Preparation,Characterization of Ternary Europium Complex-Doped Thin Sol-Gel Hybrid Film by Fluorescence Spectroscopy

ernary europium complex with dibenzoylmethane(DBM), 1,10-phenanthroline(phen) was in-situ syn thesized in thin SiO₂/polyvinyl butyral(PVB) hybrid films by a two-step sol-gel process, characterized by means of fluorescence spectroscopy. The luminescence spectra, fluorescence lifetimes, photostability were all investigated. The results showed that the hybrid films exhibited the characteristic emission bands of the central rare earth Eu³⁺. In addition, Eu³⁺ presented longer fluorescence lifetime than in an ethanol solution, the complex had a higher photostability in the hybrid film than in the PVB film containing the corresponding pure complex.     

In situ spectroelectrochemical behaviour of nanocrystalline TiO_2 thin films electrode fabricated by pulsed laser deposition

Nanocrystalline titanium oxide thin films have been successfully deposited on ITO coated glass by pulsed laser ablation of metallic Ti target in O_3/O_2 ambient gases. The intercalation of Li ions in the anatase TiO_2 film electrode is examined by cyclic vohammetry. The electrochromic behaviour of TiO_2 electrode is investigated by in-situ visible transmittance measurement, and two absorption bands at 420 and 650 nm are observed. The absorption falling and rising in color changing with excellent revisibility is relative to the insertion and deintercalation processes of Li ion. These resuits suggest that nanocrystalline titanium oxide films fabricated by pulsed laser deposition exhibit excellent spectroelectrochemical property.     

Application of Spline Wavelet Transform in Potentiometric Titration

Wavelet analysis is a new mathematical subject that has been developed at the end of the 1980s. Because of its properties including orthogonality, orientation, flexible time-frequency windows and governed localized support, it is unique in signal processing.     

锅炉内煤粉燃烧的通用计算方法

1前言 四角喷燃的煤粉锅炉是目前我国大型发电锅炉最主要的炉型,为保证其动力工况的可靠性,合理地布置受热面和选择受热面材料,有效组织炉膛内的燃烧过程以提高锅炉运行的安全性,锅炉设计人员需要准确地预报锅炉炉膛内,特别是燃烧器区及炉膛出口区的烟气温度分布等参数.     

Preparation of ethyl levulinate from wheat stalk over Zr(SO4)2/SiO2

A series of Zr(SO₄)₂/SiO₂ solid acid catalysts with different Zr(SO₄)₂ loadings were prepared by water-soluble-impregnation method at room temperature. Then, the prepared catalysts were characterized by Fourier transform infrared spectroscopy, transmission electron microscopy and energy-dispersive X-ray spectrum, X-ray diffraction, adsorption/desorption of N₂, and temperature-programmed desorption of NH₃. The results showed that the active component Zr(SO₄)₂ was successfully adhered to the mesoporous SiO₂, and the acid amount of Zr(SO₄)₂/SiO₂ increased with the increasing of the Zr(SO₄)₂ loadings. Finally, the wheat stalk was used as raw material and depolymerized over Zr(SO₄)₂/SiO₂ to produce ethyl levulinate (EL). The reaction mixture was separated and purified by filtration and vacuum distillation. The kinetic characteristics and the reaction pathway were also studied. A comparative study showed that 20 wt.% Zr(SO₄)₂/SiO₂ exhibited higher catalytic activity. When reaction temperature, time, catalyst dosage and Zr(SO₄)₂ loadings were 190 °C, 50 min, 20 wt.% and 30 wt.%, the EL yield reached a maximum of 17.14%. The relative content of EL exceeded 90% after three steps of distillation.     

Measurement of Angular Distributions for Elastic Scattering of 16O+94Zr and 16O+116Sn Reactions

The angular distributions for elatic scattering of the two systems,¹⁶O+⁹⁴Zr at energies 52,57,59,62,72,82 and 92 MeV and ¹⁶O+¹¹⁶Sn at energies 57,59,62,67,72,82 and 92 MeV have been measured.The scattered ions were datected by the Beijing Q3D magnetic spectrometer and its heavy ion focal plane detector.The optical model analysis of the data was made with the Coupled Channels code ECIS, and the optical potential parameters have been obtained by fitting the data.Within the limited data,the phenomenon of the ‘threshold anomaly’is observed.     

伴随有水蒸气凝结的烟气对流换热的实验研究

本文通过实验研究了冷凝式燃气热水器中烟气伴随有水蒸气凝结的受迫对流换热过程。着重介绍实验系统、测试方法和对塔板式换热器和肋片板式换热器的实验研究结果。实验表明,有水蒸气凝结时的烟气对流换热系数远大于无凝结时的换热系数,可提高数倍。在冷凝式换热器中,塔板式换热器的换热系数大于肋片板式换热器。     

超高能γ–强子族的能量集中现象

通过对甘巴拉山铁乳胶室观测到的族事例以及COSMOS程序和CORSI-KA程序产生的模拟族事例进行分析、对比,对超高能γ强子族的能量集中现象的产生特征进行了细致的研究.初步的结论是:超高能γ强子族的能量集中现象是族中含有的高能中心簇射集团的外在表现,这种现象在实验上发生的频度为(20.5±3.1)%,集团的平均横向扩展约为0.37cm.与传统的以唯象多团模型为基础的COSMOS程序相比,基于SIBYLL模型的CORSIKA程序的模拟结果较为接近实验的分析结果.     

HFC32/HFCl43a/HFCl34a在空调/直接式蓄冷空调循环中替代HCFC22的研究

提出探讨了一种有希望替代HCFC22的三元混合工质—HFC32／HFCl43a／HFCl34a。理论制冷循环和水合性能分析表明。在推荐组成下该物系的热力学性质与HCFC22基本相当,理论制冷循环GOP和容积制冷量均略优于HCFC22,在空调循环蒸发工况下能够形成气体水合物。     

二溴羟基苯基荧光酮荧光熄灭法测定铜

研究了在pH 6 2～ 8 2磷酸二氢钾 磷酸氢二钠缓冲体系中 ,非离子表面活性剂TritonX 10 0存在下 ,铜 (Ⅱ )与二溴羟基苯基荧光酮 (DBH PF)形成 1∶2红色三元混配合物而使荧光熄灭 ,建立了荧光熄灭法测定铜的新方法。配合物的λex=5 3 0nm ,λem=5 60nm ,含量在 0～ 80 μg·L-1范围内有良好的线性关系 ,检测限为 0 2 μg·L-1。体系的灵敏度高 ,选择性好。Al(Ⅲ )、Fe(Ⅲ )、Ti(Ⅳ )的干扰 ,可用氟化钠、苦杏仁酸掩蔽。方法快速简便 ,用于人发、茶叶及水中微量铜的测定与AAS相符 ,RSD(n=5 ) <6 9% ,回收率在 98%～ 10 4 %之间。