全文获取类型
收费全文 | 399篇 |
免费 | 12篇 |
国内免费 | 1篇 |
专业分类
化学 | 258篇 |
晶体学 | 14篇 |
力学 | 18篇 |
数学 | 48篇 |
物理学 | 74篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 14篇 |
2020年 | 9篇 |
2019年 | 9篇 |
2018年 | 15篇 |
2017年 | 18篇 |
2016年 | 10篇 |
2015年 | 13篇 |
2014年 | 17篇 |
2013年 | 32篇 |
2012年 | 21篇 |
2011年 | 34篇 |
2010年 | 31篇 |
2009年 | 19篇 |
2008年 | 31篇 |
2007年 | 24篇 |
2006年 | 18篇 |
2005年 | 15篇 |
2004年 | 14篇 |
2003年 | 12篇 |
2002年 | 9篇 |
2001年 | 10篇 |
2000年 | 3篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 7篇 |
1996年 | 1篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1983年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有412条查询结果,搜索用时 15 毫秒
281.
Summary We introduce a class of submanifolds, namely, Generalized Cauchy--Riemann (GCR) lightlike submanifolds of indefinite Kaehler
manifolds. We show that this new class is an umbrella of invariant (complex), screen real [8] and CR lightlike [6] submanifolds.
We study the existence (or non-existence) of this new class in an indefinite space form. Then, we prove characterization theorems
on the existence of totally umbilical, irrotational screen real, complex and CR minimal lightlike submanifolds. We also give
one example each of a non totally geodesic proper minimal GCR and CR lightlike submanifolds. 相似文献
282.
Let q??3 be a prime and let H(?? q ) be the Hecke group associated to q. Let m be a positive integer and H m (?? q ) be the mth power subgroup of H(?? q ). In this work, we study the commutator subgroups of the power subgroups H m (?? q ) of H(?? q ). Then, we give the derived series for all triangle groups of the form (0;2,q,n) for n a positive integer, since there is a nice connection between the signatures of the subgroups we studied and the signatures of these derived series. 相似文献
283.
The theory of higher-dimensional shifts of finite type is stilllargely an open area of investigation. Recent years have seenmuch activity, but fundamental questions remain unanswered.In this paper we consider the following basic question. Givena shift of finite type (SFT), under what topological mixingconditions are we guaranteed the existence of Bernoulli (oreven K, mixing, or weakly mixing) invariant measures? 相似文献
284.
In the present paper, we estimate the rate of pointwise convergence of the Bézier Variant of Chlodowsky operators Cn,α for functions, defined on the interval extending infinity, of bounded variation. To prove our main result, we have used some methods and techniques of probability theory. 相似文献
285.
Umit Hakan Yildiz Elif Sahin Idris M. Akhmedov Cihangir Tanyeli Levent Toppare 《Journal of polymer science. Part A, Polymer chemistry》2006,44(7):2215-2225
A new polythiophene derivative was synthesized by both chemical and electrochemical oxidative polymerization of 1‐(1‐phenylethyl)‐2,5‐di(2‐thienyl)‐1H‐pyrrole (PETPy). Of which the chemical method produces a polymer that is completely soluble in organic solvents. The structures of both the monomer and the soluble polymer were elucidated by nuclear magnetic resonance (1H and 13C NMR) and Fourier transform infrared (FTIR) spectroscopy. The average molecular weight has been determined by gel permeation chromatography to be Mn = 3.29 × 103 for the chemically synthesized polymer. Polymer of PETPy was synthesized via potentiostatic electrochemical polymerization in acetonitrile (AN)/NaClO4/LiClO4 (0.1 M) solvent–electrolyte couple. Characterizations of the resulting polymer were performed by cyclic voltammetry, FTIR, scanning electron microscopy, and UV–vis spectroscopy. Four‐probe technique was used to measure the conductivities of the samples. Moreover, the spectroelectrochemical and electrochromic properties of the polymer films were investigated. In addition, dual‐type polymer electrochromic devices based on P(PETPy) with poly(3,4‐ethylenedioxythiophene) were constructed. Spectroelectrochemistry, electrochromic switching, and open circuit stability of the devices were studied. They were found to have good switching times, reasonable contrasts, and optical memories. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2215–2225, 2006 相似文献
286.
