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11.
12.
The redistribution of impurities in a sample in the shape of a slab filled with an isotropic liquid submitted to an external field is considered. The case in which the impurities are ions dissolved in the liquid, and the external field is an electric field is also investigated. It is shown that the intrinsic time connected with the presence of the electric field is proportional to the drift time. The constant of proportionality is of the order of the ratio between the thermal agitation energy and the electrostatic energy. A closed solution for the time evolution of the density of particles is obtained. The importance of the effect on real situations is investigated. The possible application of these results to nematic samples submitted to an external electric field is discussed. 相似文献
13.
Prado AG Pescara IC Evangelista SM Holanda MS Andrade RD Suarez PA Zara LF 《Talanta》2011,84(3):759-765
Biodiesel and diesel-like have been obtained from soybean oil by transesterification and thermal cracking process, respectively. These biofuels were characterized as according to ANP standards by using specific ASTM methods. Ethanol, gasoline, and diesel were purchased from a gas station. Deacetylation degree of chitosan was determined by three distinct methods (conductimetry, FTIR and NMR), and the average degree was 78.95%. The chitosan microspheres were prepared from chitosan by split-coating and these spheres were crosslinked using glutaraldehyde. The surface area of microspheres was determined by BET method, and the surface area of crosslinked microspheres was 9.2 m2 g−1. The adsorption isotherms of cooper, nickel and zinc on microspheres of chitosan were determined in petroleum derivatives (gasoline and diesel oil), as well as in biofuels (alcohol, biodiesel and diesel-like). The adsorption order in all fuels was: Cu > Ni > Zn. The elution tests presented the following preconcentration degrees: >4.5 to ethanol, >4.4 to gasoline, >4.0 to diesel, >3.8 to biodiesel and >3.6 to diesel-like. The application of chitosan microspheres in the metal ions preconcentration showed the potential of this biopolymer to enrich fuel sample in order to be analyzed by flame atomic absorption spectrometry. 相似文献
14.
Soares SF Galvão RK Araújo MC da Silva EC Pereira CF de Andrade SI Leite FC 《Analytica chimica acta》2011,(1):30-28
This work proposes a modification to the successive projections algorithm (SPA) aimed at selecting spectral variables for multiple linear regression (MLR) in the presence of unknown interferents not included in the calibration data set. The modified algorithm favours the selection of variables in which the effect of the interferent is less pronounced. The proposed procedure can be regarded as an adaptive modelling technique, because the spectral features of the samples to be analyzed are considered in the variable selection process. The advantages of this new approach are demonstrated in two analytical problems, namely (1) ultraviolet–visible spectrometric determination of tartrazine, allure red and sunset yellow in aqueous solutions under the interference of erythrosine, and (2) near-infrared spectrometric determination of ethanol in gasoline under the interference of toluene. In these case studies, the performance of conventional MLR-SPA models is substantially degraded by the presence of the interferent. This problem is circumvented by applying the proposed Adaptive MLR-SPA approach, which results in prediction errors smaller than those obtained by three other multivariate calibration techniques, namely stepwise regression, full-spectrum partial-least-squares (PLS) and PLS with variables selected by a genetic algorithm. An inspection of the variable selection results reveals that the Adaptive approach successfully avoids spectral regions in which the interference is more intense. 相似文献
15.
A. A. Lamberov I. F. Khalilov I. R. IL’yasov A. Sh. Bikmurzin V. M. Shatilov I. F. Nazmieva 《Russian Journal of Applied Chemistry》2011,84(8):1385-1393
Effect of modification with an alkali metal on the acid properties of alumina supports and on the oligomerization capacity
and working stability of Pd-Al2O3 catalysts was studied. 相似文献
16.
The electrical response of an electrolytic cell in which the diffusion of mobile ions in the bulk is governed by a fractional diffusion equation of distributed order is analyzed. The boundary conditions at the electrodes limiting the sample are described by an integro-differential equation governing the kinetic at the interface. The analysis is carried out by supposing that the positive and negative ions have the same mobility and that the electric potential profile across the sample satisfies the Poisson's equation. The results cover a rich variety of scenarios, including the ones connected to anomalous diffusion. 相似文献
17.
The set of correlated equilibria for a bimatrix game is a closed, bounded, convex set containing the set of Nash equilibria. We show that every extreme point of a maximal Nash set is an extreme point of the above convex set. We also give an example to show that this result is not true in the payoff space, i.e. there are games where no Nash equilibrium payoff is an extreme point of the set of correlated equilibrium payoffs. 相似文献
18.
G. Barbero L.R. Evangelista N.V Madhusudana 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,1(3):327-331
We analyse the influence of adsorbed ions and the resulting surface electric field and its gradient on the anchoring properties
of nematics with ionic conductivity. We take into account two physical mechanisms for the coupling of the nematic director
with the surface electric field: (i) the dielectric anisotropy and (ii) the coupling of the quadrupolar component of the flexoelectric
coefficient with the field gradient. It is shown that for sufficiently large fields near saturated coverage of the adsorbed
ions, there can be a spontaneous curvature distortion in the cell even when the anchoring energy is infinitely strong. We
also discuss the director distortion when the anchoring energy of the surface is finite.
Received: 29 September 1997 / Received in final from: 10 November 1997 / Accepted: 18 November 1997 相似文献
19.
T. Armstrong M. Baubillier J.C. Brient W. Beusch I.J. Bloodworth G. Boca M. Bonesini D. Bortoletto A. Burns J.N. Carney G. Cecchet G. Costa C. Evangelista B. Ghidini J.B. Kinson V. Lenti L. Mandelli F. Navach R. Zitoun 《Nuclear Physics B》1983,224(2):193-217
Results from the first PWA of the K+K? system produced by incident K?, are presented in the mass range from the threshold to 1.70 GeV. In the P and D waves only the φ and f′ mesons are observed and their production mechanism studied. A broad S wave peaking at 1.4 GeV is observed but the lack of information about its phase makes the search for new 0++ mesons inconclusive. 相似文献
20.