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991.
I. P. Dobrovol’skaya M. V. Mokeev Yu. N. Sazanov A. V. Gribanov T. E. Sukhanova 《Russian Journal of Applied Chemistry》2006,79(8):1312-1315
Variation of the supramolecular structure of heat-resistant polymide films in the course of high-temperature treatment was studied by X-ray diffraction analysis and NMR spectroscopy in solids. 相似文献
992.
V. N. Kizhnyaev A. F. Pokatilov L. I. Vereshchagin L. V. Adamova A. P. Safronov A. I. Smirnov 《Russian Journal of Applied Chemistry》2006,79(7):1167-1173
Carbon-chain polymers with 1,3,4-oxadiazole rings were prepared by radical polymerization and polymer-analogous transformations. The kinetic relationships of the polymerization of vinyl-1,3,4-oxadiazole monomers and some properties of the resulting polymers were studied. The thermodynamics of interaction of poly-2-vinyl-5-methyl-1,3,4-oxadiazole, a nonionic water-soluble polymer, with water was examined. 相似文献
993.
High temperature GaN layers have been grown on Si (1 1 1) substrate by metalorganic vapor phase epitaxy (MOVPE). AlN was used as a buffer layer and studied as a function of thickness and growth temperature. The growth was monitored by in situ laser reflectometry. High resolution X-ray diffraction (HRXRD) revealed that optimized monocrystalline GaN was obtained for a 40 nm AlN grown at 1080 °C. This is in good agreement with the results of morphological study by scanning electron microscopy (SEM) and also confirmed by atomic force microscopy (AFM) observations. The best morphology of AlN with columnar structure and lower rms surface roughness is greatly advantageous to the coalescence of the GaN epilayer. Symmetric and asymmetric GaN reflections were combined for twist and stress measurements in monocrystalline GaN. It was found that mosaicity and biaxial tensile stress are still high in 1.7 μm GaN. Curvature radius measurement was also done and correlated to the cracks observations over the GaN surface. 相似文献
994.
K.E. Lee T.L. Phan N.D. Ha M.H. Phan S.C. Yu C.O. Kim 《Journal of magnetism and magnetic materials》2006
Influences of oxygen-partial pressure and annealing on the electrical and magnetic properties of CoFeAlO thin films were systematically investigated by means of resistivity, permeability, magnetization and ferromagnetic resonance (FMR) measurements. It was found that, with increasing oxygen-partial pressure or under annealing, the electrical resistivity of the film increased and the magnetic softness decreased, which is attributed to the microstructural change of the film. Interestingly, an as-deposited Co45.30Fe20.65Al19.34O14.71 film was found to exhibit an inverted hysteresis loop with negative coercivity, and this peculiar phenomenon disappeared upon effects of oxygen-partial pressure and annealing. It was also found that the as-deposited films owned a narrow FMR line width that increased with increasing oxygen-partial pressure or under annealing. 相似文献
995.
3d-metal antimonides: Fe1+x Sb, N+x Sb, Co+x Sb and the (Ni1?y Fe y )Sb solid solution have been studied by the Mössbauer effect method at 57Fe and 119Sn. It was found that the quadrupole interactions at the Fe and Sn nucleus in 3d-metal antimonides are very sensitive to the filling of different crystallographic sites with metal atoms. The metal atoms in trigonal-bipyramidal sites have a strong effect on the quadrupole splitting of 119Sn. They are nearest to anions (Sb or Sn) with the typical axial ratio of c/a = 1.25. The QS(x) dependence of 119 Sn in 3d-metal antimonides in the 0 ≤ x ≤ 0.1 concentration range can be used to determine x – the concentration of transition metal excess relative to the stoichiometric composition. 相似文献
996.
T. Kasahara H.S. Park D. Shindo H. Yoshikawa T. Sato K. Kondo 《Journal of magnetism and magnetic materials》2006
Domain wall motion in Mn–Zn and Ni–Zn ferrites with applied magnetic fields is investigated by in situ observations with Lorentz microscopy and electron holography. It is found that both Mn–Zn and Ni–Zn ferrites have a mean grain size of approximately 10 μm and several pores with sizes ranging from 0.2 to 1.1 μm. In situ observations by Lorentz microscopy with an applied magnetic field reveals that in Mn–Zn ferrite, the domain walls move easily across the grain boundary, while in Ni–Zn ferrite, the domain walls move along the grain boundary but are pinned at the grain boundary and pores. From in situ observations of Ni–Zn ferrite by electron holography, it is clarified that domain wall pinning at the grain boundary retards a sensitive increase in magnetic flux parallel to the applied field direction, which is considered to result in high hysteresis loss. 相似文献
997.
B. D. Kabulov K. A. Akhundzhanov F. U. Yunusov O. A. Shpigun S. S. Negmatov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2007,81(3):354-356
The hydrolytic polycondensation of tetraethoxysilane in the presence of various polymers (polyacrylonitrile, polycaproamide, and chitosan) as templates was performed with the use of the sol-gel technology to obtain nanohybrid composite polymer-silica sorbents-nanofractals. 相似文献
998.
E. Baggio Saitovitch F. J. Litterst I. Souza Azevedo R. B. Scorzelli 《Hyperfine Interactions》1989,50(1-4):529-535
The Mössbauer spectra of YBa2(Cu1?x Fe x )3O7 at room temperature show several doublets attributed to Fe in Cu(1) sites with different oxygen configurations. Here we present a systematic study performed at 4.2 K forx=0.005, 0.01, 0.03, 0.05, 0.10, 0.15. To obtain information about the magnetic ordered state two samples, withx=0.005 andx=0.15, have been studied at 4.2 K underB ext=5 T. The Mössbauer spectra indicate that the iron moments are polarized forx=0.005, while in the ordered state (x=0.15) they have an antiferromagnetic or spin-glass-like arrangement with high anisotropy. 相似文献
999.
1000.
The hyperfine fields for the systems140CeLa and140CeLu have been determined by time differential perturbed angular correlations (TDPAC) in the temperature range 4.2 K≤T≤330 K. Magnitude and temperature dependence of the paramagnetic enhancement factor β indicate that cerium in either system
is of intermediate valence. This behaviour is discussed in terms of a theory proposed by Ramakrishnan et al. [1–3]. 相似文献