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981.
Mária Meiarová Katarína Hubinská tefan Toma Burkhard Koch Albrecht Berkessel 《Monatshefte für Chemie / Chemical Monthly》2007,138(11):1181-1186
Summary.
N-Toluensulfonyl-l-prolin amide was tested as catalyst in the enantioselective Michael addition of carbonyl compounds to (E)-β-nitrostyrene in nine ionic liquids under different reaction conditions. The reaction rates and enantioselectivities were
strongly dependent on the ionic liquids. Change of enantioselectivity was observed too and it is attributed to both the cation
and the anion of ionic liquid. The best yields (up to 98%) and enantioselectivity (70% ee) of product were obtained in a basic ionic liquid [bmim]BF4 at room temperature. 相似文献
982.
Juan F García-Reyes Pilar Ortega-Barrales Antonio Molina-Díaz 《Analytical sciences》2007,23(4):423-428
A combined approach based on solid-phase optosensing and multicommutation principles has been applied to develop a method for the simultaneous analysis of two pharmaceuticals (naproxen and salicylic acid) in biological fluids. The multicommuted flow-through optosensor was based on direct native fluorescence measurements of both analgesics using a non-polar sorbent (C18 silica gel) as a solid sensing zone. The flow system was controlled by Java-written home-made software and designed using three-way solenoid valves for an independent automated manipulation of sample and carrier solutions. Using an optimized sampling time, the method was calibrated in the range of 1 - 25 and 5 - 200 ng mL(-1). The obtained detection limits were 0.3 and 1.3 ng mL(-1) for naproxen and salicylic acid, respectively, with RSD (%) values of better than 2% for both analytes. The proposed methodology was successfully applied to urine, serum and pharmaceutical preparations. Recovery percentages ranging from 96.1 to 104% were obtained for both analytes. 相似文献
983.
S. S. Stavitskaya N. T. Kartel’ N. N. Tsyba M. F. Kovtun T. P. Petrenko 《Russian Journal of Applied Chemistry》2007,80(3):379-385
The mineral and chemical compositions, as well as some structure-sorption characteristics were determined for clay minerals selected for examination. The integrated coefficients of contamination of bottom sediments with each of the toxicant metals (Fe, Ni, Co, Cu, Zn, Pb, Mn) were calculated. The minerals examined presumably can be used in medicine as efficient application materials, cosmetic agents, and sorbents (enterosorbents). 相似文献
984.
985.
Summary Two polyampholyte copolymers based on sodium-2-acrylamido-2-methylsulfonate (NaAMPS) and methacryloyloxyethyltrimethylammonium
chloride (MADQUAT) have been prepared either in homogeneous solution or by an inverse microemulsion polymerization technique.
The copolymer microstructure was shown to depend on the method of preparation. The microemulsion polymerization yields copolymers
with a monomer sequence distribution not far from random while those obtained by polymerization in solution have a strong
tendency to alternation. The aqueous-solution properties of the two samples have been investigated by viscometry. The results
show that the charge distribution along the copolymer chain affects considerably its conformation, in good agreement with
recent theoretical studies.
Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994 相似文献
986.
C. Saragovi F. Labenski S. M. Duhalde S. Acebal R. Venegas 《Hyperfine Interactions》1994,91(1):765-769
Clay fractions of a Mollisol sample as is, treated with ammonium oxalate (AO), with dithionite-citrate-bicarbonate (DCB) and with dithionite-ethilene-diamine-tetraacetic acid (D-EDTA) methods, were studied. Illite-montmorillonites together with hematites, goethites and maghemites, all of the AI-substituted and with a wide range of sizes, were identified. It is found that the AO attack extracts little iron, whereas the other two attacks extract the magnetic signal. Furthermore, the DCB attack facilitates the reduction of the Fe3+ ions, while the D-EDTA method does not. Instead, this attack extracts more clay mineral Fe ions. A comparison with large grain soil samples is made. 相似文献
987.
G. F. R. Ellis 《General Relativity and Gravitation》1992,24(10):1047-1068
This paper gives a covariant formalism enabling investigation of the possibility of change of signature in classical General Relativity, when the geometry is that of a Robertson-Walker universe. It is shown that such changes are compatible with the Einstein field equations, both in the case of a barotropic fluid and of a scalar field. A criterion is given for when such a change of signature should take place in the scalar field case. Some examples show the kind of resulting exact solutions of the field equations. 相似文献
988.
B. F. Araujo H. T. Matsuda T. A. Kuada J. A. Araujo 《Journal of Radioanalytical and Nuclear Chemistry》1992,166(1):75-83
In the actinide separation process using TBP as extractant, hydrolytic and radiolytic reactions cause a gradual decomposition of the extractant, resulting in the formation of degradation products which can affect process performance adversely. The TBP diluent has to be cleaned from these degradation products before it is reused. This paper deals with a procedure for solvent cleanup, using a fourstage continuous contactor for increasing the scrubbing efficiency. 相似文献
989.
M F Yama 《The Journal of the Acoustical Society of America》1992,91(1):327-335
In the present study detection under diotic (NoSo) and dichotic (NoS pi) listening conditions in a forward masking paradigm was investigated. Both the level of a noise masker and the temporal separation between the masker and a 250-Hz tone burst served as independent variables. Results showed that most of the variance in the data could be accounted for by the amount of masking in the NoSo condition, independent of the value of the temporal parameter, which itself accounted for only 1.4% of the variance that remained. Once the data were corrected for NoSo masking effectiveness, the MLD was found to decrease by only 1.4 dB as temporal separation increased from 5-100 ms, which is consistent with a very long time constant for the binaural system. Consistent with this finding, it was shown that slope changes of the growth of masking functions, for simultaneous as compared to forward masking, were similar for both the NoSo and NoS pi conditions. 相似文献
990.
Domokos Szász 《Communications in Mathematical Physics》1992,145(3):595-604
TheK-property is demonstrated for a class of planar billiards satisfying Wojtkowski's principles. Their boundary may consist of convex-scattering, concave and linear pieces. Earlier Wojtkowski showed that these billards had non-zero Lyapunov exponents. 相似文献