Thermoluminescence (TL) studies of cobalt-doped Al2O3 crystals irradiated with X-rays have shown that the TL glow curve consists of three peaks at 105, 195 and 260°C. Bleaching, annealing and quanching studies have been performed in order to understand the nature of colour centers responsible for the formation of the three peaks. The values of the fundamental parameters like trap depth and frequency factor are estimated from TL data and the results obtained are discussed. 相似文献
Elevated irradiation temperature studies with NaYF4 samples reveal that the intensity of the two glow peaks observed around 120 and 180°C enhances. The effect of temperature of irradiation (Tirr) on the sensitisation of the both peaks are studied. The half lives of these glow peaks were calculated and concluded that the half lives of these peaks decreases with the increase in irradiation temperatures. 相似文献
Infrared investigations demonstrate a chemical interaction of quartz in hydrogen atmosphere during mechanical activation: By means of the SiH stretching band the number of formed SiH-groups is estimated as a function of the period of activation. of activation. This number is more than one order of magnitude less than the total number of adsorbed molecules. 相似文献
X-ray (XS) and X-ray photoelectron (XPS) spectra are reported for vanadium oxides. Because of the multivalent character of vanadium in the oxide system high quality measurements can be used for chemical shift investigation. Both inner level and valence band spectroscopy give information on the electronic structure and their systematic change with increasing oxidation state. The experimental results are discussed favourable in terms of molecular orbital theory (MO-theory). The complete set of XS and XPS data reported here for V-oxides allows the identification of unknown vanadium oxidation states too. 相似文献
The microporous aluminophosphate SAPO-35 with the levyne-like structure was prepared hitherto only with quinuclidine as templating agent. In this paper it is shown that also cyclohexylamine can be used for the synthesis of SAPO-35. The samples were characterized by X-ray diffraction, thermal analysis, adsorption isotherms, and micrographs. These investigations confirm the few data reported on SAPO-35 and give further informations. The number of acid sites (Brönstedt centres) was determined from the differential molar heat of chemisorption of NH3 to three per unit cell. 相似文献
Silicalite-1, the aluminum-free end number of the ZSM-5 zeolites, was synthesized from a batch composition of 3.25 Na2O · 40.0 SiO2 · 552 H2O · 2.00 TPA by using tetrapropylammonium bromide (TPA-Br) or chloride (TPA-Cl) as templates in the temperature range of 100 to 175 °C in a batch system. Conversion of silica in the starting batch composition into silicalite-1 in the product was followed quantitatively. The activation energies of nucleation and crystallization were determined as 37.2 and 66.5 kJ/mol, respectively. The use of TPA-Cl as the template instead of TPA-Br results in longer induction period for crystallization to start and a larger crystal size in product. 相似文献
C12H10N2O2; monoclinic, space group P1 21/c 1 (Z = 2), 826 observed independent reflexions, R = 0.043; lattice dimensions at 25 °C, a = 975.8(3) pm, b = 466.8(1) pm, c = 1186.8(2) pm, β = 108.51(1)°. 相似文献