非有机溶剂液-固萃取体系提取血红蛋白研究

用聚乙二醇(PEG8000)修饰物混合吐温80-磷酸钾盐液-固萃取体系从血液中直接提取血红蛋白,考察了PEG8000修饰物、磷酸钾盐和吐温80的浓度及酸度和温度等因素对血红蛋白分离纯化的影响.结果表明,采用该体系的一次固相萃取率大于99%,一次反萃取率达到75%.所得到的血红蛋白干粉的纯度为99%.该方法不使用有机溶剂,无毒性,对蛋白质具有稳定和保护作用,易于放大规模使用.     

红外焦平面探测器制冷组件可靠性研究进展

红外焦平面探测器制冷组件的可靠性研究对推进组件工程化应用具有重要意义。介绍了国外在组件的可靠性模型、失效模式、加速应力以及可靠性试验等方面的研究进展,并对国内的组件可靠性研究状况作了简要分析,总结了对组件可靠性研究的总体思路,为国内红外焦平面探测器制冷组件的可靠性研究提供参考。     

A monolithic resonant terahertz sensor element comprising a metamaterial absorber and micro‐bolometer

In this article a monolithic resonant terahertz sensor element with a noise equivalent power superior to that of typical commercial room temperature single pixel terahertz detectors and capable of close to real time read‐out rates is presented. The detector is constructed via the integration of a metamaterial absorber and a micro‐bolometer sensor. An absorption magnitude of 57% at 2.5 THz, a minimum NEP of and a thermal time constant of 68 ms for the sensor are measured. As a demonstration of detector capability, it is employed in a practical Nipkow terahertz imaging system. The monolithic resonant terahertz detector is readily scaled to focal plane array formats by adding standard read‐out and addressing circuitry enabling compact, low‐cost terahertz imaging.     

颗粒圆孔射流碰撞并行直接数值模拟算法研究

本文对空间模式发展的颗粒圆孔射流碰撞进行了并行直接数值模拟算法研究。气相采用可压缩的N-S方程直接求解。颗粒相采用Lagrangian方法跟踪实际的颗粒运动。利用并行求解算法,实现了颗粒穿越边界面的模拟以及高效颗粒碰撞算法。考虑了颗粒和流体的双相耦合以及颗粒之间的碰撞。在本文的计算条件下,颗粒的直径远小于网格的间距,平均的Kolmogorov尺度和网格的间距在一个量级。气相和颗粒相的应力与实验的对比研究表明,本文的颗粒并行程序是可信的。     

Influence of mesoporous substrate morphology on the structural, optical and electrical properties of RF sputtered ZnO layer deposited over porous silicon nanostructure

Morphological, optical and transport characteristics of the RF sputtered zinc oxide (ZnO) thin films over the mesoporous silicon (PS) substrates have been studied. Effect of substrate porosity on the grain growth and transport properties of ZnO has been analyzed. Physical and optical properties of ZnO-PS structures were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), atomic force microscopy (AFM), and photoluminescence (PL) spectroscopy. Our experimental results indicate that on changing porosity of the PS substrates, regularity of the spatial distribution of the ZnO nanocrystallites can be controlled. While the morphology and grain size of ZnO depended strongly on the morphology and pore size of the PS substrates, the rectifying factors of the metal semiconductor junction were found to be different by a factor of 3. The deposition of semiconducting oxides on such mesoporous substrates/templates offers the possibility to control their properties and amplify their sensing response.     

Kinetics of N(2)O(5) hydrolysis on secondary organic aerosol and mixed ammonium bisulfate-secondary organic aerosol particles

The kinetics of the hydrolysis reaction of N(2)O(5) on secondary organic aerosol (SOA) produced through the ozonolysis of α-pinene and on mixed ammonium bisulfate-SOA particles was investigated using an entrained aerosol flow tube coupled to a chemical ionization mass spectrometer. We report room temperature uptake coefficients, γ, on ammonium bisulfate and SOA particles at 50% relative humidity of 1.5 × 10(-2) ± 1.5 × 10(-3) and 1.5 × 10(-4) ± 2 × 10(-5), respectively. For the mixed ammonium bisulfate-SOA particles, γ decreased from 2.6 × 10(-3) ± 4 × 10(-4) to 3.0 × 10(-4) ± 3 × 10(-5) as the SOA mass fraction increased from 9 to 79, indicating a strong suppression in γ with the addition of organic material. There is an order-of-magnitude reduction in the uptake coefficient with the smallest amount of SOA material present and smaller additional reductions with increasing aerosol organic content. This newly coated organic layer may either decrease the mass accommodation coefficient of N(2)O(5) onto the particle or hinder the dissolution and diffusion of N(2)O(5) into the remainder of the aerosol after it has been accommodated onto the surface. The former corresponds to a surface effect and the latter to bulk processes. The low value of the uptake coefficient on pure SOA particles will likely make N(2)O(5) hydrolysis insignificant on such an aerosol, but atmospheric chemistry models need to account for the role that organics may play in suppressing the kinetics of this reaction on mixed organic-inorganic particles.     

