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31.
C. Magron Ph. Alfaurt B. Blank L. Daudin T. Eronen M. Gerbaux J. Giovinazzo D. Gorelov S. Grévy H. Guérin J. Hakala V. S. Kolhinen J. Koponen T. Kurtukian Nieto I. D. Moore H. Penttilä I. Pohjalainen J. Reinikainen M. Reponen S. Rinta-Antila M. Roche A. de Roubin N. Smirnova B. Thomas A. Voss L. Xayavong 《The European Physical Journal A - Hadrons and Nuclei》2017,53(4):77
32.
T. A. Gracheva T. A. Kuz’micheva V. N. Perevezentsev L. A. Smirnova A. E. Mochalova E. B. Salomatina 《Technical Physics》2017,62(8):1228-1232
Using methods of optical spectroscopy and small-angle X-ray scattering, the kinetics of the UV radiation-induced formation of gold nanoparticles in HAuCl4-doped water–acid solutions of chitosan has been studied from the very beginning of the reaction. It has been shown that, during synthesis, as the mean size of nanoparticles grows from 2.9 to 6.3 nm, the maximum of the plasmon resonance shifts toward shorter waves (535–523 nm), whereas for a fully formed ensemble of nanoparticles, the reverse trend is observed. It has been found experimentally that the particle size distribution curve changes during synthesis. Based on the inverse problem analysis, conclusions have been drawn regarding the dominant mechanisms behind nanoparticle growth. 相似文献
33.
Rassolov A. V. Ivanov G. A. Bragina G. O. Baeva G. N. Smirnova N. S. Kazakov A. V. Usachev N. Ya. Stakheev A. Yu. 《Kinetics and Catalysis》2021,62(5):641-650
Kinetics and Catalysis - The catalytic performance of a bimetallic RhIn/SiO2 catalyst was studied in the liquid-phase hydrogenation of nitrobenzene. The formation of intermetallic Rh1In1... 相似文献
34.
35.
Selective Synthesis of 2,5‐Diformylfuran by Sustainable 4‐acetamido‐TEMPO/Halogen‐Mediated Electrooxidation of 5‐Hydroxymethylfurfural 下载免费PDF全文
Dr. Vera P. Kashparova Dr. Victor A. Klushin Dr. Daria V. Leontyeva Prof. Dr. Nina V. Smirnova Prof. Dr. Victor M. Chernyshev Prof. Dr. Valentine P. Ananikov 《化学:亚洲杂志》2016,11(18):2578-2585
A new method was developed for the selective gram‐scale synthesis of 2,5‐diformylfuran (DFF), which is an important chemical with a high application potential, via oxidation of biomass‐derived 5‐hydroxylmethylfurfural (HMF) catalyzed by 4‐acetylamino‐2,2,6,6‐tetramethylpiperidine‐1‐oxyl (4‐AcNH‐TEMPO) in a two‐phase system consisting of a methylene chloride and aqueous solution containing sodium hydrogen carbonate and potassium iodide. The key feature of this method is the generation of the I2 (co‐)oxidant by anodic oxidation of iodide anions during pulse electrolysis. In addition, the electrolyte can be successfully recycled five times while maintaining a 62–65 % yield of DFF. This novel method provides a sustainable pathway for waste‐free production of DFF without the use of metal catalysts and expensive oxidants. An advantage of electrooxidation is utilized in the preparation of demanding chemical. 相似文献
36.
A. Mdicke D. Demus A. I. Pavluchenko V. V. Titov N. I. Smirnova 《Crystal Research and Technology》1986,21(1):111-115
The phase transitions of 5-n-hexyl-2-[4-n-pentyloxyphenyl]-pyridine were determined by miroscopic and calorimetric investigations. The classification of the smectic modifications was done by investigation of the miscibility relations. Besides the nematic phase smectic phases C, F, G and H were identified. 相似文献
37.
T. I. Smirnova 《Applied magnetic resonance》2007,31(3-4):431-446
High-field electron paramagnetic resonance (EPR) experiments to monitor binding of lipophilic Gd(III) complexes to human serum albumin (HSA) are described. It was observed that magnetic interactions between the nitroxide moiety ofn-doxyl-stearic acids bound to HSA and Gd(III) complexes resulted in broadening of nitroxide continuous-wave EPR spectra. The broadening effect can be well described by a one-parameter model of additional Lorentzian broadening At 95 GHz, continuous-wave EPR spectra from Gd(III) complexes are fully resolved from the nitroxide signal allowing for simultaneous and independent line shape analysis. Analysis of the line width broadening effects for spectra from a series ofn-doxyl-stearic acids bound to HSA indicated a progressive decrease of spin label-Gd(III) magnetic interactions along the fatty acid (FA) binding channel, consistent with binding of Gd-DOTAP complex in the vicinity of the main FA binding site. The substantial difference in spin label-metal interactions along the FA binding channel for lipophilic Gd(III) complexes with different chelates is indicative of binding to different sites. We also report measurements of dissociation constant for noncovalent binding of Gd(III) complexes to HSA on the basis of analyses of 95 GHz Gd(III) EPR line shapes. 相似文献
38.
Skotnikova D. S. Mochalova A. E. Smirnova L. A. 《Russian Journal of Applied Chemistry》2019,92(5):634-638
Russian Journal of Applied Chemistry - Chitosan copolymers with vinyl monomers: 4-N-vinylpyridine, acrylamide, and acrylic acid, were synthesized and these sorption properties were investigated.... 相似文献
39.
Daria V. Chernysheva Victor A. Klushin Alexander F. Zubenko Lyudmila S. Pudova Oleg A. Kravchenko Victor M. Chernyshev Nina V. Smirnova 《Mendeleev Communications》2018,28(4):431-433
The Pt/C catalysts with various Pt content (5-30 wt%) synthesized via electrochemical pulse alternating current technique have been evaluated for the base-free aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid. The higher Pt content in the catalyst (30 wt%) provides the product yield up to 65% upon performing the process in concentrated (~0.1 M) aqueous solutions of the substrate. 相似文献
40.
N. S. Smirnova 《Journal of Mathematical Sciences》1990,50(6):2044-2049
The result of the calculation of the field of a longitudinal wave which has passed through an elastic layer is studied and the character of the propagation of different phases of this wave is determined.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im V. A. Steklova AN SSSR, Vol. 165, pp. 159–165, 1987. 相似文献