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41.
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The random-crystal field spin-1 Blume–Capel model is investigated by the lowest approximation of the cluster-variation method which is identical to the mean-field approximation. The crystal field is either turned on randomly with probability p or turned off with q=1−p in a bimodal distribution. Then the phase diagrams are constructed on the crystal field (Δ)–temperature (kT/J) planes for given values of p and on the (kT/J,p) planes for given Δ by studying the thermal variations of the order parameters. In the latter, we only present the second-order phase transition lines, because of the existence of irregular wiggly phase transitions which are not good enough to construct lines. In addition to these phase transitions, the model also yields tricritical points for all values of p and the reentrant behavior at lower p values. 相似文献
43.
We investigate the continuity of expected exponential utility maximization with respect to perturbation of the Sharpe ratio of markets. By focusing only on continuity, we impose weaker regularity conditions than those found in the literature. Specifically, we require, in addition to the V-compactness hypothesis of Larsen and ?itkovi? (2007) [13], a local bmo hypothesis, a condition which is essentially implicit in the setting of [13]. For markets of the form S=M+∫λd〈M〉, these conditions are simultaneously implied by the existence of a uniform bound on the norm of λ⋅M in a suitable bmo space. 相似文献
44.
Mine en Teker Erhan Karaca Nuran
ziek Pekmez Uur Tamer Kadir Pekmez 《Electroanalysis》2019,31(1):75-82
A poly(2‐aminophenylbenzimidazole)/gold nanoparticles (P2AB/AuNPs) coated disposable pencil graphite electrode (PGE) was fabricated as an enzyme‐free sensor for the H2O2 determination. P2AB/AuNPs and P2AB were successfully synthesized electrochemically on PGE in acetonitrile for the first time. The coatings were characterized by scanning electron microscopy, X‐ray diffraction spectroscopy, Energy‐dispersive X‐ray spectroscopy, Surface‐enhanced Raman spectroscopy, and UV‐Vis spectroscopy. AuNPs interacted with P2AB as carrier enhances the electrocatalytic activity towards reduction of H2O2. The analytical performance was evaluated in a 100 mM phosphate buffer solution at pH 6.5 by amperometry. The steady state current vs. H2O2 concentration is linear in the range of 0.06 to 100 mM (R2=0.992) with a limit of detection 3.67×10?5 M at ?0.8 V vs. SCE and no interference is caused by ascorbic acid, dopamine, uric acid, and glucose. The examination for the sensitive determination of H2O2 was conducted in commercially available hair oxidant solution. The results demonstrate that P2AB/AuNPs/PGE has potential applications as a sensing material for quantitative determination of H2O2. 相似文献
45.
Erbilen Nesibe Zor Erhan Saf Ahmet Ozgur Akgemci Emine Guler Bingol Haluk 《Journal of Solid State Electrochemistry》2019,23(9):2695-2705
Journal of Solid State Electrochemistry - Chirality is a universal characteristic of natural systems and discrimination of enantiomers of a chiral molecule plays a major role particularly in... 相似文献
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47.
Gyrgy Keglevich Tungalag Chuluunbaatar Beta Dajka Bat‐Amgalan Namkhainyambuu Krisztina Ludnyi Lszl Tke 《Heteroatom Chemistry》2001,12(7):633-635
Four different [4 + 2] cycloadditions were observed to take place in the equimolar mixtures of two different arylphosphole oxides 2a + 2b or 2b + 2c . In addition to the phosphole oxide dimers 3a‐a and 3b‐b , or 3b‐b and 3c‐c , the crossed cycloadducts 3a‐b and 3b‐a , or 3b‐c and 3c‐b were also formed in considerable portions. © 2001 John Wiley & Sons, Inc. Heteroatom Chem 12:633–635, 2001 相似文献
48.
The objective of this work was to obtain a simpler and more accurate analytical expression to determine the Debye–Waller factor of crystals using an n-dimensional Debye approximation involving binomial coefficients and incomplete gamma functions. The results obtained were compared with the corresponding experimental and theoretical results and, the calculated values were shown to be in excellent agreement with those obtained in the experimental and other previous studies. 相似文献
49.
The statistical mechanics of spin-1 Ising model with AFM/AFM interactions on a bilayer Bethe lattice
Erhan Albayrak Seyma Akkaya Tun Cengiz 《Journal of magnetism and magnetic materials》2009,321(22):3726-3733
The spin-1 Ising model is studied for the case of antiferromagnetic (AFM)/AFM interactions on the bilayer Bethe lattice by using the pairwise approach for several values of the coordination numbers q=3, 4 and 6 when the layers are linked with the external magnetic fields. The ground state (GS) phase diagrams, thermal variations of the order-parameters and the response functions are studied in detail to obtain the phase diagrams of the model. It was found that the system gives only one Néel temperature, TN, for q=3. Two TN's and first-order phase transition temperature, Tt, thus tricritical point, are found and the existence of two TN's leads to the reentrant behavior when q=4 and 6 for some given system parameters. 相似文献
50.
Yavuz Kysal amil Ik Gülay ahin Erhan Palaska 《Acta Crystallographica. Section C, Structural Chemistry》2005,61(9):o542-o544
The structures of N‐ethyl‐3‐(4‐fluorophenyl)‐5‐(4‐methoxyphenyl)‐2‐pyrazoline‐1‐thiocarboxamide, C19H20FN3OS, (I), and 3‐(4‐fluorophenyl)‐N‐methyl‐5‐(4‐methylphenyl)‐2‐pyrazoline‐1‐thiocarboxamide, C18H18FN3S, (II), have similar geometric parameters. The methoxy/methyl‐substituted phenyl groups are almost perpendicular to the pyrazoline (pyraz) ring [interplanar angles of 89.29 (8) and 80.39 (10)° for (I) and (II), respectively], which is coplanar with the fluorophenyl ring [interplanar angles of 5.72 (9) and 10.48 (10)°]. The pyrazoline ring approximates an envelope conformation in both structures, with the two‐coordinate N atom involved in an intramolecular N—H⋯Npyraz interaction. In (I), N—H⋯O and C—H⋯S intermolecular hydrogen bonds are the primary interactions, whereas in (II), there are no intermolecular hydrogen bonds. 相似文献