全文获取类型
收费全文 | 200000篇 |
免费 | 2309篇 |
国内免费 | 672篇 |
专业分类
化学 | 111448篇 |
晶体学 | 3332篇 |
力学 | 7960篇 |
综合类 | 4篇 |
数学 | 19117篇 |
物理学 | 61120篇 |
出版年
2016年 | 2411篇 |
2015年 | 1778篇 |
2014年 | 2530篇 |
2013年 | 8052篇 |
2012年 | 5563篇 |
2011年 | 6983篇 |
2010年 | 4587篇 |
2009年 | 4482篇 |
2008年 | 6292篇 |
2007年 | 6466篇 |
2006年 | 6185篇 |
2005年 | 5666篇 |
2004年 | 5180篇 |
2003年 | 4626篇 |
2002年 | 4498篇 |
2001年 | 5867篇 |
2000年 | 4481篇 |
1999年 | 3583篇 |
1998年 | 2802篇 |
1997年 | 2833篇 |
1996年 | 2794篇 |
1995年 | 2583篇 |
1994年 | 2453篇 |
1993年 | 2353篇 |
1992年 | 2851篇 |
1991年 | 2718篇 |
1990年 | 2664篇 |
1989年 | 2688篇 |
1988年 | 2617篇 |
1987年 | 2622篇 |
1986年 | 2431篇 |
1985年 | 3340篇 |
1984年 | 3332篇 |
1983年 | 2750篇 |
1982年 | 2974篇 |
1981年 | 2894篇 |
1980年 | 2812篇 |
1979年 | 2941篇 |
1978年 | 3193篇 |
1977年 | 3011篇 |
1976年 | 2935篇 |
1975年 | 2787篇 |
1974年 | 2722篇 |
1973年 | 2757篇 |
1972年 | 1779篇 |
1971年 | 1482篇 |
1968年 | 1941篇 |
1967年 | 2133篇 |
1966年 | 1922篇 |
1965年 | 1500篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
991.
Spatio temporal dynamics of the positive column of a dc neon glow discharge is studied and investigated experimentally and theoretically. Spatio temporal analysis by means of biorthogonal decomposition method (BOD) gives insights into the mechanism of irregularity and can be employed for characterization of spatio‐ temporal complexity. In the weak nonlinear region, the wave dynamics is approximated by an amplitude equation of the Ginzburg‐Landau equation (CGLE) with complex coefficients and an additional integral term based on a fluid model. In the present work we deal with irregular spatio‐temporal data. A comparison between the numerical analysis of the experimental data and simulation results are studied. A good agreement between the dynamical behaviour for experimental space‐time data and theoretical simulation space‐time results was obtained. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
992.
Christian Kluger Wolfgang H. Binder 《Journal of polymer science. Part A, Polymer chemistry》2007,45(3):485-499
Block copolymers on basis of poly(oxanorbornenes) bearing functional moieties in their side‐chains are prepared via a combination of ROMP‐methods and 1,3‐dipolar‐“click”‐reactions. Starting from N‐substituted‐ω‐bromoalkyl‐oxanorbornenes and alkyl‐/perfluoroalkyl‐oxanorbornenes, block copolymers with molecular weights up to 25,000 g mol?1 were generated. Subsequent nucleophilic exchange‐reactions yielded the block‐copolymers functionalized with ω‐azidoalkyl‐moieties in one block. The 1,3‐azide/alkine‐“click” reactions with a variety of terminal alkynes in the presence of a catalyst system consisting of tetrakis(acetonitrile)hexafluorophosphate copper(I) and tris(1‐benzyl‐5‐methyl‐1H‐ [1,2,3]triazol‐4‐ylmethyl)‐amine furnished the substituted block copolymers in high yields, as proven by NMR‐spectroscopy. The resulting polymers were investigated via temperature‐dependent SAXS‐methods, revealing their microphase separated structure as well as their temperature‐dependent behavior. The presented method offers the generation of a large set of different block‐copolymers from only a small set of starting materials because of the high versatility of the “click” reaction, thus enabling a simple and complete functionalization after the initial polymerization reaction. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 485–499, 2007 相似文献
993.
The concept of crystallization dynamics method evaluating the miscibility of binary blend system including crystalline component
was proposed. Three characteristic rates, nucleation, crystal growth rates (N*, G*) and growth rate of conformation (G
c*) were used to evaluate the miscibility of PVDF/at-PMMA and PVDF/iso-PMMA by the simultaneous DSC-FTIR. N*, G* and G
c* depended remarkably on both temperature and blend fraction (ϕPMMA) for PVDF/at-PMMA system, which indicated the miscible system. PVDF/iso-PMMA showed small ϕPMMA dependency of N*, G* and G
c*, was estimated the immiscible system. The ΔT/T
m0 values, corresponding to Gibbs energy required to attend the constant G* and G
c*, evaluated from G* and G
c* showed the good linear relationships with different slope. The experimental results suggested that the concentration fluctuation
existed in PVDF/iso-PMMA system. 相似文献
994.
The analytical method using transfer function or impulse response is very effective for analyzing non-linear systems with localized non-linearities. This is because the number of non-linear equations can be reduced to that of the equations with respect to points connected with the non-linear element. In the present paper, analytical method for the steady state vibration of non-linear system including subharmonic vibration is proposed by utilizing convolution integral and the impulse response. The Galerkin method is introduced to solve the non-linear equations formulated by the convolution integral, and then the steady state vibration is obtained. An advantage of the present method is that stability or instability of the steady state vibration can be discriminated by the transient analysis from convolution integral. The three-degree-of-freedom mass-spring system is shown as a numerical example and the proposed method is verified by comparing with the result by Runge-Kutta-Gill method. 相似文献
995.
