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71.
The determination of doxazosin by high-performance liquid chromatography with fluorescence detection is described. Propanolol was used as the internal standard. Plasma samples were treated with methanol to precipitate the proteins. Doxazosin was isolated with C18 reversed-phase extraction columns. The determination limit is 1 ng/ml of plasma, while the extraction columns can be reused frequently. The method is applied to clinical trial samples. 相似文献
72.
Joseph B. Schlenoff W. Jack Rink Lawrence Seger 《Physica C: Superconductivity and its Applications》1991,180(5-6):387-393
Single crystals and polycrystalline pellets of the high-temperature cuprate superconductor Bi2Sr2Ca1Cu2O8 were doped at room temperature by electrochemical reduction at > 95% Coulombic efficiency using lithium dopant ions in propylene carbonate electrolyte. Cyclic voltammetry and potential step measurements on single crystals suggest an unusual reduction mechanism, with a diffusion coefficient for Li+ in the c-axis direction of bulk superconductor of ca. 3 × 10−11 cm2s−1. Sintered pellets of polycrystalline powder could be doped more rapidly, with an apparent diffusion coefficient of 7 × 10−8 cm2s−1. X-ray susceptibility analysis show extensive disordering occurs on heavy Li doping, with a first-order transition from a crystalline/superconducting to an amorphous/non-superconducting phase. Single, crystals of Bi2Sr2Ca1Cu2O8 exhibited a color change on reduction from metallic gray to golden bronze. The reduced material was highly air-sensitive, forming a hydroxide surface film on exposure to ambient atmosphere. 相似文献
73.
W.A. Mangum 《Natural Resource Modeling》1992,6(4):373-384
This paper presents a discrete age structured SI model of tracheal mite (Acarapis woodi (Rennie)) infestation of honey bees (Apis mellifera L.) at the colony level. The model describes the elevated honey bee attrition during winter and predicts that winter brood rearing should promote colony survival by decreasing the colony's infestation and increasing the colony's population. The model also predicts that swarming and the artificial removal of part of the colony's forager honey bees should reduce the colony's infestation level. 相似文献
74.
Chrysostomos Wesdemiotis Aberra Fura Fred W. McLafferty 《Journal of the American Society for Mass Spectrometry》1991,2(6):459-463
Collisionally activated dissociation and neutralization-reionization experiments reveal that protonation of ethanol leads to two distinct isomers, the classical ion CH3CH2OH+2 and the proton-bound complex C2H4…H+…OH2. The neutral counterpart of the latter is unstable, whereas that of the former can be produced in a bound state if the CH3CH2OH+2 precursor ion is formed under low ion source pressure conditions and, thus, with higher internal energies. This suggests that there are substantial differences in the geometries of CH3CH2OH+2 and the hypervalent CH3CH2OH2 ·. This provides only a partial explanation for unusual isotope effects; C2H5OD2 ·, CH3CD2OD2 ·, and CD3CH2OD2 · are substantially more stable than C2D5OD2 · and C2H5OH2 ·. 相似文献
75.
76.
To assess the historical and sociological significance of the cold fusion saga, researchers need accurate information about the dates of various events associated with the saga. Based on materials in the Cornell Cold Fusion Archive, this article provides both a chronology and citations to documentary evidence for cold fusion events from 1926 to the end of 1990. 相似文献
77.
L Jirovetz G Buchbauer W J?ger A Woidich A Nikiforov 《Biomedical chromatography : BMC》1992,6(3):133-134
After inhalation experiments with sandalwood oil and the pure fragrance compounds coumarin and alpha-terpineol, substances were detected and measured in the blood samples of test animals (mice) using gas chromatography/mass spectrometry (GC/MS) (MID) in connection with GC/FTIR (SWC), GC/AES (carbon and oxygen trace) and flame ionization detection/gas chromatography. Using tiglinic acid benzyl ester as the internal standard the following concentrations in serum could be found: alpha-santalol 6.1 ng/mL, beta-santalol 5.3 ng/mL and alpha-santalene 0.5 ng/mL. In separate inhalation experiments with coumarin and with alpha-terpineol the corresponding concentrations were 7.7 ng/mL and 6.9 ng/mL, respectively. 相似文献
78.
79.
Methotrexate (MTX) has been convalently attached to an IgG-type monoclonal antibody (791T/36) directed to tumour-associated antigen gp72. Conjugates were synthesized by the active ester method using MTX N-succinimidyl ester at various pH values (7.5-10.5). Following purification by gel filtration, high performance liquid chromatography was used to assess the free drug or its derivatives in samples of MTX-791T/36 conjugates previously treated (or not) with hydroxylamine. Quantitative analysis, performed on a reversed phase column (pore size 300 A) with isocratic acetonitrile-sodium acetate buffer (pH 4.8) as mobile phase, indicated no detectable amount of free methotrexate in hydroxylamine-treated conjugates even six months after their preparation. Similar observations were made with conjugates, whose synthesis were performed at pH greater than or equal to 10. In contrast, the presence of increasing amounts of drug/metabolite could be demonstrated in samples produced at lower pH values. Based on these findings, the pH-dependent kinetics of MTX release has been determined and used to design conditions under which stable MTX-791T/36 conjugates could be prepared without hydroxylamine reaction. 相似文献
80.
W. H. Langbeck 《Fresenius' Journal of Analytical Chemistry》1885,24(1):467-468
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