Energising the E-factor: The E+-factor

The E-factor has become an important measure for the environmental impact of (bio)chemical reactions. However, summing up the obvious wastes generated in the laboratory neglects energy-related wastes (mostly greenhouse gases) which are generated elsewhere. To estimate these wastes, we propose to extend the E-factor by an energy-term (E⁺-factor). At the example of a lab-scale enzyme fermentation, we demonstrate that the E⁺-factor can constitute a multiple of the classical E-factor and therefore must not be neglected striving for a holistic estimation of the environmental impact.     

Analytic vectors,anomalies and star representations

It is hinted that anomalies are not really anomalous since (at least in characteristic examples) they can be related to a lack of common analytic vectors for the Hamiltonian and the observables. We reanalyze the notions of analytic vectors and of local representations of Lie algebras in this light, and show how the notion of preferred observables introduced in the deformation (star product) approach to quantization may help give an anomaly-free formulation to physical problems. Finally, some remarks are made concerning the applicability of these considerations to field theory, especially in two dimensions.     

A general halide-to-anion switch for imidazolium-based ionic liquids and oligocationic systems using anion exchange resins (A- form)

Further studies on the application of an AER (A(-) form) method broadened the anion exchange scope of representative ionic liquids and bis(imidazolium) systems. Depending on the hydrophobicity nature of the targeted imidazolium species and counteranions, different organic solvents were used to swap halides for assorted anions, proceeding in excellent to quantitative yields.     

Peroxygenase-Catalysed Selective Oxidation of Silanes to Silanols

A peroxygenase-catalysed hydroxylation of organosilanes is reported. The recombinant peroxygenase from Agrocybe aegerita (AaeUPO) enabled efficient conversion of a broad range of silane starting materials in attractive productivities (up to 300 mM h⁻¹), catalyst performance (up to 84 s⁻¹ and more than 120 000 catalytic turnovers). Molecular modelling of the enzyme-substrate interaction puts a basis for the mechanistic understanding of AaeUPO selectivity.