T. V. Ramakrishnan H. R. Krishnamurthy S. R. Hassan G. Venketeswara Pai 《Journal of Chemical Sciences》2003,115(5-6):767-774
Manganites of the LA1−x
Ca
x
MnO3 family show a variety of new and poorly understood electronic, magnetic and structural effects. Here we outline a new approach
recently proposed by us, where we argue that due to strong Jahn-Teller (JT) coupling with phonons the twofold degeneratee
g
states at the Mn sites dynamically reorganize themselves into localised, JT polaronsl with exponentially small inter-site hopping, and band-like, nonpolaronic statesb, leading to anew 2-band model for manganites which includes strong Coulomb and Hund’s couplings. We also discuss some results from a dynamical mean-field theory treatment
of the model which explains quantitatively a wide variety of experimental results, including insulator-metal transitions and
CMR, in terms of the influence of physical conditions on the relative energies and occupation of thel andb states. We argue that this microscopic coexistence of the two types of electronic states, and their relative occupation and
spatial correlation is the key to manganite physics.
Dedicated to Professor C N R Rao on his 70th birthday 相似文献
996.
997.
H. W. Wenz W. J. Lichtenberg H. Katterwe 《Fresenius' Journal of Analytical Chemistry》1991,341(3-4):155-165
Summary When a shot is fired, the projectile and the cartridge case are released from the weapon, as well as components of the priming charge and propellant, the so-called powder-gunshot residues. In order to solve firearm offences, it is therefore very important to determine the topography of trace-bearing areas on the bullet and the cartridge case, as well as the chemical composition of gunshot residue particles. Gunshot residue particles are made visible with the scanning electron microscope (SEM) and are analysed by means of energy-dispersive X-ray spectroscopy (EDXS) and lately also by means of wavelength-dispersive X-ray spectroscopy (WDXS). In addition to this, analyses of these particles are displayed by means of Auger electron spectroscopy (AES) and secondary ion mass spectroscopy (SIMS) and depth profiles are prepared. To determine the local distributions of gunshot residue elements with regard to their quantity, the direct Zeeman atomic absorption spectroscopy (DZ-AAS) is employed. Besides the determination of the chemical composition, the topography of the trace-bearing areas on the bullet and cartridge case plays an important part. For the detection of these surfaces, light optical and electron-optical methods are employed. Moreover, the use of opto-electronical testing systems has been attracting more and more attention recently. 相似文献
998.
Yang H. C. 《显形杂志》2007,10(1):83-89
Motionless mixers have found a large range of applications, including blending, reaction, dispersion, heat transfer and mass
transfer. Understanding the mixing processes that occur in these diverse systems is essential for predicting many aspects
of practical importance. The objective of this study is to perform the experimental investigations of mixing characteristics
for three different motionless mixers. The red color dye tracer was mixed in the main stream of green hair styling gel, and
then the mixing efficiency was quantified by calculating the percentage area concentration of red color at the outlet cross
section using a digital image processing technique. In the Sulzer SMX and YHC mixer, a single element mixes the fluid nearly
in two dimensions, and three-dimensional mixing is accomplished by the next elements aligned at 90o to their former one. In
the Sulzer SMX mixer, the flow appears to be globally well mixed after 5 elements, while in the YHC and YNU mixers, it is
necessary to globally well mix more than 1 and 2 elements. 相似文献
999.
R. Arnaldi R. Averbeck K. Banicz J. Castor B. Chaurand C. Cicalo A. Colla P. Cortese S. Damjanovic A. David A. De Falco A. Devaux A. Drees L. Ducroux H. En’yo A. Ferretti M. Floris A. Foerster P. Force N. Guettet A. Guichard H. Gulkanian J. Heuser M. Keil L. Kluberg J. Lozano C. Lourenço F. Manso A. Masoni P. Martins A. Neves H. Ohnishi C. Oppedisano P. Parracho P. Pillot G. Puddu E. Radermacher P. Ramalhete P. Rosinsky E. Scomparin J. Seixas S. Serci R. Shahoyan P. Sonderegger H.J. Specht R. Tieulent G. Usai R. Veenhof H.K. Wöhri 《The European Physical Journal C - Particles and Fields》2007,49(1):235-241
The NA60 experiment at the CERN SPS has studied low-mass muon pairs in 158 A GeV In–In collisions. A strong excess of pairs
is observed above the yield expected from neutral meson decays. The unprecedented sample size close to 400000 events and the
good mass resolution of about 2% made it possible to isolate the excess by subtraction of the decay sources. The shape of
the resulting mass spectrum shows some non-trivial centrality dependence, but is largely consistent with a dominant contribution
from π+π-→ϱ→μ+μ- annihilation. The associated ϱ spectral function exhibits considerable broadening, but essentially no shift in mass. The
pT-differential mass spectra show the excess to be much stronger at low pT than at high pT. The results are compared to theoretical model predictions; they tend to rule out models linking hadron masses directly to
the chiral condensate.
PACS 25.75.-q; 12.38.Mh; 13.85.Qk 相似文献
1000.
E.Y. Kang Yoon B. Kim K.Y. Kim Y.H. Chung H.K. Baik 《Journal of magnetism and magnetic materials》2006
FeSiBNb amorphous powder cores were prepared with the amorphous powder by gas atomization and subsequent hot pressing of resulting powder after creating oxide layers on the amorphous powder. Fully amorphous FeSiBNb powders with good soft magnetic properties were successfully obtained in the particle size range below 100 μm. FeSiBNb amorphous powder cores exhibit stable permeability up to 10 MHz, showing excellent high-frequency characteristics. 相似文献