Nitrogen adsorption at 77 K on mesoporous silica materials (MPS) with varying synthesis time and treatment conditions was
investigated. Scanning electron microscope (SEM) and X-ray diffraction (XRD) were also used to characterize the mesoporous
materials. This study was performed at 6, 24 and 72-h synthesis times. It is shown that 6-h is not enough for complete formation
of the MPS material and at least 24-h is necessary. The pore structure starts decaying for the 72-h synthesis time. The three-after-synthesis
treatment conditions used were 1) washed, 2) washed and calcined and 3) directly calcined after synthesis. Ethanol/HCl mixtures
were used for washing and calcinations were performed at 550°C. Among these samples, directly washed sample yields the lowest
adsorption capacity while washed and calcined sample yields the highest adsorption capacity. Hence, it is concluded that washing
stabilizes the structure before high temperature treatment. 相似文献
287.
Gorkem Sahin Aylin Ziylan Albayrak Zeynep Sarayli Duygu Avci 《Journal of polymer science. Part A, Polymer chemistry》2006,44(23):6775-6781
Novel aromatic mono‐ and diphosphonate monomers based on t‐butyl α‐bromomethacrylate were prepared for use in dental composites. The synthesis of the two monomers involved three steps: the reaction of diethyl phosphite with phenol or hydroquinone, the rearrangement of the resulting phosphate derivatives into o‐hydroxyaryl phosphonates with lithium diisopropylamide, and the reaction of o‐hydroxyaryl phosphonates with t‐butyl α‐bromomethacrylate. Then, the selective hydrolysis of the t‐butyl ester groups of the monomers with trifluoroacetic acid gave the other carboxylic acid containing monomers. The photopolymerization behaviors of the synthesized monomers with glycerol dimethacrylate and triethylene glycol dimethacrylate were investigated with photodifferential scanning calorimetry at 40 °C with 2,2′‐dimethoxy‐2‐phenyl acetophenone as the photoinitiator. The hydrolysis of the t‐butyl groups of the monomers increased the reactivity and the rates of polymerization of the monomers. The mixtures of the acid monomers showed rates of polymerizations similar to those of homopolymerizations of triethylene glycol dimethacrylate and glycerol dimethacrylate. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 6775–6781, 2006 相似文献
288.
M. Duran Toksarı Selçuk K. İşleyen Ertan Güner Ömer Faruk Baykoç 《Applied Mathematical Modelling》2008
In this paper, we introduced learning effect into assembly line balancing problems. In many realistic settings, the produced worker(s) (or machine(s)) develops continuously by repeated the same or similar activities. Therefore, the production time of product shortens if it is processed later. We show that polynomial solutions can be obtained for both simple assembly line balancing problem (SALBP) and U-type line balancing problem (ULBP) with learning effect. 相似文献
289.
Filiz Maden Yücel Ertan Yildirim Tuncer Caykara 《Journal of polymer science. Part A, Polymer chemistry》2019,57(10):1140-1146
2‐Hydroxyethyl acrylamide was successfully polymerized via single‐electron transfer initiation on the silicon surface and propagation through the reversible addition–fragmentation chain transfer (SET‐RAFT) polymerization at ambient temperature for different polymerization times. This work is the first time application of the surface‐initiated SET‐RAFT mechanism to afford the preparation of well‐defined poly(2‐hydroxyethyl acrylamide) [poly(HEAAm)] brushes at ambient temperature. The polymerization was well controlled and produced poly(HEAAm) brushes on the silicon surface with a well‐defined target molecular weight. The controlled nature of the polymerization was further demonstrated in the presence of sulfur atoms at the chain ends in X‐ray photoelectron spectroscopy experiments. The grafting density (σ, chains nm?2) and the average distance between grafting points (D, nm) were found to be 0.42 chains nm?2 and 1.74 nm, respectively, indicating moderate grafting density. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 1140–1146 相似文献
290.
Rabbi Hossain Md. Fazle Sahin Ahmet Z. 《Journal of Thermal Analysis and Calorimetry》2021,143(2):1345-1360
Journal of Thermal Analysis and Calorimetry - The biggest shortcoming of conventional solar still is its limited productivity. In this work, improvement of solar still performance using two hybrid... 相似文献