An Interconnect Bus Power Optimization Method

A simple yet accurate interconnect parasitical capacitance model is presented. Based on this model a novel interconnect bus optimization methodology is proposed. Combining wire spacing with wire ordering, this methodology focuses on bus dynamic power optimization with consideration of bus performance requirements. The optimization methodology is verified under a 65 nm technology node and it shows that with 50% slack in the routing space, a 33.039% power saving can be provided by the proposed optimization methodology for an intermediate video bus compared to the 27.68% power saving provided by uniform spacing technology. The proposed methodology is especially suitable for computer-aided design of nanometer scale on-chip buses.     

Some unexpected proportionalities between components of the spin—other-orbit interaction in the f shell

The reduced matrix elements of the component z _i of the inter-electronic spin-other-orbit interaction have been calculated for all the states of the atomic f shell. Three of the z _i , each of which belongs to the irreducible representation (30) of Racah's group G₂, are found to exhibit matrix elements that are often related to one another in ways that go beyond what the Wigner-Eckart theorem, generalized to G₂, would predict. Examples are presented for matrix elements whose bras belong to the IR (20) of G₂ and whose kets belong to (31). The challenges to current theory are discussed.     

A REALIZATION OF CERTAIN MODULES FOR THE <Emphasis Type="Italic">N</Emphasis> = 4 SUPERCONFORMAL ALGEBRA AND THE AFFINE LIE ALGEBRA <Emphasis Type="Italic">A</Emphasis><Stack><Subscript>2</Subscript><Superscript>(1)</Superscript></Stack>

We shall first present an explicit realization of the simple N = 4 superconformal vertex algebra L _c ^N?=?4 with central charge c = ?9. This vertex superalgebra is realized inside of the bcβγ system and contains a subalgebra isomorphic to the simple affine vertex algebra L _A1 \( \left(-\frac{3}{2}{\varLambda}_0\right) \). Then we construct a functor from the category of L _c ^N?=?4 -modules with c = ?9 to the category of modules for the admissible affine vertex algebra L _A1 \( \left(-\frac{3}{2}{\varLambda}_0\right) \). By using this construction we construct a family of weight and logarithmic modules for L _c ^N?=?4 and L _A1 \( \left(-\frac{3}{2}{\varLambda}_0\right) \). We also show that a coset subalgebra L _A1 \( \left(-\frac{3}{2}{\varLambda}_0\right) \) is a logarithmic extension of the W(2; 3)-algebra with c = ?10. We discuss some generalizations of our construction based on the extension of affine vertex algebra L _A1 (kΛ ₀) such that k + 2 = 1/p and p is a positive integer.     

Simple solar cells of 3.5% efficiency with antimony sulfide‐selenide thin films

Thin films of antimony sulfide‐selenide solid solutions (Sb₂S_x Se_3–x) were prepared by chemical bath deposition and thermal evaporation to constitute solar cells of a transparent conductive oxide (FTO)/CdS/Sb₂S_x Se_3–x/C–Ag. The cell parameters vary depending on the sulfide‐selenide composition in the films. The best solar cell efficiency of 3.6% was obtained with a solid solution Sb₂S_1.5Se_1.5 prepared by thermal evaporation of the precipitate for which the open circuit voltage is 0.52 V and short circuit current density, 15.7 mA/cm²under AM 1.5G (1000 W/m²) solar radiation. For all‐chemically deposited solar cells of Sb₂S_1.1Se_1.9 absorber, these values are: 2.7%, 0.44 V, and 15.8 mA/cm², and for Sb₂S_0.8Se_2.2, they are: 2.5%, 0.38 V and 18 mA/cm². (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim)