首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   2156篇
  免费   79篇
  国内免费   22篇
化学   1439篇
晶体学   15篇
力学   35篇
数学   209篇
物理学   559篇
  2024年   8篇
  2023年   18篇
  2022年   54篇
  2021年   74篇
  2020年   57篇
  2019年   44篇
  2018年   35篇
  2017年   37篇
  2016年   92篇
  2015年   54篇
  2014年   73篇
  2013年   167篇
  2012年   144篇
  2011年   166篇
  2010年   89篇
  2009年   82篇
  2008年   120篇
  2007年   125篇
  2006年   115篇
  2005年   112篇
  2004年   96篇
  2003年   87篇
  2002年   77篇
  2001年   39篇
  2000年   41篇
  1999年   26篇
  1998年   26篇
  1997年   22篇
  1996年   20篇
  1995年   13篇
  1994年   16篇
  1993年   30篇
  1992年   17篇
  1991年   5篇
  1990年   12篇
  1989年   10篇
  1988年   3篇
  1986年   3篇
  1985年   6篇
  1984年   4篇
  1983年   6篇
  1982年   4篇
  1981年   7篇
  1980年   6篇
  1979年   2篇
  1978年   2篇
  1975年   4篇
  1969年   1篇
  1968年   1篇
  1966年   1篇
排序方式: 共有2257条查询结果,搜索用时 15 毫秒
871.
Compact composition operators on the Smirnov class   总被引:1,自引:0,他引:1  
We show that a composition operator on the Smirnov class is compact if and only if it is compact on some (equivalently: every) Hardy space for . Along the way we show that for composition operators on both the formally weaker notion of boundedness, and a formally stronger notion we call metric compactness, are equivalent to compactness.

  相似文献   

872.
We propose a way of using DEA cross-efficiency evaluation in portfolio selection. While cross efficiency is an approach developed for peer evaluation, we improve its use in portfolio selection. In addition to (average) cross-efficiency scores, we suggest to examine the variations of cross-efficiencies, and to incorporate two statistics of cross-efficiencies into the mean-variance formulation of portfolio selection. Two benefits are attained by our proposed approach. One is selection of portfolios well-diversified in terms of their performance on multiple evaluation criteria, and the other is alleviation of the so-called “ganging together” phenomenon of DEA cross-efficiency evaluation in portfolio selection. We apply the proposed approach to stock portfolio selection in the Korean stock market, and demonstrate that the proposed approach can be a promising tool for stock portfolio selection by showing that the selected portfolio yields higher risk-adjusted returns than other benchmark portfolios for a 9-year sample period from 2002 to 2011.  相似文献   
873.
Many simple and complex methods have been developed to solve the classification problem. Boosting is one of the best known techniques for improving the accuracy of classifiers. However, boosting is prone to overfitting with noisy data and the final model is difficult to interpret. Some boosting methods, including AdaBoost, are also very sensitive to outliers. In this article we propose a new method, GA-Ensemble, which directly solves for the set of weak classifiers and their associated weights using a genetic algorithm. The genetic algorithm utilizes a new penalized fitness function that limits the number of weak classifiers and controls the effects of outliers by maximizing an appropriately chosen $p$ th percentile of margins. We compare the test set error rates of GA-Ensemble, AdaBoost, and GentleBoost (an outlier-resistant version of AdaBoost) using several artificial data sets and real-world data sets from the UC-Irvine Machine Learning Repository. GA-Ensemble is found to be more resistant to outliers and results in simpler predictive models than AdaBoost and GentleBoost.  相似文献   
874.
    
