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51.
It is shown that a minimal graph with a normal at infinity is in a-priori bounded vertical distance from its approximating halfcatenoid. This is used to show that the exterior contact angle problem is wellposed under natural geometric conditions on the domain, while the exterior Dirichlet problem can be solvable only for data which satisfy an oscillation bound.This paper was written under the support of the Deutsche Forschungsgemeinschaft while the author was visiting the department of mathematics at Stanford University.This article was processed by the author using the LaTEX style filepljour1 from Springer-Verlag. 相似文献
52.
The probability of first return to the initial intervalx and the diffusion tensorD
x are calculated exactly for a ballistic Lorentz gas on a Bethe lattice or Cayley tree. It consists of a moving particle and a fixed array of scatterers, located at the nodes, and the lengths of the intervals between scatterers are determined by a geometric distribution. The same values forx andD
x apply also to a regular space lattice with a fraction of sites occupied by a scatterer in the limit of a small concentration of scatterers. If backscattering occurs, the results are very different from the Boltzmann approximation. The theory is applied to different types of lattices and different types of scatterers having rotational or mirror symmetries. 相似文献
53.
Crawford G Daubenmier CM Fulton R Fujino D Gan KK Honscheid K Kagan H Kass R Lee J Malchow R Morrow F Skovpen Y Sung M White C Whitmore J Wilson P Butler F Fu X Kalbfleisch G Lambrecht M Ross WR Skubic P Snow J Wang PL Wood M Bortoletto D Brown DN Fast J McIlwain RL Miao T Miller DH Modesitt M Schaffner SF Shibata EI Shipsey IP Wang PN Battle M Ernst J Kroha H Roberts S Sparks K Thorndike EH Wang CH Dominick J Sanghera S Skwarnicki T Stoynowski R Artuso M He D Goldberg M Horwitz N Kennett R 《Physical review letters》1993,71(20):3259-3262
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Glass capillaries coated with Chirasil-Val, a chirally functionalised polysiloxane, are capable in principle of resolving all protein amino-acid enantiomers in a single run and within a short analysis time, thus allowing for example the quantitative amino acid determination by enantiomer labelling. The elution characteristics of the individual amino acids however are also dependent upon the chemical nature of the capillary wall surface, and a surface pretreatment is found to be necessary if all protein amino acids are to be analysed. Of the various methods of pretreatment tested, etching of borosilicate glass with gaseous HCl followed by deposition of colloidal silicic acid is considered to be the most suitable. 相似文献
56.
Gerhard Holxe Titus A. Jenny Petr Nesvadba Albert Gossauer Ludger Ernst Walter Keller Christoph Kratky 《Helvetica chimica acta》1991,74(6):1287-1295
On treatment with H2SO4/MeOH, epimerization of hexamethyl cis-5,6-dihydroxycobyrinate c,8-lactam ( 3 ) takes place quantitatively at C(6), yielding the corresponding trans-diol 4 . The corresponding lactone 7 , whose structure has been established by X-ray analysis, is obtained from xanthocorrinoids 5 and 6 under similar conditions. 相似文献
57.
Computerized quantification of components under overlapping chromatographic peaks is done by calibration of chromatograms against component mixtures. For conventional (single-channel) detectors, the limitations of earlier methods based on ordinary multiple regression, can be circumvented by data reduction with the aid of principal component analysis with the partial least-squares approach. Simulation studies show that the method can be applied even when there is severe peak overlap, unstable baseline, noisy chromatograms or non-linear detector response. Advantages in the quantification of fused peaks by means of multichannel detectors are outlined. Present limitations on the quantitative evaluation of several overlapping component peaks from a single spectro-chromatogram by means of the partial least-squares method combined with multiple regression on the pure component spectra, are discussed with respect to practical high-performance liquid chromatography. 相似文献
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Automatic titrators are designed to do exactly what a lab-technician used to do. Much more sophisticated automation of volumetry is possible. Omegaphoresis [3] in buffer-free [2] sample solutions automatically creates a stationary multiple component titration curve or zoned pattern with normalized concentrations of each separated species. An automatic measurement of each zone length yields their quantity. Simultaneous automatic detection of all the zones in a 10–20 component solution in less than 2 minutes, with a precision of ±2%, a required amount of the order of less than one nanomol and a resolution of ±pK < 0.01 replaces acid-base, complexometric, and certain types of redox-titrimetry. An option of the method allows identification of the components as well. 相似文献