Oxygen separation induced by Xe ion beam upon electrodeposited oxygen-nickel and oxygen-chromium systems on iron substrate studied by conversion electron Mössbauer spectroscopy

Nickel was electrodeposited on one side and chromium on the other side of a sheet of α-iron enriched (∼85%) with⁵⁷Fe. The electrodeposited Ni and Cr contained oxygen and it could be separated by 500 keV xenon implantation. The separated oxygen formed an amorphous metal-oxide interphase at the interface of iron substrate and electrodeposited Ni or Cr.     

Mössbauer and XRD study of pulse plated Fe–P and Fe–Ni thin layers

⁵⁷Fe conversion electron Mössbauer spectroscopy, X-ray diffraction, electrochemical and magnetic measurements were used to study pulse electroplated Fe–P and Ni–Fe coatings. XRD and ⁵⁷Fe CEMS measurements revealed the amorphous character of the novel pulse plated Fe–P alloys. CEM spectra indicated significant differences in the short range order and in the magnetic anisotropy between the Fe–P deposits pulse plated at medium long deposition time (t _on?=?2 ms), with short relaxation time (t _off?=?9 ms) and low current density (I _p?=?0.05 Acm^?2) or at short deposition time (t _on?=?1 ms) with long relaxation time (t _off?=?250 ms) and high current density (I _p?=?1.0 Acm^?2). The broad peaks centred around the fcc reflections in XRD of the pulse plated Ni-22 wt.% Fe deposit reflected a microcrystalline Ni–Fe alloy with a very fine, 5–8 nm, grain size. The CEM spectrum of the pulse plated Ni-22 wt.% Fe coating corresponded to a highly disordered solid solution alloy containing a minute amount of ferrihydrite. Extreme favourable soft magnetic properties were observed with these Ni–Fe and Fe–P pulse plated thin layers.     

Effect of FeCl3 and acetone on the structure of Na–montmorillonite studied by Mössbauer and XRD measurements

⁵⁷Fe Mössbauer spectroscopy, X-ray diffraction, X-ray fluorescence spectroscopy and infrared spectroscopy were used to study the effect of FeCl₃ and acetone on the structure of a Na–bentonite. XRD indicated the incorporation of Fe³⁺ ions into the interlayer space since the basal lattice spacing of montmorillonite increased to 1.6 from 1.24 nm after treatment with FeCl₃ dissolved in acetone. Interlayer Na⁺ ions could be exchanged to Fe³⁺. Magnetically split Mössbauer subspectra with internal magnetic fields 41 and 46 T at 74 K, were associated with two main Fe³⁺ microenvironments within the interlayer regions. The resultant Fe–montmorillonite was successfully applied as a catalyst in the preparation of 1,1-diacetates from aromatic aldehydes and acetic acid anhydride.     

Crystal structure of rosmanol-9-ethylether

The title compound: 2H-10,4a-(epoxy-methano)-phenantren-12-one-1,3,4,9,10,10a-hexahydro-5,6-dihydroxy-9-etoxy-1,1-dirnethyl-7-(1-methylethyl), was isolated fromSalvia officinalis L. andHyssopus officinalis L. C₂₂H₃₀O₅, orthorhombic, P2₁2₁2₁, (No. 19)a=8.309(1),b=11.320(2),c=22.060(3) Å,V=2075.0(9) ų,Z=4,D _x=1.199 g·cm^–3, (CuK)=1.54184 Å,=6.43 cm^–1, F(000)=808,T=296(1) K. The structure was solved by direct methods and refined toR=0.047 for 1824 observed reflections collected on a CAD-4 diffractometer. In the course of structure refinement conformational disorder of the isopropyl moiety and the terminal methyl group pertaining to the ethoxy ligand was established. They result altogether in four different conformers.Alternatively it can be termed 9-ethoxyrosmanol.     

Intervals in lattices of quasiorders

We investigate the structure of intervals in the lattice of all closed quasiorders on a compact or discrete space. As a first step, we show that if the intervalI has no infinite chains then the underlying space may be assumed to be finite, and in particular,I must be finite, too. We compute several upper bounds for its size in terms of its heighth, which in turn can be computed easily by means of the least and the greatest element ofI. The cover degreec of the interval (i.e. the maximal number of atoms in a subinterval) is less than 4h. Moreover, ifc4(n–1) thenI contains a Boolean subinterval of size 2 ⁿ , and ifI is geometric then it is already a finite Boolean lattice. While every finite distributive lattice is isomorphic to some interval of quasiorders, we show that a nondistributive finite interval of quasiorders is neither a vertical sum nor a horizontal sum of two lattices, with exception of the pentagon. Many further lattices are excluded from the class of intervals of quasiorders by the fact that no join-irreducible element of such an interval can have two incomparable join-irreducible complements. Up to isomorphism, we determine all quasiorder intervals with less than 9 elements and all quasiorder intervals with two complementary atoms or coatoms.     

Standard completions for quasiordered sets

A standard completion for a quasiordered set Q is a closure system whose point closures are the principal ideals of Q. We characterize the following types of standard completions by means of their closure operators:

1. V-distributive completions,
2. Completely distributive completions,
3. A-completions (i.e. standard completions which are completely distributive algebraic lattices),
4. Boolean completions.

Moreover, completely distributive completions are described by certain idempotent relations, and the A-completions are shown to be in one-to-one correspondence with the join-dense subsets of Q. If a pseudocomplemented meet-semilattice Q has a Boolean completion ?, then Q must be a Boolean lattice and ? its MacNeille completion.