全文获取类型
收费全文 | 158篇 |
免费 | 9篇 |
专业分类
化学 | 117篇 |
晶体学 | 3篇 |
力学 | 5篇 |
数学 | 26篇 |
物理学 | 16篇 |
出版年
2023年 | 1篇 |
2022年 | 2篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 4篇 |
2017年 | 4篇 |
2016年 | 6篇 |
2015年 | 3篇 |
2014年 | 6篇 |
2013年 | 12篇 |
2012年 | 6篇 |
2011年 | 24篇 |
2010年 | 7篇 |
2009年 | 9篇 |
2008年 | 7篇 |
2007年 | 8篇 |
2006年 | 2篇 |
2005年 | 6篇 |
2004年 | 3篇 |
2003年 | 5篇 |
2002年 | 9篇 |
2001年 | 2篇 |
2000年 | 4篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1989年 | 2篇 |
1985年 | 2篇 |
1983年 | 2篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1878年 | 2篇 |
排序方式: 共有167条查询结果,搜索用时 375 毫秒
61.
62.
Improvement in the prediction of very low vapor pressures is checked by introducing heat capacity data into the estimation of cubic equation-of-state (EOS) parameters. As the key parameter is the temperature-dependent parameter a, several expressions (mainly of exponential form) were investigated. All of them were chosen in order to show a consistent behavior for the two considered properties (vapor pressures and heat capacities). The cubic EOS used as an illustration is of the Peng–Robinson type applied to heavy hydrocarbons. No satisfactory refinement in the prediction of the very low vapor pressures was observed in comparison with the results obtained by extrapolating the EOS from medium to very low pressures. This work has, however, the following benefits: (1) to point out the changes that should be made to improve these predictions; (2) to inform on the accuracy that may be obtained if vapor pressures of heavy organic compounds are predicted from heat capacity data as the sole alternative for estimating the temperature-dependent parameter a of a cubic EOS; (3) to confirm the reliability of the cubic group-contribution (GC)-based EOS proposed by Coniglio et al. [Ind. Eng. Chem. Res. 39 (2000) 5037] when extrapolated for modeling crude oils or gas condensates encountered in the petroleum industry. 相似文献
63.
Bernard Maillard Abdelmajid Kharrat Felicien Rakotomanana Evelyne Montaudon Christian Gardrat 《Tetrahedron》1985,41(19):4047-4056
Free radical additions of hydrogen donor solvents to tert-butyl perpent-4-enoate have given 4-substituted γ-butyrolactones, with yields of 50 % or greater. Such reactions applied to allyl-tert-butyl peroxide have produced 2,3-epoxypropanation of these solvents. Similar addition-elimination processes occurred with tert-butyl 4-methyl-perpent-4-enoate, tert-butyl 2,2-dimethyl-perpent-4-enoate and tert-butyl-methallyl peroxide, but they failed with tert-butyl 5-methyl-perhex-4-enoate and tert-butyl-3-methyl-but-2-enyl peroxide. 相似文献
64.
Evelyne Grander Grard Leclerc Jean-Daniel Ehrhardt 《Journal of heterocyclic chemistry》1989,26(6):1781-1785
4-Alkyl-2-methyl-3,4-diphenyl-1,2-thiazetidine 1,1-dioxide 5, 6 and 7 were obtained from 2-methyl-3,4-diphenyl-1,2-thiazetidine 1,1-dioxide 1 by reaction of its anion 4 with alkyl halides. cis- and trans-Configuration of the 4-alkylated products were determined by 1H-nmr and NOE difference spectro-scopy studies. 相似文献
65.
66.
Supervised clustering of variables 总被引:1,自引:0,他引:1
In predictive modelling, highly correlated predictors lead to unstable models that are often difficult to interpret. The selection of features, or the use of latent components that reduce the complexity among correlated observed variables, are common strategies. Our objective with the new procedure that we advocate here is to achieve both purposes: to highlight the group structure among the variables and to identify the most relevant groups of variables for prediction. The proposed procedure is an iterative adaptation of a method developed for the clustering of variables around latent variables (CLV). Modification of the standard CLV algorithm leads to a supervised procedure, in the sense that the variable to be predicted plays an active role in the clustering. The latent variables associated with the groups of variables, selected for their “proximity” to the variable to be predicted and their “internal homogeneity”, are progressively added in a predictive model. The features of the methodology are illustrated based on a simulation study and a real-world application. 相似文献
67.
We discuss a generalization of the resolution of the identity by considering one-body resolutions of two-body operators, with particular emphasis on the Coulomb operator. We introduce a set of functions that are orthonormal with respect to 1r(12) and propose that the resulting "resolution of the Coulomb operator," r(12) (-1)=mid R:phi(i)phi(i)mid R:, may be useful for the treatment of large systems due to the separation of two-body interactions. We validate our approach by using it to compute the Coulomb energy of large systems of point charges. 相似文献
68.
Artem Malakho Evelyne Fargin Vincent Rodriguez Bertrand Poumellec 《Journal of solid state chemistry》2009,182(5):1156-2582
Thermally poled niobium borophosphate glasses in the system 0.55(0.95−y) NaPO3+y/2 Ba(PO3)2+0.05Na2B4O7)+0.45Nb2O5 were investigated for second order optical nonlinear (SON) properties. Bulk glasses were studied by Raman spectroscopy, thermal analysis, optical and dielectric measurements. The sodium to barium substitution does not lead to significant changes in optical properties, crystallization of glasses and coordination environment of polarizable niobium atoms. However, the ionic conductivity decreases drastically with the increase of barium concentration. Secondary ion mass spectroscopy has been used to determine the element distribution in the anode layer of the thermally poled glasses. The second order optical susceptibilities gradually decrease from χ(2)=2.8 pm/V to zero with the increase of barium content. Using a simple electrical model, variations of nonlinear optical responses have been correlated with dielectric characteristics. 相似文献
69.
Martin Python Evelyne Vallat-Sauvain Julien Bailat Didier Dominé Luc Fesquet Arvind Shah Christophe Ballif 《Journal of Non》2008,354(19-25):2258-2262
In the present paper, the structural and electrical performances of microcrystalline silicon (μc-Si:H) single junction solar cells co-deposited on a series of substrates having different surface morphologies varying from V-shaped to U-shaped valleys, are analyzed. Transmission electron microscopy (TEM) is used to quantify the density of cracks within the cells deposited on the various substrates. Standard 1 sun, variable illumination measurements (VIM) and Dark J(V) measurements are performed to evaluate the electrical performances of the devices. A marked increase of the reverse saturation current density (J0) is observed for increasing crack densities. By introducing a novel equivalent circuit taking into account such cracks as non-linear shunts, the authors are able to relate the magnitude of the decrease of Voc and FF to the increasing density of cracks. 相似文献
70.