Significant progress in solar‐cell research is currently made by the development of metal–organic perovskites (MOPs) owing to their superior properties, such as high absorption coefficients and effective transport of photogenerated charges. As for other semiconductors, it is expected that the properties of MOPs may be significantly improved by a defined nanostructure. However, their chemical sensitivity (e.g., towards hydrolysis) prohibits the application of methods already known for the synthesis of other nanomaterials. A new and general method for the synthesis of various (CH3NH3)PbI3 nanostructures from a novel single‐source precursor is presented. Nanoporous MOP single crystals are obtained by a crystal‐to‐crystal transformation that is accompanied by spinodal demixing of the triethylene glycol containing precursor structure. Selective binding of a capping agent can be used to tune the particle shape of the MOP nanocrystals. 相似文献
Hexagonal Ca5(PO4)3F, known as natural crystal fluorapatite and oldest host‐crystal for Ln3+‐lasant ions, is presented as a Raman‐active material. High‐order Raman‐induced χ(3)‐nonlinear processes are discovered in natural crystals of fluorapatite under picosecond pumping at 1.064 μm and 0.532 μm wavelength. A multitude of Stokes and anti‐Stokes components is generated in the ultraviolet, visible and near‐infrared spectral region by stimulated Raman scattering (SRS) and Raman four‐wave mixing (FWHM), resulting in a frequency comb with a width of 520 THz. The spectral lines are identified and attributed to the ν1(Ag) vibration mode of the tetrahedral [PO4] units which is related to a Raman shift of ωSRS ≈ 965 cm−1. The first Stokes steady‐state Raman gain coefficient in the near‐infrared spectral range is estimated to be >0.38 cm·GW−1. Finally, a short review of SRS‐promoting vibration modes and observed χ(3)‐ nonlinear interactions in all known SRS‐active natural crystals (minerals) is given.
The hydrodynamic stability of the steady spherical front of a reaction accompanied by a strong increase in viscosity taking place in a radial, centrally symmetric flow of condensed reaction medium is considered. The flow is assumed to be bounded by two permeable concentric spherical surfaces. The stability is investigated in the linear approximation with respect to small perturbations. A relation is obtained for the dependence of the perturbation growth rate on the parameters of the problem: the viscosity ratio of the medium at the front, the ratio of the boundary surface radii to the radius of the front, and the dimensionless hydrodynamic resistances of the boundary surfaces. It is shown that the front is stable over almost the entire physical region of variation of the parameters and that instability occurs only in the case of a low hydrodynamic resistance of the outer boundary surface as the front approaches.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 46–53, May–June, 1988. 相似文献