Nouveaux thiochlorures de molybdène(II): Mo6Cl10Y (Y = S,Se, Te): Structure et propriétés magnétiques et électriques

The thiochlorides Mo₆Cl₁₀Y (Y = S, Se, Te) have been prepared; they are isostructural with Nb₆I₁₁, space group Pccn, and have four formula units per unit cell. The X-ray structure of Mo₆Cl₁₀Se has been determined from three-dimensional single-crystal counter data and refined to a final R value of 0.053 for 3350 independent reflections. The most important result concerning this structure is a statistical distribution of the Se atom on the unit (Mo₆X′₈) with $\text{X′ ?}\text{7}\text{8}\text{Cl}\text{+}\text{1}\text{8}\text{Se}$: so the compound Mo₆Cl₁₀Se must be formulated $\text{(Mo}{}_6\text{Cl}{}_7\text{Se)Cl}{}_{\mathrm{<mtext>4</mtext><mtext>2</mtext>}}\text{Cl}{}_{\mathrm{<mtext>2</mtext><mtext>2</mtext>}}$. The diamagnetic and dielectric behavior of these new thiochlorides is discussed.     

Formation of m- and p-xylenes during dehydrocyclization of n-octane on chromium oxide catalysts

Conclusions In the dehydrocyclization of n-octane the m- and p-xylenes are formed as a result of the isomerization of the carbon skeleton of the aliphatic intermediate products of the reaction, namely the octadienes and octatrienes.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1675–1676, July, 1973.     

New Catalytic Synthesis of Polyfluoroalkyl Chlorosulfites

Russian Journal of General Chemistry -     

Diffusion Boundary Layers in Transport of Aliphatic Acids in Electromembrane Systems

The regularities of the formation of diffusion boundary layers during the transport of aliphatic acids in electromembrane systems are studied and their characteristics obtained experimentally are analyzed. It is shown that their concentration profiles in solutions of the electrodialyzer sections are asymmetric near membranes of different polarity. Experimental values of diffusion layer thicknesses are compared with those following from the known theoretical relations. The equation, which is proposed for the surface concentration, permits the prediction of the operation mode of apparatus during electrodialysis of solutions of aliphatic acids and other weak electrolytes. Specific features characterizing the emergence of a limiting state and the character of the distribution of limiting current densities over the height of the membrane channel are revealed.     

Coordination of aza heterocycles with macroheterocyclic metal complexes in amphiprotic media: III. Kinetics and mechanism of inner-sphere ligand exchange in (tetraphenylporphyrinato)chromium(III)

Inner-sphere replacement of alcohols by imidazole and its derivatives in the complex (acetato)-(tetraphenylporphyrinato)chromium(III) was studied by electronic absorption spectroscopy. The rate constants and activation parameters of the process were calculated. The entering ligand structure was shown to affect the reaction rate, while the alcohol nature (departing ligand) does not influence the kinetic parameters of the process to an appreciable extent. Regression analysis revealed participation of imidazole and ethanol in the rate-determining stages. The kinetic equation for the inner-sphere axial substitution implies interaction of a free alcohol molecule with that coordinated to chromium, followed by replacement of the associate by the heteroring. Mathematical processing of the kinetic data in terms of the proposed solvolytic association-dissociation mechanism gave the rate constants for particular stages of the process and showed an extremal relation between the rate constant and composition of the solvent.