing monounits. The slow increase is unaffected by pH changes in the 3.5-7 range, markedly reduced in the 7-9 range and is replaced by a slight decrease in conductivity in buffered solutions. An explanation is that poly(U)-bound excited Ru(II) reacts with S2O8(2-) forming Ru(III) and SO4.- as oxidizing species both of which react with poly(U) bases. The resulting base radicals react with Ru(III) or the ligands in the ruthenium complex, producing protons which give rise to the slow conductivity increase (k = 15 s-1 at N/S = 10). The formation of single-strand breaks and the ensuing release of condensed counterions does not appear to contribute significantly to the slow conductivity signal. At N/S less than 10 the observed rate and extent of Ru(III)--Ru(II) conversion and of the slow proton production vary markedly with the N/S ratio. 相似文献
42.
Michael A. Luzuriaga Candace E. Benjamin Michael W. Gaertner Hamilton Lee Fabian C. Herbert Snipta Mallick 《Supramolecular chemistry》2019,31(8):485-490
ABSTRACTDrug delivery using metal-organic frameworks (MOF) has elicited interest in their biocompatibility; however, few studies have been conducted on their stability in common buffers, cell media, and blood proteins. In particular, the use of ZIF-8, a MOF interconnected by Zn and methylimidazole, has been frequently employed. In this study, we tested single crystals of ZIF-8 with common laboratory buffers, cell media, and serum, and noted several issues. Buffers containing phosphate and bicarbonate alter the appearance and composition of ZIF-8; however, these buffers do not appear to cause cargo to leak out even when the ZIF-8 itself is displaced by phosphates. On the other hand, serum dissolves ZIF-8, causing premature cargo release. Our results show that ZIF-8 undergoes surface chemistry changes that may affect the interpretation of cellular uptake and cargo release data. On the other hand, it provides a rational explanation as to how ZIF-8 neatly dissolves in vivo. 相似文献
43.
Journal of Theoretical Probability - We investigate the space-time regularity of the local time associated with Volterra–Lévy processes, including Volterra processes driven by $$\alpha... 相似文献
44.
Abe K Akagi T Anthony PL Antonov R Arnold RG Averett T Band HR Bauer JM Borel H Bosted PE Breton V Button-Shafer J Chen JP Chupp TE Clendenin J Comptour C Coulter KP Court G Crabb D Daoudi M Day D Dietrich FS Dunne J Dutz H Erbacher R Fellbaum J Feltham A Fonvieille H Frlez E Garvey D Gearhart R Gomez J Grenier P Griffioen KA Hoibraten S Hughes EW Hyde-Wright C Johnson JR Kawall D Klein A Kuhn SE Kuriki M Lindgren R Liu TJ Lombard-Nelsen RM Marroncle J Maruyama T Maruyama XK McCarthy J Meyer W 《Physical review letters》1995,74(3):346-350
45.
Adams MR Aïd S Anthony PL Averill DA Baker MD Baller BR Banerjee A Bhatti AA Bratzler U Braun HM Breidung H Busza W Carroll TJ Clark HL Conrad JM Davisson R Derado I Dhawan SK Dietrich FS Dougherty W Dreyer T Eckardt V Ecker U Erdmann M Faller F Fang GY Figiel J Finlay RW Gebauer HJ Geesaman DF Griffioen KA Guo RS Haas J Halliwell C Hantke D Hicks KH Hughes VW Jackson HE Jancso G Jansen DM Jin Z Kaufman S Kennedy RD Kinney ER Kirk T Kobrak HG Kotwal AV Kunori S Lancaster S Lord JJ Lubatti HJ 《Physical review letters》1995,74(9):1525-1529
46.
Fabian Wenger 《Zeitschrift für Physik B Condensed Matter》1995,98(2):171-185
We show that weak static random potentials have pronounced effects on the quasiparticle states of a 2Dd-wave superconductor close to a node. We prove that the vertex correction coming from the simplest crossed diagram is important even for a nonmagnetic potential. The leading frequency and momentum dependent logarithmic singularities in the self-energy are calculated exactly to second order in perturbation theory. The self-energy corrections lead to a modified low energy density of states which depends strongly on the type of random potential and which can be measured in experiments. There is an exceptional case for a potential with extremely local scatterers and opposite nodes separated by (, ) where an exact cancelation takes place eliminating the leading frequency dependent singularity in the simplest crossed diagram. A comparison of the perturbative results with a self-consistent CPA (coherent potential approximation) for the nonmagnetic disorder reveals qualitative differences in the self-energy at the smallest energies which are due to the neglectance of vertex corrections in CPA. 相似文献
47.
van den Brand JF Ent R Anthony PL Arnold RG Arrington J Beise EJ Belz JE Bosted PE Bulten H Chapman MS Coulter KP Dietrich FS Epstein M Filippone BW Gao H Gearhart RA Geesaman DF Hansen J Holt RJ Jackson HE Jones CE Keppel CE Kinney ER Kuhn S Lee K Lorenzon W Lung A Makins NC Margaziotis DJ McKeown RD Milner RG Mueller B Napolitano J Nelson J O'Neill TG Papavassiliou V Petratos GG Potterveld DH Rock SE Spengos M Szalata ZM Tao LH van Bibber K Wasson DA White JL Zeidman B 《Physical review D: Particles and fields》1995,52(9):4868-4871
48.
Makins NC Ent R Chapman MS Hansen J Lee K Milner RG Nelson J Arnold RG Bosted PE Keppel CE Lung A Rock SE Spengos M Szalata ZM Tao LH White JL Coulter KP Geesaman DF Holt RJ Jackson HE Papavassiliou V Potterveld DH Zeidman B Arrington J Beise EJ Belz E Filippone BW Gao H Lorenzon W Mueller B McKeown RD O'Neill TG Epstein M Margaziotis DJ Napolitano J Kinney E Anthony PL van Bibber K Dietrich FS Gearhart RA Patratos GG Kuhn SE van den Brand JF Bulten H Jones CE 《Physical review letters》1994,72(13):1986-1989
49.
50.
Dasu S de Barbaro P Bodek A Harada H Krasny MW Lang K Riordan EM Andivahis L Arnold R Benton D Bosted P deChambrier G Lung A Rock SE Szalata ZM Walker RC Filippone BW Jourdan J Milner R McKeown R Potterveld D Para A Dietrich F Van Bibber K Button-Shafer J Debebe B Hicks RS Gearhart R Whitlow LW Alster J 《Physical review D: Particles and fields》1994,49(11):5641-5670