Two glasses, the first one with the composition of Li2O·2SiO2 and the second one with the addition of CaO, P2O5 and CaF2 in the stoichiometric ratio corresponding to fluoroapatite were prepared and their tendency to crystallize has been studied
by non-isothermal DTA analysis. The values of kinetic parameters calculated using the isoconversional integral method have
been used to determine the temperature dependencies of both the length of isothermal induction period and the length of overall
isothermal crystallization for both glasses. The estimated dependencies indicate that the glass containing CaO, P2O5 and CaF2 has a lower thermal stability. 相似文献
Research on mesoporous materials for biomedical purposes has experienced an outstanding increase during recent years. Since 2001, when MCM-41 was first proposed as drug-delivery system, silica-based materials, such as SBA-15 or MCM-48, and some metal-organic frameworks have been discussed as drug carriers and controlled-release systems. Mesoporous materials are intended for both systemic-delivery systems and implantable local-delivery devices. The latter application provides very promising possibilities in the field of bone-tissue repair because of the excellent behavior of these materials as bioceramics. This Minireview deals with the advances in this field by the control of the textural parameters, surface functionalization, and the synthesis of sophisticated stimuli-response systems. 相似文献
The hyperfine interaction of phosphorus donors in fully strained Si thin films grown on virtual Si(1-x)Ge(x) substrates with x< or =0.3 is determined via electrically detected magnetic resonance. For highly strained epilayers, hyperfine interactions as low as 0.8 mT are observed, significantly below the limit predicted by valley repopulation. Within a Green's function approach, density functional theory shows that the additional reduction is caused by the volume increase of the unit cell and a relaxation of the Si ligands of the donor. 相似文献
Optical properties of thin Cu2ZnSnS4 films produced by RF magnetron sputtering of preliminarily synthesized material are studied. Transmission and reflection coefficients are studied in a range from 0.4 to 26 μm. The optical band-gap width depending on substrate temperature is estimated; in optimal modes, it is equal to 1.47 eV. The study of electrical properties shows that Cu2ZnSnS4 possesses low charge-carrier mobility, μ = 1.9 cm2/(V s), at room temperature and hole concentration р = 5 × 1018 cm–3. Electron microscopy shows that the film possesses a polycrystalline structure with a crystallite size on the order of 100 nm. 相似文献
Organisations are concerned about measuring the performance of the product/service they deliver to their customers. In all types of organisations, if a proper performance assessment is to be developed, it should be measured in different dimensions. At University, the new study programs include the development and assessment of transversal competences due to their importance in enhancing the abilities and improving the employability of students. The achievement of transversal competences can be assessed in different levels/stages; for example, the 1st and 2nd years of a Bachelor’s degree; the 3rd and 4th years of a Bachelor’s degree and at Master’s level. The purpose of this paper is to integrate the research into performance management in organisations to develop an approach consisting of four components (a methodology, a solid and integrated performance management framework, graphical diagrams and quantitative techniques) to assess and manage the achievement of transversal competences through the different levels of study using a consolidated approach. The proposal uses the Analytic Network Process (ANP) to model dependences and feedback among the elements of the competences.
Classification is concerned with the development of rules for the allocation of observations to groups, and is a fundamental
problem in machine learning. Much of previous work on classification models investigates two-group discrimination. Multi-category
classification is less-often considered due to the tendency of generalizations of two-group models to produce misclassification
rates that are higher than desirable. Indeed, producing “good” two-group classification rules is a challenging task for some
applications, and producing good multi-category rules is generally more difficult. Additionally, even when the “optimal” classification
rule is known, inter-group misclassification rates may be higher than tolerable for a given classification model. We investigate
properties of a mixed-integer programming based multi-category classification model that allows for the pre-specification
of limits on inter-group misclassification rates. The mechanism by which the limits are satisfied is the use of a reserved
judgment region, an artificial category into which observations are placed whose attributes do not sufficiently indicate membership
to any particular group. The method is shown to be a consistent estimator of a classification rule with misclassification
limits, and performance on simulated and real-world data is demonstrated. 相似文献
For k, d?2, a Bethe tree is a rooted tree with k levels which the root vertex has degree d, the vertices from level 2 to k-1 have degree d+1 and the vertices at the level k are pendent vertices. So et al, using a theorem by Ky Fan have obtained both upper and lower bounds for the Laplacian energy of bipartite graphs. We shall employ the above mentioned theorem to obtain new and improved bounds for the Laplacian energy in the case of Bethe trees. 相似文献
[Cp*Rh(κ3N,N′,P- L )][SbF6] (Cp*=C5Me5), bearing a guanidine-derived phosphano ligand L , behaves as a “dormant” frustrated Lewis pair and activates H2 and H2O in a reversible manner. When D2O is employed, a facile H/D exchange at the Cp* ring takes place through sequential C(sp3)−H bond activation. 相似文献
Fluorescent nanoparticles, such as quantum dots, hold great potential for biomedical applications, mainly sensing and bioimaging. However, the inefficient cell uptake of some nanoparticles hampers their application in clinical practice. Here, the effect of the modification of the quantum dot surface with fluorinated ligands to increase their surface activity and, thus, enhance their cellular uptake was explored. 相似文献