Differential algebra of quantum fermions

Lie coalgebra equips an exterior algebra (algebra of fermions) with a structure of a differential algebra. In similar way we equip an algebra of quantum fermions (quantized exterior algebra) with a structure of a differential algebra. This leads to a notion of a variety of Lie coalgebras for a Hecke braid. This approach is different from that of Gurevich (1988 and 1993), Woronowicz (1989) and of Majid (1993).     

Properties of Chaotic and Regular Boundary Crisis in Dissipative Driven Nonlinear Oscillators

The phenomenon of the chaotic boundary crisis and the related concept of the chaotic destroyer saddle has become recently a new problem in the studies of the destruction of chaotic attractors in nonlinear oscillators. As it is known, in the case of regular boundary crisis, the homoclinic bifurcation of the destroyer saddle defines the parameters of the annihilation of the chaotic attractor. In contrast, at the chaotic boundary crisis, the outset of the destroyer saddle which branches away from the chaotic attractor is tangled prior to the crisis. In our paper, the main point of interest is the problem of a relation, if any, between the homoclinic tangling of the destroyer saddle and the other properties of the system which may accompany the chaotic as well as the regular boundary crisis. In particular, the question if the phenomena of fractal basin boundary, indeterminate outcome, and a period of the destroyer saddle, are directly implied by the structure of the destroyer saddle invariant manifolds, is examined for some examples of the boundary crisis that occur in the mathematical models of the twin-well and the single-well potential nonlinear oscillators.     

Free convection from horizontal screened plates

Experimental investigations of laminar free convection from horizontal isothermal surfaces screened by cylindrical vertical walls are presented. Screen diameters (D) were equal to the diameter of a heating plate while their heights (H) were varied. Results obtained for several heating fluxes and two different liquids indicate that depending on the (H/D) ratio of cylindrical screens, the heat flux transferred from the heating plate to the liquid varies. Three subranges of screening effect have been distinguished: primary inhibition, intensification and secondary inhibition. For primary inhibition, a theoretical model has been proposed and critical ratio of (H/D) has been predicted. The results of flow visualization are also discussed.

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Freie Konvektion von horizontalen, seitlich abgeschirmten Platten

Zusammenfassung Es werden experimentelle Untersuchungen der laminaren freien Konvektion an horizontalen, isothermen Flächen mit vertikalen zylindrischen Abschirmflächen beschrieben. Die Schirmdurchmesser (D) waren gleich dem einer Heizplatte, während die Schirmhöhen (H) variiert wurden. Die Resultate, welche für mehrere Wärmeflüsse und mit zwei verschiedenen Flüssigkeiten gewonnen wurden, zeigen, daß — abhängig von VerhältnisH/D der zylindrischen Schirme — der von der Heizplatte an das Fluid übergehende Wärmestrom stark variiert. Drei Bereiche konnten bezüglich des Abschirmeffektes unterschieden werden: erste Hemmung, Verstärkung und zweite Hemmung. Für den Fall der ersten Hemmung wird ein theoretisches Modell vorgeschlagen und das kritischeH/D-Verhältnis vorausberechnet. Abschließend erfolgt die Diskussion von Ergebnissen, welche aus der sichtbaren Darstellung des Strömungsfeldes gewonnen wurde.

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Nomenclature a thermal diffusivity [m²/s] - D external diameter of the plate, internal diameter of screens [m] - g gravitational acceleration [m/s²] - H height of screen [m] - Nu= D/ Nusselt number - Nu _(H/D)=0 Nusselt number for plate without screens - Nu _H/D Nusselt number for plate with screen of heightH - Ra=g (T _w1–T _F)D ³/( a) Rayleigh number - Ra _H=g (T _w–T _w1)H ³/( a) Rayleigh number inside screen - q heat flux density [W/m²] - T _w surface temperature of the heating plate [°C] - T _w1 boundary temperature of the motionless liquid [°C] - T _F bulk temperature of the liquid [°C] - heat transfer coefficient [W/(m²·K)] - coefficient of volumetric expansion [1/K] - kinematic viscosity - thermal conductivity [W/(m·K)]     

On Thermodynamics of Nonlinear Poroelastic Materials

The paper contains a brief presentation of a macroscopical thermodynamic model of poroelastic materials with many fluid components. A particular emphasis is placed on a Lagrangian formulation of the model and, consequently, on a consistent formulation of field equations on the reference configuration of the skeleton (solid phase of the mixture). It is demonstrated that the model possesses an identical structure as that in the pioneering work of C.A. Truesdell on the continuum mixture of fluids. An issue of porosity as an additional microstructural variable is particularly exposed.     

Phenanthriporphyrin: An Antiaromatic Aceneporphyrinoid as a Ligand for a Hypervalent Organophosphorus(V) Moiety

The incorporation of a phenanthrene moiety into a porphyrin framework results in the formation of a hybrid macrocycle—phenanthriporphyrin—merging the structural features of polycyclic aromatic hydrocarbons and porphyrins. An antiaromatic aceneporphyrinoid, adopting the trianionic {CCNN} core, is suitable for the incorporation of a phosphorus(V) center to form a hypervalent organophosphorus(V) derivative.     

π‐Expanded α,β‐Unsaturated Ketones: Synthesis,Optical Properties,and Two‐Photon‐Induced Polymerization

A library of π‐expanded α,β‐unsaturated ketones was designed and synthesized. They were prepared by a combination of Wittig reaction, Sonogashira reaction, and aldol condensation. It was further demonstrated that the double aldol condensation can be performed effectively for highly polarized styrene‐ and diphenylacetylene‐derived aldehydes. The strategic placement of two dialkylamino groups at the periphery of D ‐π‐A‐π‐D molecules resulted in dyes with excellent solubility. These ketones absorb light in the region 400–550 nm. Many of them display strong solvatochromism so that the emission ranges from 530–580 nm in toluene to the near‐IR region in benzonitrile. Ketones based on cyclobutanone as central moieties display very high fluorescence quantum yields in nonpolar solvents, which decrease drastically in polar media. Photophysical studies of these new functional dyes revealed that they possess an enhanced two‐photon absorption cross section when compared with simpler ketone derivatives. Due to strong polarization of the resulting dyes, values of two‐photon absorption cross sections on the level of 200–300 GM at 800 nm were achieved, and thanks to that as well as the presence of the keto group, these new two‐photon initiators display excellent performance so that the operating region is 5–75 mW in some cases.