An out-of-plane linear coefficient of thermal expansion (CTE) measurement method was developed to overcome the difficulty in measuring the in-plane deformation of freestanding thin films with a thickness of less than 1 μm. The out-of-plane profile measurement was relatively easy with the added advantage of simplicity, easy specimen preparation, and a simple test setup. White light interferometry was used for determining the out-of-plane thermal deformation as a function of temperature. Two types of supporting substrates, silicon and ZERODUR®, were used to account for the substrate effect on the CTE measurement. Attempts were made to fit the measured profiles using several peak functions and then find the optimal one. The test procedures were demonstrated using a freestanding 530-nm-thick aluminum film that was used in a previous in-plane measurement method. The calculated CTE value of this aluminum film was 23.7 ppm/°C, which was in good agreement with the in-plane measurement result. The out-of-plane CTE measurement method incorporating a zero CTE substrate was shown to be the most convenient and straightforward method.  相似文献   
875.
    
Photochromic molecule-incorporated optical devices offer desirable properties for photocontrollable optical systems, including advanced optical data storage and super-resolution imaging. However, these molecules require multiple illumination sources, such as UV and visible light, for reversible photochemical reactions, which restricts their potential for advanced application. This study reports an effective strategy for modulating photoisomerization via a single near-infrared light source assisted by plasmonically enhanced photoswitchable upconversion photoluminescence (UCPL). The proposed quasi-periodic metal nanostructures to facilitate the resonance modes in the broadband region enable the substitution of the detrimental high-energy light source (i.e., UV light) with near-infrared stimuli, which is associated with UCPL enhancement of over two orders with spectrum orthogonality. To validate this concept, the accelerated reversible-photoisomerization kinetics is experimentally confirmed by three- and tenfold amplification of the PL intensities of the photochromic disulfonyldiarylethene derivatives. Further validation of the proposed strategy is performed using photodynamic imaging, which reveals accelerated photoisomerization, high photocyclization stability, and high spatial resolution.  相似文献   
876.
    
With advances in the design, synthesis and analysis of various metallic nanoparticles and substrates, surface-enhanced Raman scattering (SERS) with plasmonic nanostructures has been extensively studied, and numerous SERS applications have been demonstrated in various applications including biomedical applications; however, the mechanism of SERS is not completely understood yet, and many challenges, including structural and spectral reproducibility, exist to achieve quantitative SERS analysis for practical and reliable use of SERS. Since SERS signal reproducibility mainly stems from structural reproducibility of targeted nanostructures, single-particle SERS analysis is highly beneficial in understanding SERS signals generated from different plasmonic nanostructures and provides analytical insights that cannot be obtained with ensemble-average spectrum-based analysis. Single-particle analysis is typically composed of single-particle images and spectra, and the statistical results show the single-particle SERS enhancement factor distribution of SERS signals and precise structure-spectrum relationship. In particular, studying and evaluating single-molecule SERS results require single-particle analysis to fully understand how single-particle images and spectra are correlated with how the position, orientation and resonance of a Raman dye affect single-molecule SERS signals from individual nanoparticles, and this is often correlated with computational simulation results. In this mini-review, we introduce key issues for quantitative SERS and present the fundamental SERS features obtained by single-particle analysis, focused on plasmonic nanogap structures since these structures offer the very strong electromagnetic field-based SERS signals with high controllability in structure and signal. We categorized the nanogap particle-based SERS platforms into two different classes – plasmonic nanogap strctures with an intergap (the gap between two structures; intergap nanoparticles) and plasmonic nanogap structures with an intragap (the gap formed inside a single particle; intragap nanoparticles). Finally, we discuss the challenges and perspectives in designing and synthesizing nanogap structures that deliver strong, reproducible, and reliable SERS signals for the quantitative SERS analysis.  相似文献   
877.
    
