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311.
V. I. Kosyakov V. A. Shestakov S. F. Solodovnikov 《Journal of Structural Chemistry》1994,34(5):810-813
Using the Zimmennan-Pimentel potential, we have calculated the basic atomic coordinates of the unit cell of the gas hydrate HS-lframework. A minimum change in the strain energy of hydrogen bonh UH fakes place in formation of this framework from ice Ih. The dependence of UH on the lattice parameters is derived.Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Strukturnoi Khimii, Vol. 34, No. 5, pp. 175–178, September–October, 1993.Translated by T. Yudanova 相似文献
312.
Karasevich E. I. Karasevich Yu. K. Shestakov A. F. Shilov A. E. 《Kinetics and Catalysis》2003,44(1):112-120
Published data on the kinetic isotope effects of the hydroxylation of deuterium-substituted methane molecules (CHD3, CH2D2, and CH3D) by methane monooxygenase are examined in the framework of the two-step nonradical mechanism through the intermediate formation of a complex containing pentacoordinate carbon. The kinetic schemes with the first step involving one, two, and three hydrogen atoms of the oxidized substrate are considered. Contrary to the widely accepted oxygen rebound mechanism, the experimental results obtained for the oxidation of various substrates by methane monooxygenase and cytochrome P450 can be explained from the viewpoint of the dynamics of a general nonradical mechanism. 相似文献
313.
Ponomarev N. E. Stambirskii M. V. Dvorko G. F. 《Russian Journal of General Chemistry》2002,72(1):79-85
The salt effect on the rate of dehydrobromination of 3-bromocyclohexene in PhNO2 depends on the nature of the verdazyl indicator. With triphenylverdazyl and its chloro and nitro derivatives in the presence of Et4NClO4, a normal salt effect is observed, in the presence of bromides, a superposition of normal and special salt effects, while in the presence of chlorides, a superposition of normal and special negative salt effects. With the dimethoxy verdazyl derivative, a normal salt effect is always observed. 相似文献
314.
An immobiline DryStrip application method enabling high-capacity two-dimensional gel electrophoresis 总被引:5,自引:0,他引:5
Sabounchi-Schütt F Aström J Olsson I Eklund A Grunewald J Bjellqvist B 《Electrophoresis》2000,21(17):3649-3656
In the field of proteomics the need to detect low-abundance cellular components, such as regulatory proteins, is of critical importance. Two-dimensional polyacrylamide gel electrophoresis (2-D PAGE) is one of the most commonly used separation tools for these biological investigations. In this paper we report an alternative micropreparative 2-D PAGE sample application method, called the "paper bridge loading" method. This method makes it possible to apply a larger sample volume to commercially available immobilized pH gradient (IPG) strips. The Vh products required for focusing are only marginally longer than those used in analytical experiments. The method was compared to traditional cup loading and in-gel rehydration. With 18 cm long narrow-range Immobiline DryStrip pH 4.5-5.5, the "paper bridge" method allowed the application of 10 mg human plasma proteins compared to 3 mg with traditional loading methods. The corresponding figures using Escherichia coli sample was found to be 6 mg and less than 2 mg, respectively. The paper bridge method also showed the best results in terms of spot resolution and separation of high molecular weight proteins. 相似文献
315.
316.
317.
E. S. Domnina G. G. Skvortsova N. P. Glazkova M. F. Shostakovskii 《Chemistry of Heterocyclic Compounds》1967,2(3):283-286
The reaction of indole with acetylene under pressure is investigated. It is shown that under the action of KOH in aqueous dioxane at 220° C, N-vinylindole C10H9N is formed in 66% yield, and that this compound undergoes free radical and cationic polymerization. 相似文献
318.
L. N. Ivanova T. A. Severina G. A. Kogan V. F. Kucherov 《Russian Chemical Bulletin》1966,15(7):1167-1170
Conclusions The reactions of hexahydro-1,3-indandlone with ammonia and some amines were studied, and the structures of the products formed were proved. In the alkylation of-diketones of the hexahydroindan series and their enamines under the usual conditions C-alkylation products are not formed.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1214–1218, July, 1966. 相似文献
319.
A technique for following the hydrolysis of pyromellitic acid dianhydride (PMDA) by differential thermal analysis (DTA) is described. On exposure of PMDA to moisture, an endothennic peak is initiated between 190 and 200 degrees . As the degree of hydrolysis increases, this peak becomes more intense and shifts to higher temperatures. The formation of pyromellitic acid (PMA) during the hydrolysis of PMDA can be determined qualitatively by DTA. 相似文献
320.
B. Brocklehurst R.S. Dixon E.M. Gardy V.J. Lopata M.J. Quinn A. Singh F.P. Sargent 《Chemical physics letters》1974,28(3):361-363
Excited state formation by ion recombination in solutions of fluorene in squalene has been studied by pulse radiolysis at the center of a large electromagnet. The products of the slower part of the ion recombination are affected by an applied magnetic field. The fluorescence yield increases by a factor of about 1.5 whereas the triplet yield decreases. 相似文献