Excess enthalpies of aqueous ternary solutions of urea and polyols at 25°C

The heats of dilution of nine ternary solutions of urea and polyols have been determined at 25°C. Excess enthalpies and their virial coefficients h _xy have been evaluated and compared with the data reported in the literature for mono- and polyfunctional alcohols and other oxygenated nonelectrolytes. The group additivity approach of Savage and Wood was applied and the contributions to the enthalpy coefficients, due to the water mediated interactions between urea and the functional groups –CH₂–, –OH, and –O– were determined. On the other hand, by using empirical combination rules among the cross- and self-enthalpic interaction coefficients it is possible to emphasize the large differences in the behavior (even in the presence of urea) of the polyols (and in particular of cyclitols) and of saccharides.     

Semilinear elliptic problems near resonance with a nonprincipal eigenvalue

We consider the Dirichlet problem for the equation −Δu=λu±f(x,u)+h(x) in a bounded domain, where f has a sublinear growth and h∈L². We find suitable conditions on f and h in order to have at least two solutions for λ near to an eigenvalue of −Δ. A typical example to which our results apply is when f(x,u) behaves at infinity like a(x)|u|^q−2u, with M>a(x)>δ>0, and 1<q<2.     

Dynamics of Multi-Body Rotors: Numerical and Experimental FEM Analysis of the Scientific Earth Experiment Galileo Galilei Ground

Some small scientific satellites can be regarded as free, multi-body, supercritical and statorless rotors. Classical rotordynamics does not cover the dynamic behaviour and the stability analysis of such rotating systems, being focused on fixed rotors. Attitude dynamics usually deals with single rigid spacecrafts, sometimes equipped with flexible appendices like solar arrays or antennas. The case of the Galileo Galilei Ground (GGG) test facility is herewith analyzed through a numerical and experimental investigation on the dynamic behaviour of a fixed multi-body fast-spinning rotor in order to validate the design approach proposed for Galileo Galilei (GG) spacecraft.     

Solid-state gas sensors for breath analysis: A review

The analysis of volatile compounds is an efficient method to appraise information about the chemical composition of liquids and solids. This principle is applied to several practical applications, such as food analysis where many important features (e.g. freshness) can be directly inferred from the analysis of volatile compounds.