Simultaneous Determination of Anthocyanin and Ponceau 4R in Drink Powders by Derivative Spectrophotometry and Partial Least-Squares Multivariate Spectrophotometric Calibration

 Two methods for the simultaneous determination of anthocyanin and ponceau 4R in drink powders by second derivative spectrophotometry and by partial least-squares multivariate spectrophotometric calibration are described. The procedures do not require any separation step. The methods were applied to determine both colorants in commercial gelatin powders; the results obtained are compared.     

Hydrogen photoevolution on InGaP polycrystalline and tandem-type electrodes

We report on preparation of p-In_1−x Ga _x P polycrystalline, p-In_0.5 Ga_0.5P/p-GaAs, and p-In_0.5 Ga_0.5P/n-GaAs/n-InP tandem-type cathodes. The photovoltaic efficiency of InGaP tandem type epitaxial electrodes is two times higher than that of polycrystalline photocathodes. The most significant advantage of epitaxial electrodes is in their markedly better corrosion resistance in comparison with polycrystalline photocatodes. Presented at the 1st Czech-Chinese Workshop “Advanced Materials for Optoelectronics”, Prague, Czech Republic, June 13–17, 1998.     

气相色谱-质谱联用分析花椒挥发油的成分

 采用气相色谱 质谱联用技术对陕西富平产花椒挥发油的成分进行了分析 ,分离出了 17个峰 ,鉴定出了相对峰面积大于 1 0 %的组分共 16个 ,用峰面积归一化法定量测定了已确定组分的相对含量 ,其占挥发油总质量的95 %以上。     

用强阴离子交换毛细管电色谱分离阴离子化合物

对阴离子性化合物在强阴离子交换毛细管电色谱中的保留行为进行了研究。发现样品中固定相上的吸附使样品的保留因子k^*变小,柱小的分离能力减小;而电压的增大,使酸性样品的k^*也增大,并且电压的改变也能改变分离的选择性;样品保留因子的对数值随着缓冲液离子强度的对数值的增大而线性减小;样品也强阴子交换毛细管电谱和毛细管区带电泳中有不同的保留行为。     

Enantioseparation of aromatic amino acids using CEC monolith with novel chiral selector,N‐methacryloyl‐l‐histidine methyl ester

A new type of polymethacrylate‐based monolithic column with chiral stationary phase was prepared for the enantioseparation of aromatic amino acids, namely d ,l ‐phenylalanine, d ,l ‐tyrosine, and d ,l ‐tryptophan by CEC. The monolithic column was prepared by in situ polymerization of butyl methacrylate (BMA), N‐methacryloyl‐l ‐histidine methyl ester (MAH), and ethylene dimethacrylate (EDMA) in the presence of porogens. The porogen mixture included DMF and phosphate buffer. MAH was used as a chiral selector. FTIR spectrum of the polymethacrylate‐based monolith showed that MAH was incorporated into the polymeric structure via in situ polymerization. Some experimental parameters including pH, concentration of the mobile phase, and MAH concentration with regard to the chiral CEC separation were investigated. Single enantiomers and enantiomer mixtures of the amino acids were separately injected into the monolithic column. It was observed that l ‐enantiomers of aromatic amino acids migrated before d ‐enantiomers. The reversal enantiomer migration order for tryptophan was observed upon changing of pH. Using the chiral monolithic column (100 μm id and 375 μm od), the best chiral separation was performed in 35:65% ACN/phosphate buffer (pH 8.0, 10 mM) with an applied voltage of 12 kV in CEC. SEM images showed that the chiral monolithic column has a continuous polymeric skeleton and large through‐pore structure.     

Particle Emission from Welding of Painted Steel

The particulate emission caused by welding of steel plates covered with 29 diversified shop primers has been investigated. The investigation includes the determination of particle mass, particle size distribution, and of the contents of heavy metals such as lead and cadmium. The results show that all investigated primers except those with high concentration of zinc pigment produce mass emissions which are very low in comparison to manual arc welding with covered electrode and CO₂-welding on uncoated steel. The emitted particles of the primers are smaller than 1 μm particle diameter and therefore respirable. Lead and cadmium was found in particles emitted during the welding process of all investigated primers. The highest amount was found in particles of primers with high contents of zinc and ferric oxide.     

On unsteady unidirectional flows of a second grade fluid

Some properties of unsteady unidirectional flows of a fluid of second grade are considered for flows produced by the sudden application of a constant pressure gradient or by the impulsive motion of one or two boundaries. Exact analytical solutions for these flows are obtained and the results are compared with those of a Newtonian fluid. It is found that the stress at the initial time on the stationary boundary for flows generated by the impulsive motion of a boundary is infinite for a Newtonian fluid and is finite for a second grade fluid. Furthermore, it is shown that initially the stress on the stationary boundary, for flows started from rest by sudden application of a constant pressure gradient is zero for a Newtonian fluid and is not zero for a fluid of second grade. The required time to attain the asymptotic value of a second grade fluid is longer than that for a Newtonian fluid. It should be mentioned that the expressions for the flow properties, such as velocity, obtained by the Laplace transform method are exactly the same as the ones obtained for the Couette and Poiseuille flows and those which are constructed by the Fourier method. The solution of the governing equation for flows such as the flow over a plane wall and the Couette flow is in a series form which is slowly convergent for small values of time. To overcome the difficulty in the calculation of the value of the velocity for small values of time, a practical method is given. The other property of unsteady flows of a second grade fluid is that the no-slip boundary condition is sufficient for unsteady flows, but it is not sufficient for steady flows so that an additional condition is needed. In order to discuss the properties of unsteady unidirectional flows of a second grade fluid, some illustrative examples are given.     

On closedness assumptions in selection theorems

We begin by a short survey of various attempts in selection theory to avoid the closedness assumption for values of multivalued mappings. We collect special cases when Michael's Gδ-problem admits an affirmative solution and we prove some unified theorems of such type. We also show that in general this problem has a negative solution. In comparison with a recent result of Filippov, we work directly in the Hilbert cube rather than in the space of all probabilistic measures endowed with different topologies.     

Some difference sequence spaces defined by a sequence of <Emphasis Type="Italic">ϕ</Emphasis> -functions

Abstract  In this paper, we introduce new difference sequence spaces combining with de la Vallee-Poussin mean using by a sequence of modulus functions and ϕ -functions. We also studied connections between statistically convergence related with this space. Keywords Difference sequence, Modulus function, ϕ -function, De la Vallee-Poussin means, Statistical convergence Mathematics Subject Classification (2000) 46A45, 40F05, 46A80