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怀孕期头发中一些元素含量的变化趋势 总被引:5,自引:1,他引:4
用同步辐射激发X射线荧光分析,对11个产妇怀孕期间头发内一些元素含量的变化趋势进行了测量,在各自对比的基础上,得到了一些结果。 相似文献
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R.L. Strong B. Firey F.W. deWette J.L. Erskine 《Journal of Electron Spectroscopy and Related Phenomena》1983,29(1):187-190
High-resolution electron energy loss spectroscopy (EELS) and lattice dynamical calculations based on pair interactions are used to investigate oxygen chemisorption on Al(111). The O/Al(111) System is complicated by the simultaneous formation of an oxygen overlayer and underlayer. Oxygen atoms at overlayer and underlayer sites near the Al(111) surface produce well-defined vibrational loss peaks in EELS spectra, however, dynamical coupling between the oxygen atoms and with the host lattice cause vibrational energies to shift with overlayer and underlayer concentrations. These shifts as well as structural parameters of the O/Al(111) complex can be deduced from a slab model of the surface lattice dynamics. 相似文献
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Photoelectron spectra of the methoxy species formed by the decomposition of methanol on nickel(111) indicate that the C-O-nickel bond is normal or nearly normal to the metal surface. This structural assignment for the adsorbate complex is consistent with new photoelectron data using linearly polarized synchrotron radiation. 相似文献
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It has been demonstrated that an element of planar chirality can influence the formation of an adjacent spiroketal stereocenter. Appropriately functionalized enantiomerically pure 1- and 2-sulfinyl 1,3-dien-5-ones and their corresponding iron(0) tricarbonyl complexes (7, 17) have been prepared, and the derived spiroketals (8, 18) are made in good to excellent diastereoselectivity. A preliminary exploration of the combined effects of planar and central chirality upon the diastereoselectivity revealed matched and mismatched combinations (14). 相似文献
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P. L. De Verter E. W. Dean G. m. b. H. Mono W. Steuer E. Ott L. S. Walters P. Lebeau P. Marmasse Siemens A. G. Halske J. Ŝvéda A. Dobrjanski W. H. Ross H. L. Trumbull K. Kling G. G. Oberfell S. D. Sbinkle S. B. Meserve A. M. Erskine B. Hilliger F. Krüger O. Reinkober H. Riegger H. Deringer E. Berl K. Andress L. Jordan J. R. Eckman 《Analytical and bioanalytical chemistry》1929,76(11-12):456-463
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Vibrational excitations of nitrogen on W(100) are investigated over the 100–300 K temperature range using elastic and inelastic electron scattering. New vibrational modes of nitrogen are identified that require different mode assignments from previous work. Experimental evidence for a molecular precursor to the atomic β2 phase of adsorbed nitrogen is presented. Coverage dependent studies of vibrational modes suggests conversion between two different molecular surface phases and between atomic and molecular phases. A new ordered nitrogen phase characterized by a (4 × 1) LEED pattern is observed. The new phase appears to consist of orthogonal domains of p(4 × 1) symmetry that contain atomic nitrogen at the four fold sites (the β2 atomic phase) with additional bridge-bonded nitrogen atoms in the unit cell. 相似文献
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Dicyclohexylamine is determined in sodium cyclamate at levels of concentration down to the order of 1 ppm by measurement of the yellow colour of the chloroform extract of its Bromophenol Blue complex. 相似文献