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91.
Veronika Nagy Erika Turcsi Péter Molnár Zoltán Szabó József Deli 《Tetrahedron letters》2007,48(51):9012-9014
Latoxanthin was isolated as a minor carotenoid from the ripe fruits of yellow tomato shaped paprika (Capsicum annuum var. lycopersiciforme flavum) and identified as (all-E,3S,5R,6R,3′S,5′R,6′S)-5′,6′-epoxy-5,6,5′,6′-tetrahydro-β,β-carotene-3,5,6,3′-tetrol based on spectral data. 相似文献
92.
Erika Szunyogová Katarína Györyová Daniela Hudecová Lenka Piknová J. Chomič Zuzanna Vargová V. Zeleňák 《Journal of Thermal Analysis and Calorimetry》2007,88(1):219-223
The thermal decomposition of the complexes Zn(form)2⋅2phen
(I), Zn(ac)2⋅2phen
(II), Zn(prop)2⋅2phen
(III), Zn(but)2⋅2phen
(IV), where phen=phenazone, form=formiate,
ac=acetate, prop=propionate, but=butyrate has been studied in air by TG/DTG
and DTA methods. The possible mechanism of the thermal decomposition was proposed.
The final product of thermal decomposition was ZnO. IR data show unidentate
coordination of carboxylate group to Zn(II) ion. The complexes were tested
against various strains of microorganisms and their efficiency decrease in
the sequence yeasts >bacteria>filamentous fungi. 相似文献
93.
Erika G. Kisvarsanyi N.S. Sullivan 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1997,127(2):192-198
The theory of the formation of NMR multiple echoes for isotopic impurities (HD) in solid para-H2has been developed for the case of weak quantum tunneling of the impurities. The results show that even for low tunneling rates (100–1000 Hz), NMR multiple echoes can be observed for experimentally accessible nuclear spin polarizations and can be used to provide an independent test for the existence of tunneling in the solid hydrogens. 相似文献
94.
Ohne Zusammenfassung 相似文献
95.
R L Diehl M A Walsh K R Kluender 《The Journal of the Acoustical Society of America》1991,89(6):2905-2909
Fowler [J. Acoust. Soc. Am. 88, 1236-1249 (1990)] makes a set of claims on the basis of which she denies the general interpretability of experiments that compare the perception of speech sounds to the perception of acoustically analogous nonspeech sound. She also challenges a specific auditory hypothesis offered by Diehl and Walsh [J. Acoust. Soc. Am. 85, 2154-2164 (1989)] to explain the stimulus-length effect in the perception of stops and glides. It will be argued that her conclusions are unwarranted. 相似文献
96.
Cubaynes D Diehl S Wuilleumier FJ Meyer M Heinecke E Richter T Zimmermann P 《Physical review letters》2007,99(21):213004
The 1s photoionization of atomic Li was studied by photoelectron spectroscopy in the photon energy region between 85 and 140 eV for the ground state and the three lowest excited configurations Li(*) 1s(2)nl, nl=2p, 3s, 3p. The importance of electron correlations was investigated by comparing the multielectron transitions, so-called shake-up and conjugate shake-up satellites, and the direct process, so-called main lines. The relative intensity of the satellites increases with the level of initial excitation of the Li atom. The shake-up process dominates for states with an n=3 valence electron and the satellites become stronger than the main lines. This spectacular effect can be explained by the spatial overlap of the initial and final state wave functions. Surprisingly, the spatial overlap affects shake-up and conjugate shake-up lines in the same way. 相似文献
97.
A Hot‐Segment‐Based Approach for the Design of Cross‐Amyloid Interaction Surface Mimics as Inhibitors of Amyloid Self‐Assembly 下载免费PDF全文
Dr. Erika Andreetto Dipl.‐Chem. Eleni Malideli Dr. Li‐Mei Yan Dipl.‐Ing. Michael Kracklauer MSc. Karine Farbiarz Dipl.‐Chem. Marianna Tatarek‐Nossol Prof. Dr. Gerhard Rammes M. Sc. Elke Prade Tatjana Neumüller Dr. Andrea Caporale M. Sc. Anna Spanopoulou B. Sc. Maria Bakou Prof. Dr. Bernd Reif Prof. Dr. Aphrodite Kapurniotu 《Angewandte Chemie (International ed. in English)》2015,54(44):13095-13100
The design of inhibitors of protein–protein interactions mediating amyloid self‐assembly is a major challenge mainly due to the dynamic nature of the involved structures and interfaces. Interactions of amyloidogenic polypeptides with other proteins are important modulators of self‐assembly. Here we present a hot‐segment‐linking approach to design a series of mimics of the IAPP cross‐amyloid interaction surface with Aβ (ISMs) as nanomolar inhibitors of amyloidogenesis and cytotoxicity of Aβ, IAPP, or both polypeptides. The nature of the linker determines ISM structure and inhibitory function including both potency and target selectivity. Importantly, ISMs effectively suppress both self‐ and cross‐seeded IAPP self‐assembly. Our results provide a novel class of highly potent peptide leads for targeting protein aggregation in Alzheimer’s disease, type 2 diabetes, or both diseases and a chemical approach to inhibit amyloid self‐assembly and pathogenic interactions of other proteins as well. 相似文献
98.
99.
Erika N. Daley Christopher M. Vogels Dr. Stephen J. Geier Dr. Andreas Decken Dr. Simon Doherty Prof. Dr. Stephen A. Westcott 《Angewandte Chemie (International ed. in English)》2015,54(7):2121-2125
The synthesis of phosphinoboronate esters containing a single P? B bond is reported, together with preliminary reactivity studies towards a range of organic substrates. These compounds add readily to aldehydes, ketones, aldimines, and α,β‐unsaturated enones to give primarily the corresponding 1,2‐addition products containing a new P? C bond. The first examples of transition‐metal‐catalyzed phosphinoborations of C‐C multiple bonds in which P? C and B? C bonds are formed in a single step are also disclosed; allenes react by a highly regioselective 1,2‐addition whereas terminal alkynes undergo a formal 1,1‐addition. 相似文献
100.
György Keglevich Alajos Grün Erika Bálint Nóra Zsuzsa Kiss Péter Bagi László Tőke 《Structural chemistry》2017,28(2):431-443
Application of the microwave (MW) technique offers many advantages in organophosphorus syntheses. Reluctant reactions may take place on MW irradiation. In most cases, MWs make the reactions more efficient in respect of rate, selectivity and yield. The benefits are shown via representative examples. MW irradiation may replace a catalyst, or simplify catalytic systems. The synthesis of catalysts incorporating heterocyclic P-ligands is also discussed. Where it was relevant, structural chemical details were also provided. 相似文献