To investigate the effect of electrical conductivity on the energy-storage characteristics of anode materials in sodium-ion batteries, covalent organic nanosheets (CONs) are hybridized with highly conductive graphene nanosheets (GNs) via two different optimized synthesis routes, that is, reflux and solvothermal methods. The reflux-synthesized hybrid shows a well-overlapped 2D structure, whereas the solvothermally prepared hybrid forms a segregated phase in which the contact area between the CONs and GNs is reduced. These two hybrids synthesized by facile methods are fully characterized, and the results reveal that their energy-storage properties can be significantly improved by enhancing the electrical conductivity via the formation of a well-overlapped structure between CONs and GNs. The discharge capacity and rate capability of the reflux-synthesized hybrid was considerably larger than that of the bare CONs, highlighting that the improvement in the charge-carrier transport properties can improve the accessibility of Na ions to the surface of the hybrids. This synthetic methodology can be extended to the fabrication of high-performance anodes for Na-ion batteries.  相似文献   
878.
    
All-solid-state lithium-ion batteries (ASLBs) employing sulfide solid electrolytes are attractive next-generation rechargeable batteries that could offer improved safety and energy density. Recently, wet syntheses or processes for sulfide solid electrolyte materials have opened opportunities to explore new materials and practical fabrication methods for ASLBs. A new wet-chemical route for the synthesis of Li-deficient Li3−xPS4 (0≤x≤0.3) has been developed, which is enabled by dual solvents. Owing to its miscibility with tetrahydrofuran and ability to dissolve elemental sulfur, o-xylene as a cosolvent facilitates the wet-chemical synthesis of Li3−xPS4. Li3−xPS4 (0≤x≤0.15) derived by using dual solvents shows Li+ conductivity of approximately 0.2 mS cm−1 at 30 °C, in contrast to 0.034 mS cm−1 for a sample obtained by using a conventional single solvent (tetrahydrofuran, x=0.15). The evolution of the structure for Li3−xPS4 is also investigated by complementary analysis using X-ray diffraction, Raman, and X-ray photoelectron spectroscopy measurements. LiCoO2/Li–In ASLBs employing Li2.85PS4 obtained by using dual solvents exhibit a reversible capacity of 130 mA h g−1 with good cycle retention at 30 °C, outperforming cells with Li2.85PS4 obtained by using a conventional single solvent.  相似文献   
879.
    
The direct utilization of simple and abundant feedstocks in carbon-carbon bond-forming reactions to embellish sp3-enriched chemical space is highly desirable. Herein, we report a novel photochemical deoxygenative hydroalkylation of unactivated alkenes with readily available carboxylic acid derivatives. The reaction displays broad functional group tolerance, accommodating carboxylic acid-, alcohol-, ester-, ketone-, amide-, silane-, and boronic ester groups, as well as nitrile-containing substrates. The reaction is operationally simple, mild, and water-tolerant, and can be carried out on multigram-scale, which highlights the utility of the method to prepare value-added compounds in a practical and scalable manner. The synthetic application of the developed method is further exemplified through the synthesis of suberanilic acid, a precursor of vorinostat, a drug used for the treatment of cutaneous T-cell lymphoma. A novel mechanistic approach was identified using thiol as a nucleophilic catalyst, which forms a key intermediate for this transformation. Furthermore, electrochemical studies, quantum yield, and mechanistic experiments were conducted to support a proposed catalytic cycle for the transformation.  相似文献   
880.
We consider the Cauchy problem for the Schrödinger maps evolution when the domain is the hyperbolic plane. An interesting feature of this problem compared to the more widely studied case on the Euclidean plane is the existence of a rich new family of finite energy harmonic maps. These are stationary solutions, and thus play an important role in the dynamics of Schrödinger maps. The main result of this article is the asymptotic stability of (some of) such harmonic maps under the Schrödinger maps evolution. More precisely, we prove the nonlinear asymptotic stability of a finite energy equivariant harmonic map under the Schrödinger maps evolution with respect to non-equivariant perturbations, provided obeys a suitable linearized stability condition. This condition is known to hold for all equivariant harmonic maps with values in the hyperbolic plane and for a subset of those maps taking values in the sphere. One of the main technical ingredients in the paper is a global-in-time local smoothing and Strichartz estimate for the operator obtained by linearization around a harmonic map, proved in the companion paper [36]. © 2021 Wiley Periodicals LLC.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号